In organometallic chemistry, a transition metal alkene complex is a coordination compound containing one or more alkene ligands. The inventory is large.[1] Such compounds are intermediates in many catalytic reactions that convert alkenes to other organic products.[2]
^Elschenbroich, C. "Organometallics" (2006) Wiley-VCH: Weinheim. ISBN 3-527-29390-6
^John Hartwig. Organotransition Metal Chemistry: From Bonding to Catalysis. University Science Books. ISBN 978-1-891389-53-5.
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In organometallic chemistry, a transitionmetalalkenecomplex is a coordination compound containing one or more alkene ligands. The inventory is large...
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turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transitionmetals (elements like titanium that...
aldehyde-based fragrances. Zeise's salt is an example of a transitionmetalalkenecomplex. Trimethylaluminium is an organometallic compound with a bridging...
{(CH3)2C=}}{\color {red}{\ce {CH2}}}} In transitionmetalalkenecomplexes, alkenes serve as ligands for metals. In this case, the π electron density is...
Metal carbonyls are coordination complexes of transitionmetals with carbon monoxide ligands. Metal carbonyls are useful in organic synthesis and as catalysts...
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Transitionmetal benzyne complexes are organometallic complexes that contain benzyne ligands (C6H4). Unlike benzyne itself, these complexes are less reactive...
In coordination chemistry, a transitionmetal NHC complex is a metalcomplex containing one or more N-heterocyclic carbene ligands. Such compounds are...
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In organometallic chemistry, transitionmetalcomplexes of nitrite describes families of coordination complexes containing one or more nitrite (−NO2) ligands...
Thus strong π backbonding causes a metal-alkenecomplex to assume the character of a metallacyclopropane. Alkenes and alkynes with electronegative substituents...
of TransitionMetal Components and Cocatalysts in Catalyst Systems for Alkene Polymerization". Alkene Polymerization Reactions with TransitionMetal Catalysts...
similarly to electron-deficient alkenes such as tetracyanoethylene. Thus, their complexes are a subset of metal-alkenecomplexes. They almost always coordinate...
The metal atom usually makes four coordination bonds to the oxygen and nitrogen atoms. The salen anion forms complexes with most transitionmetals. These...
In coordination chemistry and organometallic chemistry, transitionmetal imido complexes is a coordination compound containing an imido ligand. Imido ligands...
Metal acetylacetonates are coordination complexes derived from the acetylacetonate anion (CH 3COCHCOCH− 3) and metal ions, usually transitionmetals. The...
Metal carbonyl hydrides are complexes of transitionmetals with carbon monoxide and hydride as ligands. These complexes are useful in organic synthesis...
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