Structure of [Ru(NH3)5py]2+, illustrating the steric avoidance of the 2,6-protons and the cis ligands.[1]
Transition metal pyridine complexes encompass many coordination complexes that contain pyridine as a ligand. Most examples are mixed-ligand complexes. Many variants of pyridine are also known to coordinate to metal ions, such as the methylpyridines, quinolines, and more complex rings.
^Shin, Yeung-gyo K.; Szalda, David J.; Brunschwig, Bruce S.; Creutz, Carol; Sutin, Norman (1997). "Electronic and Molecular Structures of Pentaammineruthenium Pyridine and Benzonitrile Complexes as a Function of Oxidation State". Inorganic Chemistry. 36 (14): 3190–3197. doi:10.1021/ic9700967. PMID 11669976.
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other organic products, e.g. hydrogenation and trimerization. Transitionmetal alkyne complexes are often formed by the displacement of labile ligands by...
10–11 °C) is a mild reducing agent. Transitionmetalpyridinecomplexes are numerous. Typical octahedral complexes have the stoichiometry MCl2(py)4 and...
Metal carbonyls are coordination complexes of transitionmetals with carbon monoxide ligands. Metal carbonyls are useful in organic synthesis and as catalysts...
Transitionmetal nitrile complexes are coordination compounds containing nitrile ligands. Because nitriles are weakly basic, the nitrile ligands in these...
A transitionmetal fullerene complex is a coordination complex wherein fullerene serves as a ligand. Fullerenes are typically spheroidal carbon compounds...
In coordination chemistry, metal ammine complexes are metalcomplexes containing at least one ammonia (NH3) ligand. "Ammine" is spelled this way for historical...
Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transitionmetal. Many kinds of nitrosyl complexes are known, which vary...
Transitionmetalcomplexes of aldehydes and ketones describes coordination complexes with aldehyde (RCHO) and ketone (R2CO) ligands. Because aldehydes...
A transitionmetal oxo complex is a coordination complex containing an oxo ligand. Formally O2-, an oxo ligand can be bound to one or more metal centers...
A transitionmetal imidazole complex is a coordination complex that has one or more imidazole ligands. Complexes of imidazole itself are of little practical...
In chemistry, a transitionmetal pincer complex is a type of coordination complex with a pincer ligand. Pincer ligands are chelating agents that binds...
Transitionmetal porphyrin complexes are a family of coordination complexes of the conjugate base of porphyrins. Iron porphyrin complexes occur widely...
Metal acetylacetonates are coordination complexes derived from the acetylacetonate anion (CH 3COCHCOCH− 3) and metal ions, usually transitionmetals. The...
2016 (subscription required). Tomasik P. & Ratajewicz Z. 1985, Pyridinemetalcomplexes, vol. 14, no. 6A, The Chemistry of Heterocyclic Compounds, John...
dyestuff. Homoleptic cyanometallates are complexes where the only ligand is cyanide. For transitionmetals, well known homoleptic cyanometallates are...
forms complexes with most transitionmetal ion as do other polypyridine compounds, such as 2,2'-bipyridine and 1,10-phenanthroline. Complexes containing...
Fe-DIP complexes catalyze hydrogenation of terminal olefins. In N-heterocyclic carbene variations of the diiminopyridine complex, the pyridine or imine...
Like some other transitionmetal oxyfluorides, VO2F reacts with Lewis bases to give 1:2 adducts. One example is the yellow bis(pyridine) derivative VO2F(NC5H5)2...
compounds. Octahedral transition-metalcomplexes containing amines and simple anions are often referred to as Werner-type complexes. When two or more types...
octahedral complexes that are high spin. On the other hand, ligands lying at the right end are stronger ligands and form inner orbital octahedral complexes after...
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