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Stability constants of complexes information


In coordination chemistry, a stability constant (also called formation constant or binding constant) is an equilibrium constant for the formation of a complex in solution. It is a measure of the strength of the interaction between the reagents that come together to form the complex. There are two main kinds of complex: compounds formed by the interaction of a metal ion with a ligand and supramolecular complexes, such as host–guest complexes and complexes of anions. The stability constant(s) provide(s) the information required to calculate the concentration(s) of the complex(es) in solution. There are many areas of application in chemistry, biology and medicine.

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Stability constants of complexes

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interaction of a metal ion with a ligand and supramolecular complexes, such as host–guest complexes and complexes of anions. The stability constant(s) provide(s)...

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Stability

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its environment Thermal stability of a chemical compound Kinetic stability of a chemical compound Stability constants of complexes, in solution Convective...

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Stability constant

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Stability constant may refer to: Equilibrium constant Acid dissociation constant Stability constants of complexes This disambiguation page lists articles...

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Dynamic equilibrium

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dynamic equilibria and concentrations are governed by the stability constants of complexes. Dynamic equilibria can also occur in the gas phase as, for...

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Equilibrium constant

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Stability constants, formation constants, binding constants, association constants and dissociation constants are all types of equilibrium constants....

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KF

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Cryoscopic constant, Kf, related to freezing-point depression Karl Fischer titration Stability constants of complexes, abbreviated as Kf (constant of formation)...

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Transition metal complexes of thiocyanate

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Transition metal complexes of thiocyanate describes coordination complexes containing one or more thiocyanate (SCN-) ligands. The topic also includes...

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Acid dissociation constant

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diagrams. Proton affinity: a measure of basicity in the gas phase. Stability constants of complexes: formation of a complex can often be seen as a competition...

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Coordination complex

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several of the ligand's atoms; ligands with 2, 3, 4 or even 6 bonds to the central atom are common. These complexes are called chelate complexes; the formation...

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Avidity

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complex formation in solution is related to the stability constants of complexes, however in case of large biomolecules, such as receptor-ligand pairs...

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Lanthanide contraction

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as lattice energies, solvation energies, and stability constants of complexes are also similar. Because of this similarity, hafnium is found only in association...

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Transition metal

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Another example occurs in the Irving–Williams series of stability constants of complexes. Moreover, Zn, Cd, and Hg can use their d orbitals for bonding even...

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Denticity

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ligands of lower denticity, primarily due to entropic factors. Stability constants are a quantitative measure to assess the thermodynamic stability of coordination...

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Determination of equilibrium constants

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When determining the stability constants of metal-ligand complexes, it is common practice to fix ligand protonation constants at values that have been...

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Stability theory

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stability theory addresses the stability of solutions of differential equations and of trajectories of dynamical systems under small perturbations of...

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Hydrolysis constant

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Wettingen: NAGRA. pp. 252–259. NIST46. NIST Critically Selected Stability Constants of Metal Complexes: Version 8.0.{{cite book}}: CS1 maint: numeric names: authors...

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Hydrodynamic stability

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hydrodynamic stability is the field which analyses the stability and the onset of instability of fluid flows. The study of hydrodynamic stability aims to find...

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Equilibrium chemistry

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define all constants as association constants. The relationship between the two types of constant is given in association and dissociation constants. In biochemistry...

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Chelation

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of notation. The square brackets indicate concentration, and the subscripts to the stability constants, β, indicate the stoichiometry of the complex....

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Exponential stability

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convergence is bounded by exponential decay. Exponential stability is a form of asymptotic stability, valid for more general dynamical systems. An exponentially...

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Madelung constant

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determination of higher order Madelung constants or so-called electrostatic lattice constants. The proper calculation of electrostatic lattice constants has to...

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Stability derivatives

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Stability derivatives, and also control derivatives, are measures of how particular forces and moments on an aircraft change as other parameters related...

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Ecological stability

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ecology, an ecosystem is said to possess ecological stability (or equilibrium) if it is capable of returning to its equilibrium state after a perturbation...

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Metal aquo complex

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chemistry, metal aquo complexes are coordination compounds containing metal ions with only water as a ligand. These complexes are the predominant species...

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