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Ruthenium information


Ruthenium, 44Ru
Ruthenium
Pronunciation/rˈθniəm/ (roo-THEE-nee-əm)
Appearancesilvery white metallic
Standard atomic weight Ar°(Ru)
  • 101.07±0.02[1]
  • 101.07±0.02 (abridged)[2]
Ruthenium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Fe

Ru

Os
technetium ← ruthenium → rhodium
Atomic number (Z)44
Groupgroup 8
Periodperiod 5
Block  d-block
Electron configuration[Kr] 4d7 5s1
Electrons per shell2, 8, 18, 15, 1
Physical properties
Phase at STPsolid
Melting point2607 K ​(2334 °C, ​4233 °F)
Boiling point4423 K ​(4150 °C, ​7502 °F)
Density (at 20° C)12.364 g/cm3[3]
when liquid (at m.p.)10.65 g/cm3
Heat of fusion38.59 kJ/mol
Heat of vaporization619 kJ/mol
Molar heat capacity24.06 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 2588 2811 3087 3424 3845 4388
Atomic properties
Oxidation states−4, −2, 0, +1,[4][citation needed] +2, +3, +4, +5, +6, +7, +8 (a mildly acidic oxide)
ElectronegativityPauling scale: 2.2
Ionization energies
  • 1st: 710.2 kJ/mol
  • 2nd: 1620 kJ/mol
  • 3rd: 2747 kJ/mol
Atomic radiusempirical: 134 pm
Covalent radius146±7 pm
Color lines in a spectral range
Spectral lines of ruthenium
Other properties
Natural occurrenceprimordial
Crystal structure ​hexagonal close-packed (hcp) (hP2)
Lattice constants
Hexagonal close packed crystal structure for ruthenium
a = 270.58 pm
c = 428.16 pm (at 20 °C)[3]
Thermal expansion6.78×10−6/K (at 20 °C)[3][a]
Thermal conductivity117

αa 5.77 αc 8.80

αavr 6.78 W/(m⋅K)
Electrical resistivity71 nΩ⋅m (at 0 °C)
Magnetic orderingparamagnetic[5]
Molar magnetic susceptibility+39×10−6 cm3/mol (298 K)[5]
Young's modulus447 GPa
Shear modulus173 GPa
Bulk modulus220 GPa
Speed of sound thin rod5970 m/s (at 20 °C)
Poisson ratio0.30
Mohs hardness6.5
Brinell hardness2160 MPa
CAS Number7440-18-8
History
Namingafter Ruthenia, the 19th-century Latin name for Russia[b]
Discovery and first isolationKarl Ernst Claus (1844)
Isotopes of ruthenium
Main isotopes[8] Decay
abun­dance half-life (t1/2) mode pro­duct
96Ru 5.54% stable
97Ru synth 2.9 d ε 97Tc
γ
98Ru 1.87% stable
99Ru 12.8% stable
100Ru 12.6% stable
101Ru 17.1% stable
102Ru 31.6% stable
103Ru synth 39.26 d β 103Rh
γ
104Ru 18.6% stable
106Ru synth 373.59 d β 106Rh
Ruthenium Category: Ruthenium
| references

Ruthenium is a chemical element; it has symbol Ru and atomic number 44. It is a rare transition metal belonging to the platinum group of the periodic table. Like the other metals of the platinum group, ruthenium is unreactive to most other chemicals. Karl Ernst Claus, a Russian-born scientist of Baltic-German ancestry, discovered the element in 1844 at Kazan State University and named ruthenium in honor of Russia.[b] Ruthenium is usually found as a minor component of platinum ores; the annual production has risen from about 19 tonnes in 2009[9] to some 35.5 tonnes in 2017.[10] Most ruthenium produced is used in wear-resistant electrical contacts and thick-film resistors. A minor application for ruthenium is in platinum alloys and as a chemistry catalyst. A new application of ruthenium is as the capping layer for extreme ultraviolet photomasks. Ruthenium is generally found in ores with the other platinum group metals in the Ural Mountains and in North and South America. Small but commercially important quantities are also found in pentlandite extracted from Sudbury, Ontario, and in pyroxenite deposits in South Africa.[11]

  1. ^ "Standard Atomic Weights: Ruthenium". CIAAW. 1983.
  2. ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (4 May 2022). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  3. ^ a b c d Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
  4. ^ "Ruthenium: ruthenium(I) fluoride compound data". OpenMOPAC.net. Retrieved 10 December 2007.
  5. ^ a b Haynes, p. 4.130
  6. ^ Matthey, Johnson. "The Discovery of Ruthenium". Johnson Matthey Technology Review. Retrieved 25 August 2020.
  7. ^ Pitchkov, V. N. (1996). "The Discovery of Ruthenium". Platinum Metals Review. 40 (4): 181–188.
  8. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  9. ^ Summary. Ruthenium. platinum.matthey.com, p. 9 (2009)
  10. ^ PGM Market Report. platinum.matthey.com, p. 30 (May 2018)
  11. ^ Haynes (2016), p. 4.31.


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Ruthenium oxide may refer to either of the following: Ruthenium(IV) oxide, RuO2 Ruthenium(VIII) oxide, RuO4 This set index article lists chemical compounds...

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Ruthenium tetroxide

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Ruthenium tetroxide is the inorganic compound with the formula RuO4. It is a yellow volatile solid that melts near room temperature. It has the odor of...

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the ruthenium particles, the ruthenium precursor and the amount of ruthenium used. The reinforcing effect of the basic carrier used in the ruthenium catalyst...

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several ruthenium chlorides: Ruthenium(II) chloride, a brown salt Ruthenium(III) chloride, a black salt and the most common ruthenium chloride Ruthenium tetrachloride...

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Synthesis of precious metals

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nuclear reactors or particle accelerators to produce these elements. Ruthenium and rhodium are precious metals produced as a small percentage of the...

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Ruthenium pentafluoride is the inorganic compound with the empirical formula RuF5. This green volatile solid has rarely been studied but is of interest...

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Ruthenium pentacarbonyl is the organoruthenium compound with the formula Ru(CO)5. It is a colorless, light-sensitive liquid that readily decarbonylates...

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Ruthenium compounds are compounds containing the element ruthenium (Ru). Ruthenium compounds can have oxidation states ranging from 0 to +8, and −2. The...

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ammoniated ruthenium oxychloride, also known as ruthenium red, is used in histology to stain aldehyde fixed mucopolysaccharides. Ruthenium red (RR) has...

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of chemical elements in the periodic table. It consists of iron (Fe), ruthenium (Ru), osmium (Os) and hassium (Hs). "Group 8" is the modern standard designation...

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