Transition metal hydrides are chemical compounds containing a transition metal bonded to hydrogen. Most transition metals form hydride complexes and some are significant in various catalytic and synthetic reactions. The term "hydride" is used loosely: some of them are acidic (e.g., H2Fe(CO)4), whereas some others are hydridic, having H−-like character (e.g., ZnH2).
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Transitionmetalhydrides are chemical compounds containing a transitionmetal bonded to hydrogen. Most transitionmetals form hydride complexes and some...
bridging hydrides. Classical transitionmetalhydride feature a single bond between the hydrogen centre and the transitionmetal. Some transitionmetal hydrides...
Metal carbonyl hydrides are complexes of transitionmetals with carbon monoxide and hydride as ligands. These complexes are useful in organic synthesis...
Sodium hydride is the chemical compound with the empirical formula NaH. This alkali metalhydride is primarily used as a strong yet combustible base in...
compound with the formula H2Fe(CO)4. This compound was the first transitionmetalhydride discovered. The complex is stable at low temperatures but decomposes...
presence of a formal hydride ion, the oxidation state of cobalt in this compound is +1. But unlike some other transition-metalhydrides complexes, HCo(CO)4...
Lithium hydride is an inorganic compound with the formula LiH. This alkali metalhydride is a colorless solid, although commercial samples are grey. Characteristic...
oxyhydrides, hydride sulfides, and hydride tellurides. Salt-like hydride selenides may be formed by heating selenium with a metalhydride in an oxygen-free...
carbonyl hydride is used in the commercial production of many aldehyde-based fragrances. Zeise's salt is an example of a transitionmetal alkene complex...
Palladium hydride is palladium metal with hydrogen within its crystal lattice. Despite its name, it is not an ionic hydride but rather an alloy of palladium...
saline hydride, meaning that its structure is salt-like. The alkali metals and the alkaline earth metals heavier than beryllium all form saline hydrides. A...
temperature; despite this it is the most stable of the binary first row transitionmetalhydrides. A variety of coordination compounds containing Zn–H bonds are...
Potassium hydride, KH, is the inorganic compound of potassium and hydrogen. It is an alkali metalhydride. It is a white solid, although commercial samples...
N-allylamides. LAH is widely used to prepare main group and transitionmetalhydrides from the corresponding metal halides. LAH also reacts with many inorganic ligands...
1016/S0360-3199(00)00037-9. Lummis, Paul Ashley (2015). Earth-Abundant TransitionMetalHydride Complexes for Dehydrocoupling and Hydrosilylation Catalysis. University...
organic matter and is a greenhouse gas. The other hydrides are generally unstable, poisonous metalhydrides. They take on a pyramidal structure, and as such...
Metal carbonyls are coordination complexes of transitionmetals with carbon monoxide ligands. Metal carbonyls are useful in organic synthesis and as catalysts...
Pnictogen hydrides or hydrogen pnictides are binary compounds of hydrogen with pnictogen (/ˈpnɪktədʒən/ or /ˈnɪktədʒən/; from Ancient Greek: πνῑ́γω "to...
oxyhydrides, hydride sulfides, and hydride selenides. Salt-like hydride tellurides may be formed by heating tellurium with a metalhydride in an oxygen-free...
CH3CH2Cl Pseudohalogen Hypohalous acid group 13 hydrides group 14 hydrides group 15 hydrides group 16 hydrides Greenwood, Norman N.; Earnshaw, Alan (1997)...
gallane hydride species, which can act as a source of two hydrides and also a strong electron donor to stabilize resulting high-oxidation state transition metal...
Titanium hydride normally refers to the inorganic compound TiH2 and related nonstoichiometric materials. It is commercially available as a stable grey/black...
Aluminium hydride (also known as alane and alumane) is an inorganic compound with the formula AlH3. Alane and its derivatives are part of a family of...
palladium hydride) may be due to the formation and migration of polonium hydride. Polonium hydride is a more covalent compound than most metalhydrides because...
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