Complex of a transition metal bonded to nitric oxide: Me–NO
Not to be confused with Nitro compound.
Sodium nitroprusside, a medicinally significant metal nitrosyl-pentacyanoferrate (Fe-III) compound, used to treat hypertension.[1]
Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transition metal.[2] Many kinds of nitrosyl complexes are known, which vary both in structure and coligand.
^"Sodium Nitroprusside". www.drugs.com. The American Society of Health-System Pharmacists. Retrieved 21 October 2022.
^Hayton, T. W.; Legzdins, P.; Sharp, W. B. (2002). "Coordination and Organometallic Chemistry of Metal-NO Complexes". Chem. Rev. 102 (1): 935–991. doi:10.1021/cr000074t. PMID 11942784.
and 29 Related for: Metal nitrosyl complex information
Metalnitrosylcomplexes are complexes that contain nitric oxide, NO, bonded to a transition metal. Many kinds of nitrosylcomplexes are known, which vary...
Nitric oxide can serve as a ligand forming metalnitrosylcomplexes or just metalnitrosyls. These complexes can be viewed as adducts of NO+, NO−, or some...
turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that...
form homoleptic and mixed ligand complexes that are analogous to the metal carbonyls.[citation needed] Metalnitrosyls, compounds featuring NO ligands...
nitrito complexes by base-hydrolysis of electrophilic metalnitrosyls. Nitro complexes also catalyze the oxidation of alkenes. Metal nitrito complexes figure...
Metal nitrido complexes are coordination compounds and metal clusters that contain an atom of nitrogen bound only to transition metals. These compounds...
chloride is used to prepare metalnitrosylcomplexes. With molybdenum hexacarbonyl, NOCl gives the dinitrosyldichloride complex: Mo(CO)6 + 2 NOCl → MoCl2(NO)2...
In coordination chemistry, metal ammine complexes are metalcomplexes containing at least one ammonia (NH3) ligand. "Ammine" is spelled this way for historical...
NOBF4 reacts with some metal carbonyl complexes to yield related metalnitrosylcomplexes. In some cases, [NO]+ does not bind the metal nucleophile but acts...
N-methoxydiazeniumdiolate. Nitric oxide reacts with transition metals to give complexes called metalnitrosyls. The most common bonding mode of nitric oxide is the...
The related pentamethylcyclopentadienyl complex (C5(CH3)5)NiNO is also known. Cyclopentadienyl nickel nitrosyl was the subject of several patents as a...
part of cell signalling. Coordination of NO to transition metals to give metalnitrosylcomplexes is also referred to as nitrosylation. Nitrosation Mannick...
(2002). "Photoinduced Linkage Isomers of Transition-MetalNitrosyl Compounds and Related Complexes". Chemical Reviews. 102 (4): 861–883. doi:10.1021/cr000031c...
redox reaction of nitrosonium and the metal can give rise to nitrogen oxide which forms strong metalnitrosylcomplexes; nitronium ions (NO2+) are similarly...
wide variety of coordination complexes by binding to metal ions in several ways. Two examples are the red nitrito complex [Co(NH3)5(ONO)]2+ is metastable...
dioxide and with halogens to give nitrosyl halides. It also reacts with transition metal compounds to give nitrosylcomplexes, most of which are deeply coloured...
nitrosyl chloride and nitrogen dioxide. It was named by alchemists because it can dissolve noble metals like gold and platinum, though not all metals...
SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metalnitrosylcomplexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...
PETN—"around 50 times less than was used—would be enough to blast a hole in a metal plate twice the thickness of an aircraft's skin". In contrast, according...
SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metalnitrosylcomplexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...
SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metalnitrosylcomplexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...
classes of protein. Nitric oxide to a transition metal ion like iron or copper, forming metalnitrosylcomplexes. Typical cases involve the nitrosylation of...
the reaction of nitrous acid (HNO2) and secondary amines, although other nitrosyl sources (e.g. N 2O 4, NOCl, RONO) have the same effect: HONO + R2NH → R2N-NO...
Transition metal sulfate complexes or sulfato complexes are coordination complexes with one or more sulfate ligands. Sulfate binds to metals through one...
thiolate ligands are cysteinyl residues or glutathione. These metalnitrosylcomplexes have attracted much attention because they serve as biochemical...
Nitrosonium tetrafluoroborate, also called nitrosyl tetrafluoroborate, is a chemical compound with the chemical formula NOBF4. This colourless solid is...
can be used to oxidize several transition metal and main group element complexes. The first metalnitrosyl cation was prepared using the PFAA's [Al(Opftb)4]−...
nitroxyl and the chloride ion. Alkali metals react with nitric oxide to give salts of the form MNO (M = metal). However, generation of the (unstable)...
gastric upset, such as diarrheal infection, protein intolerance, heavy metal toxicity, etc. Through the Safe Drinking Water Act, the United States Environmental...
Global Information