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Technetium information


Technetium, 43Tc
Technetium
Pronunciation/tɛkˈnʃ(i)əm/ (tek-NEE-sh(ee-)əm)
Appearanceshiny gray metal
Mass number[97]
Technetium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Mn

Tc

Re
molybdenum ← technetium → ruthenium
Atomic number (Z)43
Groupgroup 7
Periodperiod 5
Block  d-block
Electron configuration[Kr] 4d5 5s2
Electrons per shell2, 8, 18, 13, 2
Physical properties
Phase at STPsolid
Melting point2430 K ​(2157 °C, ​3915 °F)
Boiling point4538 K ​(4265 °C, ​7709 °F)
Density (at 20° C)98Tc: 11.359 g/cm3
99Tc: 11.475 g/cm3[1]
Heat of fusion33.29 kJ/mol
Heat of vaporization585.2 kJ/mol
Molar heat capacity24.27 J/(mol·K)
Vapor pressure (extrapolated)
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 2727 2998 3324 3726 4234 4894
Atomic properties
Oxidation states−1, 0, +1,[2][citation needed] +2, +3, +4, +5, +6, +7 (a strongly acidic oxide)
ElectronegativityPauling scale: 1.9
Ionization energies
  • 1st: 686.9[3] kJ/mol
  • 2nd: 1470 kJ/mol
  • 3rd: 2850 kJ/mol
Atomic radiusempirical: 136 pm
Covalent radius147±7 pm
Van der Waals radius205 pm
Color lines in a spectral range
Spectral lines of technetium
Other properties
Natural occurrencefrom decay
Crystal structure ​hexagonal close-packed (hcp) (hP2)
Lattice constants
Hexagonal close packed crystal structure for technetium
a = 274.12 pm
c = 439.90 pm (at 20 °C)[1]
Thermal expansion8.175×10−6/K (at 20 °C)[1]
Thermal conductivity50.6 W/(m⋅K)
Electrical resistivity200 nΩ⋅m (at 20 °C)
Magnetic orderingParamagnetic
Molar magnetic susceptibility+270.0×10−6 cm3/mol (298 K)[4]
Speed of sound thin rod16,200 m/s (at 20 °C)
CAS Number7440-26-8
History
PredictionDmitri Mendeleev (1871)
Discovery and first isolationEmilio Segrè and Carlo Perrier (1937)
Isotopes of technetium
Main isotopes[5] Decay
abun­dance half-life (t1/2) mode pro­duct
95mTc synth 61.96 d β+ 95Mo
IT 95Tc
Preview warning: Unknown parameter cat:#U "perdc1"
96Tc synth 4.28 d β+ 96Mo
γ
97Tc synth 4.21×106 y ε 97Mo
97mTc synth 91.1 d IT 97Tc
ε ...
Preview warning: Infobox Tc isotopes: Decay product missing; pn2, ps2 for "dm2=epsi_link" cat#P
98Tc synth 4.2×106 y β 98Ru
β+
99Tc trace 2.111×105 y β 99Ru
99mTc synth 6.01 h IT 99Tc
β
Technetium Category: Technetium
| references

Technetium is a chemical element; it has symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. Technetium and promethium are the only radioactive elements whose neighbours in the sense of atomic number are both stable. All available technetium is produced as a synthetic element. Naturally occurring technetium is a spontaneous fission product in uranium ore and thorium ore (the most common source), or the product of neutron capture in molybdenum ores. This silvery gray, crystalline transition metal lies between manganese and rhenium in group 7 of the periodic table, and its chemical properties are intermediate between those of both adjacent elements. The most common naturally occurring isotope is 99Tc, in traces only.

Many of technetium's properties had been predicted by Dmitri Mendeleev before it was discovered. Mendeleev noted a gap in his periodic table and gave the undiscovered element the provisional name ekamanganese (Em). In 1937, technetium became the first predominantly artificial element to be produced, hence its name (from the Greek τεχνητός, technetos, from techne, as in "craft", "art" and having the meaning of "artificial", + -ium).

One short-lived gamma ray-emitting nuclear isomer, technetium-99m, is used in nuclear medicine for a wide variety of tests, such as bone cancer diagnoses. The ground state of the nuclide technetium-99 is used as a gamma-ray-free source of beta particles. Long-lived technetium isotopes produced commercially are byproducts of the fission of uranium-235 in nuclear reactors and are extracted from nuclear fuel rods. Because even the longest-lived isotope of technetium has a relatively short half-life (4.21 million years), the 1952 detection of technetium in red giants helped to prove that stars can produce heavier elements.

  1. ^ a b c Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
  2. ^ "Technetium: technetium(III) iodide compound data". OpenMOPAC.net. Retrieved 2007-12-10.
  3. ^ Mattolat, C.; Gottwald, T.; Raeder, S.; Rothe, S.; Schwellnus, F.; Wendt, K.; Thörle-Pospiech, P.; Trautmann, N. (24 May 2010). "Determination of the first ionization potential of technetium". Physical Review A. 81: 052513. doi:10.1103/PhysRevA.81.052513.
  4. ^ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
  5. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.

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Technetium

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Technetium is a chemical element; it has symbol Tc and atomic number 43. It is the lightest element whose isotopes are all radioactive. Technetium and...

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classified as synthetic alongside exclusively artificial elements. The first, technetium, was created in 1937. Plutonium (Pu, atomic number 94), first synthesized...

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Technetium (43Tc) is one of the two elements with Z < 83 that have no stable isotopes; the other such element is promethium. It is primarily artificial...

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group of elements in the periodic table. It contains manganese (Mn), technetium (Tc), rhenium (Re) and bohrium (Bh). This group lies in the d-block of...

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A technetium star, or more properly a Tc-rich star, is a star whose stellar spectrum contains absorption lines of the light radioactive metal technetium...

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There are three technetium chlorides: Technetium(II) chloride Technetium(III) chloride, a black solid Technetium(IV) chloride, a red solid This set index...

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Technetium oxide may refer to: Technetium(IV) oxide, TcO2 Technetium trioxide, TcO3 Technetium(VII) oxide, Tc2O7 This set index article lists chemical...

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Pertechnetate

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convenient water-soluble source of isotopes of the radioactive element technetium (Tc). In particular it is used to carry the 99mTc isotope (half-life 6...

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been noted. Technetium was the first purportedly non-naturally occurring element synthesized, in 1937, although trace amounts of technetium have since...

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however, there are exceptions, such as rhodium. This period contains technetium, one of the two elements until lead that has no stable isotopes (along...

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emitter. Technetium-99m is a gamma emitter. It is obtained on-site at the imaging center as the soluble pertechnetate which is eluted from a technetium-99m...

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unstable isotopes of molybdenum decay into isotopes of zirconium, niobium, technetium, and ruthenium. Molybdenum-100, with a half-life of approximately 8.5×1018 y...

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DMSA scan

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(DMSA) in assessing renal morphology, structure and function. Radioactive technetium-99m is combined with DMSA and injected into a patient, followed by imaging...

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Succimer

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to treat lead, mercury, and arsenic poisoning. When radiolabeled with technetium-99m, it is used in many types of diagnostic testing. A full course of...

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Technetium compounds are chemical compounds containing the chemical element technetium. Technetium can form multiple oxidation states, but often forms...

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