Structure of the methoxide anion. Although alkali metal alkoxides are not salts and adopt complex structures, they behave chemically as sources of RO−.
A transition metal alkoxide complex is a kind of coordination complex containing one or more alkoxide ligands, written as RO−, where R is the organic substituent.[citation needed] Metal alkoxides are used for coatings and as catalysts.[1][2]
^Bradley, Don C.; Mehrotra, Ram C.; Rothwell, Ian P.; Singh, A. (2001). Alkoxo and Aryloxo Derivatives of Metals. San Diego: Academic Press. ISBN 978-0-08-048832-5.
^Turova, Nataliya Y.; Turevskaya, Evgeniya P.; Kessler, Vadim G.; Yanovskaya, Maria I. (2002). The Chemistry of Metal Alkoxides. Dordrecht: Kluwer Academic Publishers. ISBN 9780792375210.
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Williamson ether synthesis. Transitionmetalalkoxides are widely used for coatings and as catalysts. Enolates are unsaturated alkoxides derived by deprotonation...
Metal carbonyls are coordination complexes of transitionmetals with carbon monoxide ligands. Metal carbonyls are useful in organic synthesis and as catalysts...
These complexes are usually prepared by the reaction of H2salen ("proligand") with metal precursors containing built-in bases, such as alkoxides, metal amides...
compound" refers to metal-containing compounds lacking direct metal-carbon bonds but which contain organic ligands. Metal β-diketonates, alkoxides, dialkylamides...
ligands for metal ions, forming complexes similar to metalalkoxides. Sodium trimethylsiloxide is useful for generating metalcomplexes by salt metathesis...
more relaxed to include also highly lipophilic complexes such as metal carbonyls and even metalalkoxides. Organometallic compounds are mainly considered...
ethers, generating alkoxides. Unlike alkyllithium compounds, alkylsodiums and alkylpotassiums cannot be made by reacting the metals with alkyl halides...
hfpp salt and can be used to oxidize several transitionmetal and main group element complexes. The first metal nitrosyl cation was prepared using the PFAA's...
the alkoxide generates a carboxylic acid: The alkoxide ion is a strong base so the proton is transferred from the carboxylic acid to the alkoxide ion...
involves treatment of a parent alcohol with a strong base to form the alkoxide, followed by addition of an appropriate aliphatic compound bearing a suitable...
the hydroxide group. The hydroxides of the transitionmetals and post-transitionmetals usually have the metal in the +2 (M = Mn, Fe, Co, Ni, Cu, Zn) or...
case of 2° haloalkanes is relatively complex. For strongly basic nucleophiles (pKaH > 11, e.g., hydroxide, alkoxide, acetylide), the result is generally...
(BR3) and alkoxide (−OR); this species could be considered as being more nucleophilic and then more reactive towards the palladium complex present in...
migratory insertion is a type of reaction wherein two ligands on a metalcomplex combine. It is a subset of reactions that very closely resembles the...
planar low-spin d8 transitionmetalcomplexes. These complexes exist as square planar complexes due to the directionality of the metal center's d orbitals...
TiCl4 to give alkoxides with the formula [Ti(OR)4]n (R = alkyl, n = 1, 2, 4). As indicated by their formula, these alkoxides can adopt complex structures...
Titanium butoxide is a metalalkoxide with the formula Ti(OBu)4 (Bu = –CH2CH2CH2CH3). It is a colorless odorless liquid although aged samples can appear...
the aromatic protons more acidic, and ready for ortho-metalation. Addition of potassium alkoxide to alkyllithium greatly increases the basicity of organolithium...
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