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Phosphorus pentafluoride information


Phosphorus pentafluoride
Structure of the phosphorus pentafluoride molecule
Space-filling model of the phosphorus pentafluoride molecule
Names
IUPAC name
Phosphorus pentafluoride
Other names
Phosphorus(V) fluoride
Pentafluoridophosphorus
Pentafluorophosphorane
Identifiers
CAS Number
  • 7647-19-0 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 22715 ☒N
ECHA InfoCard 100.028.730 Edit this at Wikidata
EC Number
  • 231-602-3
PubChem CID
  • 24295
RTECS number
  • TH4070000
UNII
  • 0OU1ESO71L checkY
UN number 2198
CompTox Dashboard (EPA)
  • DTXSID9064760 Edit this at Wikidata
InChI
  • InChI=1S/F5P/c1-6(2,3,4)5 ☒N
    Key: OBCUTHMOOONNBS-UHFFFAOYSA-N ☒N
  • InChI=1/F5P/c1-6(2,3,4)5
    Key: OBCUTHMOOONNBS-UHFFFAOYAH
SMILES
  • FP(F)(F)(F)F
Properties
Chemical formula
PF5
Molar mass 125.965777813 g·mol−1
Appearance colourless gas
Odor unpleasant
Density 5.527 kg/m3
Melting point −93.78 °C (−136.80 °F; 179.37 K)
Boiling point −84.6 °C (−120.3 °F; 188.6 K)
Solubility in water
hydrolysis
Structure
Molecular shape
trigonal bipyramidal
Dipole moment
0 D
Hazards
Flash point Non-flammable
Related compounds
Other anions
Phosphorus pentachloride
Phosphorus pentabromide
Phosphorus pentaiodide
Other cations
Arsenic pentafluoride
Antimony pentafluoride
Bismuth pentafluoride
Related compounds
Phosphorus trifluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Phosphorus pentafluoride, PF5, is a phosphorus halide. It is a colourless, toxic gas that fumes in air.[1][2]

  1. ^ Kwasnik, W. (1963). "Phosphorus(V) fluoride". In Brauer, G. (ed.). Handbook of Preparative Inorganic Chemistry. Vol. 1 (2nd ed.). New York: Academic Press. p. 190.
  2. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.

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Phosphorus pentafluoride

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Phosphorus pentafluoride, PF5, is a phosphorus halide. It is a colourless, toxic gas that fumes in air. Phosphorus pentafluoride was first prepared in...

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Pentafluoride

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Neptunium pentafluoride, NpF5 Osmium pentafluoride, OsF5 Phosphorus pentafluoride, PF5 Platinum pentafluoride, PtF5 Plutonium pentafluoride, PuF5 Protactinium...

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Phosphorus pentachloride

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Phosphorus pentachloride is the chemical compound with the formula PCl5. It is one of the most important phosphorus chlorides/oxychlorides, others being...

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Phosphorus halide

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gas phase the phosphorus pentahalides have trigonal bipyramidal molecular geometry as explained by VSEPR theory. Phosphorus pentafluoride is a relatively...

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Octet rule

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main-group atom is bonded to more than four other atoms, such as phosphorus pentafluoride, PF5, and sulfur hexafluoride, SF6. For example, in PF5, if it...

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Nitrogen pentafluoride

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nitrogen in the periodic table, such as phosphorus pentafluoride. Theoretical models of the nitrogen pentafluoride molecule are either a trigonal bipyramidal...

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Phosphorus

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and pentafluoride are Lewis acids. With fluoride, PF5 forms PF6−, an anion that is isoelectronic with SF6. The most important oxyhalide is phosphorus oxychloride...

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Trigonal bipyramidal molecular geometry

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positions. Examples of this molecular geometry are phosphorus pentafluoride (PF5), and phosphorus pentachloride (PCl5) in the gas phase. The five atoms...

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Arsenic pentafluoride

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Arsenic pentafluoride is a chemical compound of arsenic and fluorine. It is a toxic, colorless gas. The oxidation state of arsenic is +5. Arsenic pentafluoride...

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Antimony pentafluoride

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+ F2 + 2 O2 → 2 [O2]+[SbF6]− Antimony pentafluoride by itself, is also a very strong oxidizing agent. Phosphorus burns on contact with it. SbF5 has also...

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Phosphorus fluoride

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Phosphorus fluoride may refer to any of the following: Phosphorus trifluoride, PF3 Phosphorus pentafluoride, PF5 Diphosphorus tetrafluoride, P2F4 See...

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Phosphoranes

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non-bonding MOs, as also invoked for the closely related molecule phosphorus pentafluoride. The parent hydride compound is the hypothetical molecule PH5....

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Phosphorus trifluoride

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Phosphorus trifluoride (formula PF3), is a colorless and odorless gas. It is highly toxic and reacts slowly with water. Its main use is as a ligand in...

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Phosphorus pentabromide

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Phosphorus pentabromide is a reactive, yellow solid of formula PBr5, which has the structure [PBr4]+Br− (tetrabromophosphonium bromide) in the solid state...

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List of highly toxic gases

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(PDF). Environmental Protection Agency. 2007. ISBN 978-0-309-11214-7. "Phosphorus(V) fluoride Safety Data Sheet". ThermoFisher Scientific. January 6, 2023...

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Hypervalent molecule

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completed with ionic bonds to obey the octet rule. For example, in phosphorus pentafluoride (PF5), 5 resonance structures can be generated each with four covalent...

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Phosphoryl fluoride

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critical pressure of 4.25 bars. Phosphorus oxyfluoride is prepared by partial hydrolysis of phosphorus pentafluoride. Phosphorus oxyfluoride is the progenitor...

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Nonmetal

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from period 2 onward, in compounds such as nitric acid (HNO3) and phosphorus pentafluoride (PCl5). Higher oxidation states in later groups emerge from period...

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Hexafluorophosphoric acid

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Hexafluorophosphoric acid refers to a family of salts produced by combining phosphorus pentafluoride and hydrofluoric acid. The idealized chemical formula for hexafluorophosphoric...

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Bismuth pentafluoride

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Bismuth pentafluoride is an inorganic compound with the formula BiF5. It is a white solid that is highly reactive. The compound is of interest to researchers...

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List of gases

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25284-83-7 unstable at room temperature. Sulfur pentafluoride isocyanide isomerises to sulfur pentafluoride cyanide. Haynes, W. M., ed. (2016). CRC Handbook...

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Fluxional molecule

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spectrum remains unchanged. A prototypical fluxional molecule is phosphorus pentafluoride. Its 19F NMR spectrum consists of a 31P-coupled doublet, indicating...

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Chlorine trifluoride

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hexafluoride: U + 3 ClF3 → UF6 + 3 ClF With phosphorus, it yields phosphorus trichloride (PCl3) and phosphorus pentafluoride (PF5), while sulfur yields sulfur dichloride...

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Thionyl tetrafluoride

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probably because they exchange positions. It is isoelectronic with phosphorus pentafluoride. Thionyl fluoride reacting with fluorine gas can produce thionyl...

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Phosphorus pentaiodide

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Phosphorus pentaiodide is a hypothetical inorganic compound with formula PI5. The existence of this compound has been claimed intermittently since the...

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List of CAS numbers by chemical compound

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10026–13–8 PF3 phosphorus trifluoride 7783–55–3 PF5 phosphorus pentafluoride 7647–19–0 PH3 phosphorus trihydride 7803–51–2 PI3 phosphorus triiodide 13455–01–1...

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List of inorganic compounds

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nitride – NPO Phosphorus pentabromide – PBr5 Phosphorus pentafluoride – PF5 Phosphorus pentasulfide – P4S10 Phosphorus pentoxide – P2O5 Phosphorus sesquisulfide...

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Triangular bipyramid

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VSEPR theory. Some examples of this structure are the phosphorus pentafluoride and phosphorus pentachloride in the gas phase. In the study of color theory...

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