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Bismuth tribromide information


Bismuth tribromide
Bismuth bromide
α polymorph
β polymorph
Names
IUPAC name
bismuth bromide
Other names
bismuth tribromide
tribromobismuth
tribromobismuthine
tribromobismuthane
bismuth(III) bromide
Identifiers
CAS Number
  • 7787-58-8
3D model (JSmol)
  • Interactive image
ChemSpider
  • 74210
ECHA InfoCard 100.029.201 Edit this at Wikidata
EC Number
  • 232-121-1
PubChem CID
  • 82232
UNII
  • DT59198T2X
CompTox Dashboard (EPA)
  • DTXSID8064850 Edit this at Wikidata
InChI
  • InChI=1S/Bi.3BrH/h;3*1H/q+3;;;/p-3
    Key: TXKAQZRUJUNDHI-UHFFFAOYSA-K
  • InChI=1/Bi.3BrH/h;3*1H/q+3;;;/p-3
    Key: TXKAQZRUJUNDHI-DFZHHIFOAX
SMILES
  • Br[Bi](Br)Br
Properties
Chemical formula
 BiBr3
Molar mass 448.692 g·mol−1
Appearance white to light yellow or golden deliquescent crystals[1]
Density 5.72 g/cm3 at 25 °C[1]
Melting point 219 °C (426 °F; 492 K) [1]
Boiling point 462 °C (864 °F; 735 K) [1]
Solubility in water
 Soluble, slow hydrolysis
Solubility diethyl ether, THF
Magnetic susceptibility (χ)
 -147.0·10−6 cm3/mol
Thermochemistry
Std enthalpy of
formation (ΔfH⦵298)
 −276[1]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
 corrosive[2]
GHS labelling:
Pictograms
 GHS05: Corrosive
Signal word
 Danger
Hazard statements
 H314
Precautionary statements
 P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
0
1
Related compounds
Other anions
 bismuth trifluoride
bismuth trichloride
bismuth triiodide
Other cations
 nitrogen tribromide
phosphorus tribromide
arsenic tribromide
antimony tribromide
aluminium tribromide
iron(III) bromide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Bismuth tribromide is an inorganic compound of bismuth and bromine with the chemical formula BiBr3.

  1. ^ a b c d e Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 558–561. ISBN 978-0-08-037941-8.
  2. ^ "Sigma-Aldrich: 654981 Bismuth(III) bromide anhydrous, powder, 99.999% trace metals basis". Archived from the original on 2012-02-11.

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Bismuth tribromide

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Bismuth tribromide is an inorganic compound of bismuth and bromine with the chemical formula BiBr3. It may be formed by the reaction of bismuth oxide...

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Tribromide

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Americium tribromide, AmBr3 Antimony tribromide, SbBr3 Arsenic tribromide, AsBr3 Berkelium tribromide, BkBr3 Bismuth tribromide, BiBr3 Boron tribromide, BBr3...

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Bismuth pentafluoride

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Bismuth pentafluoride is an inorganic compound with the formula BiF5. It is a white solid that is highly reactive. The compound is of interest to researchers...

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List of inorganic compounds

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Bismuth(III) telluride – Bi2Te3 Bismuth(III) telluride – Bi2Te3 Bismuth tribromide – BiBr3 Bismuth tungstate – Bi2WO6 Borane – BH3 Borax – Na2B4O7·10H2O Borazine...

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Pnictogen

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the elements nitrogen (N), phosphorus (P), arsenic (As), antimony (Sb), bismuth (Bi), and moscovium (Mc). Since 1988, IUPAC calls it Group 15. Before that...

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Stibinin

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1-dibutyl-1,4-dihydrostannine with arsenic trichloride, phosphorus tribromide, or bismuth trichloride can yield arsabenzene, phosphabenzene, or 1-chloro-1-bismacyclohexa-2...

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Actinium

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ammonia. Reaction of aluminium bromide and actinium oxide yields actinium tribromide: Ac2O3 + 2 AlBr3 → 2 AcBr3 + Al2O3 and treating it with ammonium hydroxide...

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Nitrogen

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and is thus used industrially to bleach and sterilise flour. Nitrogen tribromide (NBr3), first prepared in 1975, is a deep red, temperature-sensitive,...

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Bromine

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nitrides, fluorides, or chlorides of bromine. (Nonetheless, nitrogen tribromide is named as a bromide as it is analogous to the other nitrogen trihalides...

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Nitrogen compounds

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and is thus used industrially to bleach and sterilise flour. Nitrogen tribromide (NBr3), first prepared in 1975, is a deep red, temperature-sensitive,...

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Metalloid

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beryllium, nitrogen, phosphorus, sulfur, zinc, gallium, tin, iodine, lead, bismuth, and radon. The term metalloid has also been used for elements that exhibit...

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Bromoantimonates

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designated by bromoantimonate(III) or bromoantimonate(V). Although antimony tribromide is known, SbBr5 on its own does not exist, despite the existence of SbBr−6...

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Antimony trichloride

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trichloride is prepared by reaction of chlorine with antimony, antimony tribromide, antimony trioxide, or antimony trisulfide. It also may be made by treating...

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Berkelium

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californium-249 ingrowth into crystalline berkelium-249 tribromide: a new crystalline phase of californium tribromide". Inorganic Chemistry. 19 (8): 2209. doi:10...

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Nitrogen trifluoride

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reactive than the other nitrogen trihalides nitrogen trichloride, nitrogen tribromide and nitrogen triiodide, all of which are explosive. Alone among the nitrogen...

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List of CAS numbers by chemical compound

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telluride 12002–99–2 Ag3Br2 silver dibromide 11078–32–3 Ag3Br3 silver tribromide 11078–33–4 Ag3Cl3 trisilver trichloride 12444–96–1 Ag3I3 trisilver triiodide...

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Technetium

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either trichloride phase. Instead it has the structure of molybdenum tribromide, consisting of chains of confacial octahedra with alternating short and...

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Osmium

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states are stabilized by the larger halogens, so that the trichloride, tribromide, triiodide, and even diiodide are known. The oxidation state +1 is known...

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Aluminium

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trigonal planar AlCl3 monomers similar to the structure of BCl3. Aluminium tribromide and aluminium triiodide form Al2X6 dimers in all three phases and hence...

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Nihonium

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influence of the 6d5/2 electrons on the bonding. The heavier nihonium tribromide (NhBr3) and triiodide (NhI3) are trigonal planar due to the increased...

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Fluorine compounds

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contrast to gold's distinctly ionic trifluoride, its trichloride and tribromide are volatile dimeric molecules. Aluminium trifluoride is a high melting...

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Curium

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F. H. (1965). "Crystal Structures of the Trifluorides, Trichlorides, Tribromides, and Triiodides of Americium and Curium". Inorganic Chemistry. 4 (7):...

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Lanthanide

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producing ammonia. The other pnictides phosphorus, arsenic, antimony and bismuth also react with the lanthanide metals to form monopnictides, LnQ, where...

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Glossary of chemical formulae

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Bi(VO3)5 bismuth(III) metavanadate Bi2Se3 bismuth(III) selenide bismuth selenide 12068-69-8 Bi2(MoO4)3 bismuth(III) molybdate 13565-96-3 Bi2O3 bismuth(III)...

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Ruthenium

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known trihalides, trifluoride is dark brown and decomposes above 650 °C, tribromide is dark-brown and decomposes above 400 °C, and triiodide is black. Of...

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Group 7 element

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either trichloride phase. Instead it has the structure of molybdenum tribromide, consisting of chains of confacial octahedra with alternating short and...

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