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Bismuth pentafluoride information


Bismuth pentafluoride
Names
Other names
bismuth(V) fluoride
Identifiers
CAS Number
  • 7787-62-4 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:30426 checkY
ChemSpider
  • 21172752
ECHA InfoCard 100.029.205 Edit this at Wikidata
PubChem CID
  • 123260
UNII
  • BX273GFK98 checkY
CompTox Dashboard (EPA)
  • DTXSID10228490 Edit this at Wikidata
InChI
  • InChI=1/Bi.5FH.3H/h;5*1H;;;/q+3;;;;;;;;/p-5/rBiH3.5FH/h1H3;5*1H/q+3;;;;;/p-5
    Key: MELFHUKMGVSOTN-COTDSHSIAY
SMILES
  • F[Bi](F)(F)(F)F
Properties
Chemical formula
BiF5
Molar mass 303.97 g mol−1
Appearance long white needles,[1] colourless crystalline solid[2]
Density 5.40 g cm−3[1]
Melting point 151.4 °C (304.5 °F; 424.5 K) ,[2] 154.4 °C[1]
Boiling point 230 °C (446 °F; 503 K)[1][2]
Structure
Coordination geometry
octahedral Bi
Hazards
GHS labelling:
Pictograms
GHS03: Oxidizing GHS05: Corrosive
Signal word
Danger
Hazard statements
H272, H314
Precautionary statements
P210, P220, P221, P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P370+P378, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 0: Will not burn. E.g. waterInstability 3: Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked. E.g. hydrogen peroxideSpecial hazard W+OX: Reacts with water in an unusual or dangerous manner AND is oxidizer
4
0
3
W
OX
Flash point non-combustible
Safety data sheet (SDS) MSDS
Related compounds
Other anions
bismuth trichloride, bismuth tribromide, bismuth triiodide, pentamethylbismuth
Other cations
phosphorus pentafluoride, arsenic pentafluoride, antimony pentafluoride
Related compounds
bismuth trifluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Bismuth pentafluoride is an inorganic compound with the formula BiF5. It is a white solid that is highly reactive. The compound is of interest to researchers but not of particular value.

  1. ^ a b c d Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 561–563. ISBN 978-0-08-037941-8.
  2. ^ a b c Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.), Inorganic Chemistry, translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter, pp. 769–770, ISBN 0-12-352651-5

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Bismuth pentafluoride

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Bismuth pentafluoride is an inorganic compound with the formula BiF5. It is a white solid that is highly reactive. The compound is of interest to researchers...

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Pentafluoride

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Pentafluoride may refer to: Antimony pentafluoride, SbF5 Arsenic pentafluoride, AsF5 Bismuth pentafluoride, BiF5 Bromine pentafluoride, BrF5 Chlorine pentafluoride...

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Arsenic pentafluoride

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Arsenic pentafluoride is a chemical compound of arsenic and fluorine. It is a toxic, colorless gas. The oxidation state of arsenic is +5. Arsenic pentafluoride...

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Antimony pentafluoride

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Antimony pentafluoride is the inorganic compound with the formula SbF5. This colourless, viscous liquid is a strong Lewis acid and a component of the...

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List of inorganic compounds

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oxide – Bi2O3 Bismuth oxychloride – BiOCl Bismuth pentafluoride – BiF5 Bismuth(III) sulfide– Bi2S3 Bismuth(III) telluride – Bi2Te3 Bismuth(III) telluride...

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Phosphorus pentafluoride

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Phosphorus pentafluoride, PF5, is a phosphorus halide. It is a colourless, toxic gas that fumes in air. Phosphorus pentafluoride was first prepared in...

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Nitrogen pentafluoride

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Nitrogen pentafluoride (NF5) is a theoretical compound of nitrogen and fluorine that is hypothesized to exist based on the existence of the pentafluorides of...

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Fluorine

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basic. The pentafluorides of phosphorus, arsenic, and antimony are more reactive than their respective trifluorides, with antimony pentafluoride the strongest...

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Bismuth fluoride

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Bismuth fluoride may refer to: Bismuth trifluoride, BiF3 Bismuth pentafluoride, BiF5 This set index article lists chemical compounds articles associated...

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Xenon tetrafluoride

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reaction with cesium fluoride: CsF + XeF 4 → CsXeF 5 Reaction with bismuth pentafluoride (BiF 5) forms the XeF+ 3 cation: BiF 5 + XeF 4 → XeF3BiF6 The XeF+...

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Pnictogen

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chemically. This causes bismuth(V) oxide to be unstable and bismuth(V) fluoride to be more reactive than the other pnictogen pentafluorides, making it an extremely...

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Fluorine compounds

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room-temperature (alpha) form has the same linear chain structure as bismuth pentafluoride. As a molecular (gas) species, UF5 has a square pyramidal structure...

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Iodine

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fluorinating agent, behind only chlorine trifluoride, chlorine pentafluoride, and bromine pentafluoride among the interhalogens: it reacts with almost all the...

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Nuclear reprocessing

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products. The first method selected, a precipitation process called the bismuth phosphate process, was developed and tested at the Oak Ridge National Laboratory...

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Arsenic compounds

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arsenic(III) are well known except the astatide, which is unknown. Arsenic pentafluoride (AsF5) is the only important pentahalide, reflecting the lower stability...

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Nitrogen

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tetrafluorohydrazine with strong fluoride-acceptors such as arsenic pentafluoride), as is ONF3, which has aroused interest due to the short N–O distance...

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Chlorine

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stoichiometric reactions have been characterised. Arsenic pentafluoride and antimony pentafluoride form ionic adducts of the form [ClF4]+[MF6]− (M = As, Sb)...

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Bromine

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forms a monofluoride and monochloride, as well as a trifluoride and pentafluoride. Some cationic and anionic derivatives are also characterised, such...

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Bromine compounds

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forms a monofluoride and monochloride, as well as a trifluoride and pentafluoride. Some cationic and anionic derivatives are also characterised, such...

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Iodine compounds

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fluorinating agent, behind only chlorine trifluoride, chlorine pentafluoride, and bromine pentafluoride among the interhalogens: it reacts with almost all the...

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Nihonium

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of the nihonium trifluoride and pentafluoride molecules are the same as those for chlorine trifluoride and pentafluoride. The chemical characteristics of...

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Nitrogen trifluoride

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tetrafluorohydrazine: 2NF3 + Cu → N2F4 + CuF2 NF3 reacts with fluorine and antimony pentafluoride to give the tetrafluoroammonium salt: NF3 + F2 + SbF5 → NF+ 4SbF− 6...

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List of CAS numbers by chemical compound

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pentachloride 22441–45–8 AsF3 arsenic trifluoride 7784–35–2 AsF5 arsenic pentafluoride 7784–36–3 AsH3 arsenic trihydride 7784–42–1 AsI3 arsenic triiodide 7784–45–4...

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Nonmetal

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period 2 onward, in compounds such as nitric acid HN(V)O3 and phosphorus pentafluoride PCl5. Higher oxidation states in later groups emerge from period 3 onwards...

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Protactinium

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can be prepared by reacting protactinium oxide with either bromine pentafluoride or bromine trifluoride at about 600 °C, and protactinium(IV) fluoride...

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Arsenic

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more well-known phosphorus compounds, and in fluorine to give arsenic pentafluoride. Arsenic makes arsenic acid with concentrated nitric acid, arsenous...

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Ruthenium

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mixture of lower ruthenium fluorides, releasing fluorine gas. Ruthenium pentafluoride is a tetrameric dark green solid that is also readily hydrolyzed, melting...

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Philipp Gross

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P; Hayman, C; Stuart, M C (1966). "Heat of formation of phosphorus pentafluoride". Trans Faraday Soc. 62: 2716–8. doi:10.1039/tf9666202716. "AWARD TO...

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Glossary of chemical formulae

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iodine pentafluoride 7783-66-6 F5Mo molybdenum pentafluoride 13819-84-6 F5ORe rhenium monoxide pentafluoride 23377-53-9 F5P phosphorus pentafluoride 7647-19-0...

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Iridium

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halogens. For oxidation states +4 and above, only the tetrafluoride, pentafluoride and hexafluoride are known. Iridium hexafluoride, IrF 6, is a volatile...

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