Global Information Lookup Global Information

Antimony trichloride information


Antimony trichloride
Stereo structural formula of antimony trichloride
Stereo structural formula of antimony trichloride
Ball and stick model of antimony trichloride
Ball and stick model of antimony trichloride
Names
Preferred IUPAC name
Antimony trichloride
Systematic IUPAC name
Trichlorostibane
Other names
Antimony(III) chloride, Butter of antimony, Antimonous chloride, Stibous chloride, Trichlorostibine
Identifiers
CAS Number
  • 10025-91-9 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:74856 ☒N
ChemSpider
  • 23199 checkY
ECHA InfoCard 100.030.031 Edit this at Wikidata
EC Number
  • 233-047-2
KEGG
  • C15235 ☒N
MeSH Antimony+trichloride
PubChem CID
  • 24814
RTECS number
  • CC4900000
UNII
  • J281401KK3 checkY
UN number 1733
CompTox Dashboard (EPA)
  • DTXSID4044161 Edit this at Wikidata
InChI
  • InChI=1S/3ClH.Sb/h3*1H;/q;;;+3/p-3 checkY
    Key: FAPDDOBMIUGHIN-UHFFFAOYSA-K checkY
  • InChI=1S/3ClH.Sb/h3*1H;/q;;;+3/p-3
    Key: FAPDDOBMIUGHIN-UHFFFAOYSA-K
  • InChI=1/3ClH.Sb/h3*1H;/q;;;+3/p-3
    Key: FAPDDOBMIUGHIN-DFZHHIFOAK
SMILES
  • Cl[Sb](Cl)Cl
Properties
Chemical formula
 Cl3Sb
Molar mass 228.11 g·mol−1
Appearance Colorless solid, very hygroscopic
Odor Sharp, pungent
Density 3.14 g/cm3 (25 °C)
2.51 g/cm3 (150 °C)[1]
Melting point 73.4 °C (164.1 °F; 346.5 K)[5]
Boiling point 223.5 °C (434.3 °F; 496.6 K)
Solubility in water
 601.1 g/100 ml (0 °C)[1]
985.1 g/100 mL (25 °C)
1.357 kg/100 mL (40 °C)[2]
Solubility Soluble in acetone, ethanol, CH2Cl2, phenyls, ether, dioxane, CS2, CCl4, CHCl3, cyclohexane, selenium(IV) oxychloride
Insoluble in pyridine, quinoline, organic bases
Solubility in acetic acid 143.9 g/100 g (0 °C)
205.8 g/100 g (10 °C)
440.5 g/100 g (25 °C)[3]
693.7 g/100 g (45 °C)[2]
Solubility in acetone 537.6 g/100 g (18 °C)[2][3]
Solubility in benzoyl chloride 139.2 g/100 g (15 °C)
169.5 g/100 g (25 °C)[3]
2.76 kg/100 g (70 °C)[2]
Solubility in hydrochloric acid 20 °C:
8.954 g/ g (4.63% w/w)
8.576 g/ g (14.4% w/w)
7.898 g/ g (36.7% w/w)[2]
Solubility in p-Cymene 69.5 g/100 g (-3.5 °C)
85.5 g/100 g (10 °C)
150 g/100 g (30 °C)
2.17 kg/100 g (70 °C)[2]
Vapor pressure 13.33 Pa (18.1 °C)[3]
0.15 kPa (50 °C)
2.6 kPa (100 °C)[4]
Magnetic susceptibility (χ)
 -86.7·10−6 cm3/mol
Refractive index (nD)
 1.46[1]
Structure
Crystal structure
 Orthorhombic
Dipole moment
 3.93 D (20 °C)[3]
Thermochemistry
Heat capacity (C)
 183.3 J/mol·K[3]
Std molar
entropy (S⦵298)
 110.5 J/mol·K[3]
Std enthalpy of
formation (ΔfH⦵298)
 -381.2 kJ/mol[3]
Gibbs free energy (ΔfG⦵)
 -322.5 kJ/mol[3]
Hazards
GHS labelling:
Pictograms
 GHS05: CorrosiveGHS09: Environmental hazard[5]
Signal word
 Danger
Hazard statements
 H314, H411[5]
Precautionary statements
 P273, P280, P305+P351+P338, P310[5]
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
2
0
1
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)
 525 mg/kg (oral, rat)
NIOSH (US health exposure limits):
PEL (Permissible)
 TWA 0.5 mg/m3 (as Sb)[6]
REL (Recommended)
 TWA 0.5 mg/m3 (as Sb)[6]
Safety data sheet (SDS) ICSC 1224
Related compounds
Other anions
 Antimony trifluoride
Antimony tribromide
Antimony triiodide
Other cations
 Nitrogen trichloride
Phosphorus trichloride
Arsenic trichloride
Bismuth chloride
Related compounds
 Antimony pentachloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Antimony trichloride is the chemical compound with the formula SbCl3. It is a soft colorless solid with a pungent odor and was known to alchemists as butter of antimony.

  1. ^ a b c "Antimony Trichloride, SbCl3".
  2. ^ a b c d e f Seidell, Atherton; Linke, William F. (1952). Solubilities of Inorganic and Organic Compounds. Van Nostrand.
  3. ^ a b c d e f g h i "Antimony(III) chloride".
  4. ^ Antimony trichloride in Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD) (retrieved 2014-05-28)
  5. ^ a b c d Sigma-Aldrich Co., Antimony(III) chloride. Retrieved on 2014-05-29.
  6. ^ a b NIOSH Pocket Guide to Chemical Hazards. "#0036". National Institute for Occupational Safety and Health (NIOSH).

and 29 Related for: Antimony trichloride information

Request time (Page generated in 0.8183 seconds.)

Antimony trichloride

Last Update:

butter of antimony. Antimony trichloride is prepared by reaction of chlorine with antimony, antimony tribromide, antimony trioxide, or antimony trisulfide...

Word Count : 813

Trichloride

Last Update:

Aluminium trichloride, AlCl3 Americium trichloride, AmCl3 Antimony trichloride, SbCl3 also known as butter of antimony Arsenic trichloride, AsCl3, also...

Word Count : 300

Antimony

Last Update:

of antimony can be formed from the electrolysis of antimony trichloride, but it always contains appreciable chlorine and is not really an antimony allotrope...

Word Count : 6755

Antimony pentachloride

Last Update:

in glass or PTFE containers. Antimony pentachloride is prepared by passing chlorine gas into molten antimony trichloride: SbCl3 + Cl2 → SbCl5 Gaseous...

Word Count : 532

Explosive antimony

Last Update:

the allotrope through electrolysis of a concentrated solution of antimony trichloride in hydrochloric acid, which forms an amorphous glass. This glass...

Word Count : 497

Antimony chloride

Last Update:

Antimony chloride may refer to either of the following: Antimony trichloride, SbCl3 Antimony pentachloride, SbCl5 This disambiguation page lists articles...

Word Count : 47

Absinthe

Last Update:

produced before the ban were reportedly adulterated with poisonous antimony trichloride, reputed to enhance the louching effect. Absinthe may also be naturally...

Word Count : 10695

Antimony oxychloride

Last Update:

A. V. (1981). "Physiochemical analysis of antimony trioxide–antimony trichloride, antimony trioxide–antimony tribromide systems". Zhurnal Neorganicheskoi...

Word Count : 790

Phosphorus trichloride

Last Update:

Phosphorus trichloride is an inorganic compound with the chemical formula PCl3. A colorless liquid when pure, it is an important industrial chemical,...

Word Count : 1731

Arsenic trichloride

Last Update:

Arsenic trichloride is an inorganic compound with the formula AsCl3, also known as arsenous chloride or butter of arsenic. This poisonous oil is colourless...

Word Count : 682

Organoantimony chemistry

Last Update:

synthesis typically begins with tricoordinate antimony compounds, called stibines. Antimony trichloride reacts with organolithium or Grignard reagents...

Word Count : 758

Pnictogen

Last Update:

trihalides. Antimony forms antimony(III) oxide and antimonite but not oxyacids. Its trihalides, antimony trifluoride, antimony trichloride, antimony tribromide...

Word Count : 4008

Triphenylstibine

Last Update:

angle are 95°. SbPh3 was first reported in 1886, being prepared from antimony trichloride by the reaction: 6 Na + 3 C6H5Cl + SbCl3 → (C6H5)3Sb + 6 NaCl An...

Word Count : 215

List of alchemical substances

Last Update:

spirits – ethanol, formed by distilling wine Butter (or oil) of antimony – antimony trichloride. Formed by distilling roasted stibnite with corrosive sublimate...

Word Count : 1523

Solubility table

Last Update:

3.05 7.0 Aniline C6H7N 3.6 Antimony trifluoride SbF3 385 444 562 dec Antimony sulfide Sb2S3 1.8×10−4 Antimony trichloride SbCl3 602 910 1090 1370 1917...

Word Count : 191

Chloroform

Last Update:

name "chloroform" is a portmanteau of terchloride (tertiary chloride, a trichloride) and formyle, an obsolete name for the methylidene radical (CH) derived...

Word Count : 5618

List of inorganic compounds

Last Update:

sulfate – Sb2(SO4)3 Antimony trichloride – SbCl3 Antimony trifluoride – SbF3 Antimony trioxide – Sb2O3 Antimony trisulfide – Sb2S3 Antimony pentasulfide –...

Word Count : 8726

List of common misconceptions

Last Update:

and some also reportedly adulterated cheap absinthe with poisonous antimony trichloride, reputed to enhance the louching effect. It is not possible to get...

Word Count : 53692

Chloral

Last Update:

Ethanol can also be used as a feedstock. This reaction is catalyzed by antimony trichloride: H3CCHO + 3 Cl2 + H2O → Cl3CCH(OH)2 + 3 HCl The chloral hydrate is...

Word Count : 779

List of CAS numbers by chemical compound

Last Update:

28950–34–7 SbBr3 antimony tribromide 7789–61–9 SbCl2F3 antimony dichlorotrifluoride 7791–16–4 SbCl3 antimony trichloride 10025–91–9 SbCl5 antimony pentachloride...

Word Count : 120

Trivial name

Last Update:

other names like sugar of lead (lead(II) acetate), butter of antimony (antimony trichloride), oil of vitriol (sulfuric acid), and cream of tartar (potassium...

Word Count : 2885

Antimony trifluoride

Last Update:

Antimony trifluoride is the inorganic compound with the formula SbF3. Sometimes called Swarts' reagent, it is one of two principal fluorides of antimony...

Word Count : 459

Inorganic nonaqueous solvent

Last Update:

sulfur dioxide, sulfuryl chloride fluoride, dinitrogen tetroxide, antimony trichloride, and bromine trifluoride. These solvents have proven useful for study...

Word Count : 751

Stibinin

Last Update:

product of the first step, 1,1-dibutyl-1,4-dihydrostannine, with antimony trichloride, to yield 1-chloro-1-stibacyclohexa-2,5-diene. C13H24Sn + SbCl3 →...

Word Count : 372

Halothane

Last Update:

trichloroethylene, which is reacted with hydrogen fluoride in the presence of antimony trichloride at 130 °C to form 2-chloro-1,1,1-trifluoroethane. This is then reacted...

Word Count : 2774

Metalloid

Last Update:

commonly recognised metalloids are boron, silicon, germanium, arsenic, antimony and tellurium. Five elements are less frequently so classified: carbon...

Word Count : 28116

Trithiazyl trichloride

Last Update:

Trithiazyl trichloride is the inorganic compound with the formula (NSCl)3. A white solid, it is a precursor to other sulfur nitrides, but has no commercial...

Word Count : 408

Bismuth chloride

Last Update:

mixture to give BiCl3·2H2O, which can be distilled to form the anhydrous trichloride. Alternatively, it may be prepared by adding hydrochloric acid to bismuth...

Word Count : 592

Dichloroacetaldehyde

Last Update:

heated. In the presence of Lewis acids such as antimony trichloride, iron(III) chloride, aluminum trichloride, tin(IV) chloride or boron trifluoride, the...

Word Count : 232
PDF Search Engine © AllGlobal.net