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Osmium information


Osmium, 76Os
Osmium
Pronunciation/ˈɒzmiəm/ (OZ-mee-əm)
Appearancesilvery, blue cast
Standard atomic weight Ar°(Os)
  • 190.23±0.03[1]
  • 190.23±0.03 (abridged)[2]
Osmium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Ru

Os

Hs
rhenium ← osmium → iridium
Atomic number (Z)76
Groupgroup 8
Periodperiod 6
Block  d-block
Electron configuration[Xe] 4f14 5d6 6s2
Electrons per shell2, 8, 18, 32, 14, 2
Physical properties
Phase at STPsolid
Melting point3306 K ​(3033 °C, ​5491 °F)[3]
Boiling point5281 K ​(5008 °C, ​9046 °F)[4]
Density (at 20° C)22.587 g/cm3[5]
when liquid (at m.p.)20 g/cm3
Heat of fusion31 kJ/mol
Heat of vaporization378 kJ/mol
Molar heat capacity24.7 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 3160 3423 3751 4148 4638 5256
Atomic properties
Oxidation states−4, −2, −1, 0, +1, +2, +3, +4, +5, +6, +7, +8 (a mildly acidic oxide)
ElectronegativityPauling scale: 2.2
Ionization energies
  • 1st: 840 kJ/mol
  • 2nd: 1600 kJ/mol
Atomic radiusempirical: 135 pm
Covalent radius144±4 pm
Color lines in a spectral range
Spectral lines of osmium
Other properties
Natural occurrenceprimordial
Crystal structure ​hexagonal close-packed (hcp) (hP2)
Lattice constants
Hexagonal close packed crystal structure for osmium
a = 273.42 pm
c = 431.99 pm (at 20 °C)[6]
Thermal expansion4.99×10−6/K (at 20 °C)[a]
Thermal conductivity87.6 W/(m⋅K)
Electrical resistivity81.2 nΩ⋅m (at 0 °C)
Magnetic orderingparamagnetic[7]
Molar magnetic susceptibility11×10−6 cm3/mol[7]
Shear modulus222 GPa
Bulk modulus462 GPa
Speed of sound thin rod4940 m/s (at 20 °C)
Poisson ratio0.25
Mohs hardness7.0
Vickers hardness4137 MPa
Brinell hardness3920 MPa
CAS Number7440-04-2
History
Discovery and first isolationSmithson Tennant (1803)
Isotopes of osmium
Main isotopes[8] Decay
abun­dance half-life (t1/2) mode pro­duct
184Os 0.02% 1.12×1013 y[9] α 180W
185Os synth 92.95 d ε 185Re
186Os 1.59% 2.0×1015 y α 182W
187Os 1.96% stable
188Os 13.2% stable
189Os 16.1% stable
190Os 26.3% stable
191Os synth 14.99 d β 191Ir
192Os 40.8% stable
193Os synth 29.83 h β 193Ir
194Os synth 6 y β 194Ir
Osmium Category: Osmium
| references

Osmium (from Ancient Greek ὀσμή (osmḗ) 'smell') is a chemical element; it has symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition metal in the platinum group that is found as a trace element in alloys, mostly in platinum ores. Osmium is the densest naturally occurring element. When experimentally measured using X-ray crystallography, it has a density of 22.59 g/cm3.[10] Manufacturers use its alloys with platinum, iridium, and other platinum-group metals to make fountain pen nib tipping, electrical contacts, and in other applications that require extreme durability and hardness.[11]

Osmium is among the rarest elements in the Earth's crust, making up only 50 parts per trillion (ppt).[12][13]

  1. ^ "Standard Atomic Weights: Osmium". CIAAW. 1991.
  2. ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (May 4, 2022). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  3. ^ Rumble, John R.; Bruno, Thomas J.; Doa, Maria J. (2022). "Section 4: Properties of the Elements and Inorganic Compounds". CRC Handbook of Chemistry and Physics: A Ready Reference Book of Chemical and Physical Data (103rd ed.). Boca Raton, FL: CRC Press. p. 40. ISBN 978-1-032-12171-0.
  4. ^ Rumble, John R.; Bruno, Thomas J.; Doa, Maria J. (2022). "Section 4: Properties of the Elements and Inorganic Compounds". CRC Handbook of Chemistry and Physics: A Ready Reference Book of Chemical and Physical Data (103rd ed.). Boca Raton, FL: CRC Press. p. 40. ISBN 978-1-032-12171-0.
  5. ^ Rumble, John R.; Bruno, Thomas J.; Doa, Maria J. (2022). "Section 4: Properties of the Elements and Inorganic Compounds". CRC Handbook of Chemistry and Physics: A Ready Reference Book of Chemical and Physical Data (103rd ed.). Boca Raton, FL: CRC Press. p. 40. ISBN 978-1-032-12171-0.
  6. ^ Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
  7. ^ a b Haynes 2011, p. 4.134.
  8. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  9. ^ Peters, Stefan T.M.; Münker, Carsten; Becker, Harry; Schulz, Toni (April 2014). "Alpha-decay of 184Os revealed by radiogenic 180W in meteorites: Half life determination and viability as geochronometer". Earth and Planetary Science Letters. 391: 69–76. doi:10.1016/j.epsl.2014.01.030.
  10. ^ Cite error: The named reference Arblaster1995 was invoked but never defined (see the help page).
  11. ^ Haynes 2011, p. 4.25.
  12. ^ Fleischer, Michael (1953). "Recent estimates of the abundances of the elements in the Earth's crust" (PDF). U.S. Geological Survey. Archived (PDF) from the original on October 23, 2022. Retrieved May 10, 2018.
  13. ^ "Reading: Abundance of Elements in Earth's Crust | Geology". courses.lumenlearning.com. Archived from the original on May 17, 2022. Retrieved May 10, 2018.


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Osmium

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Osmium (from Ancient Greek ὀσμή (osmḗ) 'smell') is a chemical element; it has symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition...

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Osmium tetroxide

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Osmium tetroxide (also osmium(VIII) oxide) is the chemical compound with the formula OsO4. The compound is noteworthy for its many uses, despite its toxicity...

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Isotopes of osmium

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Osmium (76Os) has seven naturally occurring isotopes, five of which are stable: 187Os, 188Os, 189Os, 190Os, and (most abundant) 192Os. The other natural...

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Osmium diphosphide

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Osmium diphosphide is a binary inorganic compound of osmium metal and phosphorus with the chemical formula OsP2. Osmium diphosphide can be obtained by...

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Osmium hexafluoride

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Osmium hexafluoride, also osmium(VI) fluoride, (OsF6) is a compound of osmium and fluorine, and one of the seventeen known binary hexafluorides. Osmium...

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Osmium fluoride

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Osmium fluoride may refer to: Osmium(IV) fluoride (osmium tetrafluoride), OsF4 Osmium(V) fluoride (osmium pentafluoride), OsF5 Osmium(VI) fluoride (osmium...

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Osmium bromide

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Osmium bromide may refer to: Osmium(IV) bromide (osmium tetrabromide), OsBr4 Osmium(III) bromide (osmium tribromide), OsBr3 This set index article lists...

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Hassium

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experiments have confirmed that hassium behaves as the heavier homologue to osmium, reacting readily with oxygen to form a volatile tetroxide. The chemical...

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Osmium tetrasulfide

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Osmium tetrasulfide is an inorganic compound, a salt of osmium metal and hydrogen sulfide acid with the chemical formula OsS4. Osmium tetrasulfide can...

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Osmium pentacarbonyl

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Osmium pentacarbonyl is the organoosmium compound with the formula Os(CO)5. It is the simplest isolatable carbonyl complex of osmium. Osmium pentacarbonyl...

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Osmium oxide

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Osmium oxide may refer to: Osmium dioxide, OsO2 Osmium tetroxide, OsO4 This set index article lists chemical compounds articles associated with the same...

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Iridium

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group, it is considered the second-densest naturally occurring metal (after osmium) with a density of 22.56 g/cm3 (0.815 lb/cu in) as defined by experimental...

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Osmium heptafluoride

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Osmium heptafluoride is an inorganic chemical compound of osmium metal and fluorine with the chemical formula OsF 7. It was first reported in 1966 by the...

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Osmium pentafluoride

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Osmium pentafluoride is an inorganic compound with the formula OsF5. It is a blue-green solid. Like the pentafluorides of Ru, Rh, and Ir, OsF5 exists as...

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Osmium octafluoride

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Osmium octafluoride is an inorganic chemical compound of osmium metal and fluorine with the chemical formula OsF8. Some sources consider it to be a still...

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Osmium dioxide

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Osmium dioxide is an inorganic compound with the formula OsO2. It exists as brown to black crystalline powder, but single crystals are golden and exhibit...

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Group 8 element

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elements in the periodic table. It consists of iron (Fe), ruthenium (Ru), osmium (Os) and hassium (Hs). "Group 8" is the modern standard designation for...

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Osmium iodides

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Osmium iodide refers to compounds of osmium with the formula OsIn. Several have been mentioned in the literature, but only the triiodide has been verified...

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Staining

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solution. Osmium tetraoxide is used in optical microscopy to stain lipids. It dissolves in fats, and is reduced by organic materials to elemental osmium, an...

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Platinum group

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and 6). The six platinum-group metals are ruthenium, rhodium, palladium, osmium, iridium, and platinum. They have similar physical and chemical properties...

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Tetramesityl compounds

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high toxicity of OsO4 and the presence of monooxo(tetraaryl)osmium(vi) and bisoxo(diaryl)osmium(vi) side products add extra complications to the purification...

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Osmium compounds

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Osmium compounds are compounds containing the element osmium (Os). Osmium forms compounds with oxidation states ranging from −2 to +8. The most common...

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