Octahedral molecular geometry is a common structural motif for homoleptic metal chloride complexes. Examples include MCl6 (M = Mo, W), [MCl6]− (M = Nb, Ta, Mo, W, Re), [MCl6]2- (M = Ti Zr, Hf, Mo, Mn, Re, Ir, Pd, Pt), and [MCl6]3- (M = Ru Os, Rh, Ir).
In chemistry, a transition metal chloride complex is a coordination complex that consists of a transition metal coordinated to one or more chloride ligand. The class of complexes is extensive.[1]
^Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
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