Chemical complexes containing one or more –NO₂ ligands
Sodium cobaltinitrite is a salt of the coordination complex [Co(NO2)6]3−.[1]
In organometallic chemistry, transition metal complexes of nitrite describes families of coordination complexes containing one or more nitrite (−NO2) ligands.[2] Although the synthetic derivatives are only of scholarly interest, metal-nitrite complexes occur in several enzymes that participate in the nitrogen cycle.[3]
^Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
^Hitchman, Michael A.; Rowbottom, Graham L. (1982). "Transition Metal Nitrite Complexes". Coordination Chemistry Reviews. 42: 55–132. doi:10.1016/S0010-8545(00)80527-5.
^Cite error: The named reference Symes was invoked but never defined (see the help page).
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organometallic chemistry, transitionmetalcomplexes of nitrite describes families of coordination complexes containing one or more nitrite (−NO2) ligands. Although...
Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transitionmetal. Many kinds of nitrosyl complexes are known, which vary...
turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transitionmetals (elements like titanium that...
A transitionmetal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the...
reactions. Nitrite can enter two kinds of reaction, depending on the physico-chemical environment. Nitrosylation is adding a nitrosyl ion NO− to a metal (e.g...
Alternatively similar borylation can be achieved using transitionmetal carbonyl complexes including dimanganese decacarbonyl. [C6H5N2]+X− + pinB−Bpin...
strong acids: H+ + N−3 → HN3 Azide as a ligand forms numerous transitionmetal azide complexes. Some such compound are more shock sensitive. Many inorganic...
A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite and nitrate anions (NO3− and NO2−)...
temperature, but it will nevertheless react with lithium metal and some transitionmetalcomplexes. This is due to its bonding, which is unique among the...
stress cracking Transitionmetal chloride complexTransitionmetal thiosulfate complex Frankel, G. S. (1998-06-01). "Pitting corrosion of metals: A review of...
functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one...
com/MEMCyanideTreatment.pdf Sharpe, A. G. The Chemistry of Cyano Complexes of the TransitionMetals; Academic Press: London, 1976[page needed] Holleman, A. F...
N-methoxydiazeniumdiolate. Nitric oxide reacts with transitionmetals to give complexes called metal nitrosyls. The most common bonding mode of nitric oxide...
than side-on (η2) donation. Today, dinitrogen complexes are known for almost all the transitionmetals, accounting for several hundred compounds. They...
stump. In heat treatment of metals as a medium temperature molten salt bath, usually in combination with sodium nitrite. A similar bath is used to produce...
NaCl is sodium chloride, and CaF2 is calcium fluoride. Cations of transitionmetals able to take multiple charges are labeled with Roman numerals in parentheses...
anhydrous transitionmetal nitrate complexes can be prepared from N2O4 and base metal. 2 N2O4 + M → 2 NO + M(NO3)2 where M = Cu, Zn, or Sn. If metal nitrates...
(2019). "Unevolved De Novo Proteins Have Innate Tendencies to Bind TransitionMetals". Life. 9 (8): 8. doi:10.3390/life9010008. PMC 6463171. PMID 30634485...
so in transitionmetal chemistry, where numerous experiments have been done to determine the relative ordering of ligands and transitionmetal ions in...
Example for Type-I blue copper protein are plastocyanine , azurin, and nitrite reductase, haemocyanin and tyrosinase. The Blue Copper Proteins, a class...
homoleptic complex tetrakis(1-norbornyl)cobalt(IV) (Co(1-norb)4), a transitionmetal-alkyl complex that is notable for its resistance to β-hydrogen elimination...
Kovalevsky A (2002). "Photoinduced Linkage Isomers of Transition-Metal Nitrosyl Compounds and Related Complexes". Chemical Reviews. 102 (4): 861–883. doi:10.1021/cr000031c...
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