Transition metal amino acid complexes are a large family of coordination complexes containing the conjugate bases of the amino acids, the 2-aminocarboxylates. Amino acids are prevalent in nature, and all of them function as ligands toward the transition metals.[1] Not included in this article are complexes of the amides (including peptide) and ester derivatives of amino acids. Also excluded are the polyamino acids including the chelating agents EDTA and NTA.
^Severin, K.; Bergs, R.; Beck, W. (1998). "Bioorganometallic Chemistry-Transition Metal Complexes with α-Amino Acids and Peptides". Angew. Chem. Int. Ed. 37 (12): 1635–1654. doi:10.1002/(SICI)1521-3773(19980703)37:12<1634::AID-ANIE1634>3.0.CO;2-C. PMID 29711516.
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Transitionmetalaminoacidcomplexes are a large family of coordination complexes containing the conjugate bases of the aminoacids, the 2-aminocarboxylates...
A transitionmetal imidazole complex is a coordination complex that has one or more imidazole ligands. Complexes of imidazole itself are of little practical...
Transitionmetal carboxylate complexes are coordination complexes with carboxylate (RCO2−) ligands. Reflecting the diversity of carboxylic acids, the inventory...
atom are common. These complexes are called chelate complexes; the formation of such complexes is called chelation, complexation, and coordination. The...
Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transitionmetal. Many kinds of nitrosyl complexes are known, which vary...
Transitionmetal hydrides are chemical compounds containing a transitionmetal bonded to hydrogen. Most transitionmetals form hydride complexes and some...
or the citric acid cycle, as detailed in image at right. Aminoacids are bidentate ligands, forming transitionmetalaminoacidcomplexes. The total nitrogen...
Metal carbonyls are coordination complexes of transitionmetals with carbon monoxide ligands. Metal carbonyls are useful in organic synthesis and as catalysts...
other organic products, e.g. hydrogenation and trimerization. Transitionmetal alkyne complexes are often formed by the displacement of labile ligands by...
Transitionmetal nitrile complexes are coordination compounds containing nitrile ligands. Because nitriles are weakly basic, the nitrile ligands in these...
Transitionmetal acyl complexes describes organometallic complexes containing one or more acyl (RCO) ligands. Such compounds occur as transient intermediates...
A transitionmetal alkoxide complex is a kind of coordination complex containing one or more alkoxide ligands, written as RO−, where R is the organic...
Transitionmetal carbyne complexes are organometallic compounds with a triple bond between carbon and the transitionmetal. This triple bond consists of...
on transitionmetals are able to reinforce π-backbonding onto a π-acid. They are also known to labilize cis-ligands. Homoleptic complexes (complexes with...
A transitionmetal carbene complex is an organometallic compound featuring a divalent carbon ligand, itself also called a carbene. Carbene complexes have...
complexes. Cationic alkene complexes are susceptible to attack by nucleophiles. Metal alkene complexes are intermediates in many or most transition metal...
of complex: compounds formed by the interaction of a metal ion with a ligand and supramolecular complexes, such as host–guest complexes and complexes of...
Transitionmetalcomplexes of phosphine oxides are coordination complex containing one or more phosphine oxide ligands. Many phosphine oxides exist and...
Peptides are short chains of aminoacids linked by peptide bonds. A polypeptide is a longer, continuous, unbranched peptide chain. Polypeptides that have...
A transitionmetal oxo complex is a coordination complex containing an oxo ligand. Formally O2-, an oxo ligand can be bound to one or more metal centers...
In coordination chemistry, metal ammine complexes are metalcomplexes containing at least one ammonia (NH3) ligand. "Ammine" is spelled this way for historical...
A transitionmetal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the...
Transitionmetalcomplexes of thiocyanate describes coordination complexes containing one or more thiocyanate (SCN-) ligands. The topic also includes transition...
Transitionmetal phosphate complexes are coordination complexes with one or more phosphate ligands. Phosphate binds to metals through one, two, three...
important biological macromolecules include: proteins, which are composed of aminoacid monomers joined via peptide bonds, and DNA molecules, which are composed...
Transitionmetal dithiocarbamate complexes are coordination complexes containing one or more dithiocarbamate ligand, which are typically abbreviated R2dtc−...
Transitionmetal thioether complexes comprise coordination complexes of thioether (R2S) ligands. The inventory is extensive. As the simplest thioether...
Transitionmetal pyridine complexes encompass many coordination complexes that contain pyridine as a ligand. Most examples are mixed-ligand complexes...
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