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Transition metal dithiocarbamate complexes information


Structure of iron tris(diethyldithiocarbamate).

Transition metal dithiocarbamate complexes are coordination complexes containing one or more dithiocarbamate ligand, which are typically abbreviated R2dtc. Many complexes are known. Several homoleptic derivatives have the formula M(R2dtc)n where n = 2 and 3.[1]

  1. ^ Coucouvanis, Dimitri (1979). "The Chemistry of the Dithioacid and 1,1-Dithiolate Complexes, 1968–1977". Prog. Inorg. Chem. Progress in Inorganic Chemistry. 26: 301–469. doi:10.1002/9780470166277.ch5. ISBN 9780470166277.

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Transition metal dithiocarbamate complexes

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Transition metal dithiocarbamate complexes are coordination complexes containing one or more dithiocarbamate ligand, which are typically abbreviated R2dtc−...

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Dithiocarbamate

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Sodium diethyldithiocarbamate

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NaCl Diethyldithiocarbamate reacts with many metal salts to give transition metal dithiocarbamate complexes. The ligands coordinate via the two sulfur atoms...

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Metal sulfur dioxide complex

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organometallic chemistry, metal sulfur dioxide complexes are complexes that contain sulfur dioxide, SO2, bonded to a transition metal. Such compounds are common...

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Pyrrolidine dithiocarbamate

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polymerase. Pyrrolidine dithiocarbamate, like other dithiocarbamates, forms coordination complexes with a variety of transition metals. One example is Fe(S2CNC4H8)3...

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Nitric oxide

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trapping of nitric oxide with iron-dithiocarbamate complexes and subsequent detection of the mono-nitrosyl-iron complex with electron paramagnetic resonance...

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Sulfur mononitride

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forming metal-thionitrosyl complexes. Transition-metal thionitrosyl complexes have been prepared by the following procedures: Sulfur transfer to metal nitrido...

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Carbon compounds

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complexes between transition metals and carbonyl ligands. Metal carbonyls are complexes that are formed with the neutral ligand CO. These complexes are...

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Zinc chloride

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formation of the tetrahedral chloro aqua complexes such as [ZnCl3(H2O)]-. Most metal dichlorides for octahedral complexes, with stronger O-H bonds. The combination...

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related anhydrides. Xanthates bind to transition metal cations as bidentate ligands. The charge-neutral complexes are soluble in organic solvents. Xanthates...

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first-row transition metals. Zinc tends to form bonds with a greater degree of covalency and much more stable complexes with N- and S- donors. Complexes of zinc...

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the metal-free SBHs. SBHs can react with many kinds of transition metal cations and thereby forming a number of complexes. Copper-SBH complexes were...

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