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Antimony tribromide information


Antimony tribromide
Names
IUPAC name
tribromostibane
Other names
Antimony(III) bromide
Identifiers
CAS Number
  • 7789-61-9 ☒N
3D model (JSmol)
  • Interactive image
  • Interactive image
ChemSpider
  • 23017 checkY
ECHA InfoCard 100.029.254 Edit this at Wikidata
EC Number
  • 232-179-8
PubChem CID
  • 24615
RTECS number
  • CC4400000
UNII
  • 6PM239QD86
UN number 1549
CompTox Dashboard (EPA)
  • DTXSID6064870 Edit this at Wikidata
InChI
  • InChI=1S/3BrH.Sb/h3*1H;/q;;;+3/p-3 checkY
    Key: RPJGYLSSECYURW-UHFFFAOYSA-K checkY
  • InChI=1/3BrH.Sb.3H/h3*1H;;;;/q;;;+3;;;/p-3/r3BrH.H3Sb/h3*1H;1H3/q;;;+3/p-3
    Key: BJUAQAQGPWXYGO-DAEPFFQNAU
  • InChI=1/3BrH.Sb/h3*1H;/q;;;+3/p-3
    Key: RPJGYLSSECYURW-DFZHHIFOAI
SMILES
  • [Br-].[Br-].[Br-].[SbH3+3]
  • Br[Sb](Br)Br
Properties
Chemical formula
SbBr3
Molar mass 361.472 g/mol
Appearance colorless to yellow crystals
hygroscopic
Density 4.35 g/cm3
Melting point 96.6 °C (205.9 °F; 369.8 K)
Boiling point 288 °C (550 °F; 561 K)
Solubility in water
soluble,partial hydrolysis
Solubility soluble in dilute HCl, HBr, CS2, acetone, benzene, chloroform, ammonia, alcohol
Magnetic susceptibility (χ)
-115.0·10−6 cm3/mol
Refractive index (nD)
1.74
Dipole moment
2.47 D
Structure
Crystal structure
Orthorhombic, oP16, SpaceGroup = Pnma, No. 62 (β form)
Thermochemistry
Heat capacity (C)
96 J/mol K
Std enthalpy of
formation fH298)
-259 kJ/mol
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation markGHS09: Environmental hazard
Signal word
Warning
Hazard statements
H302, H332, H411
Precautionary statements
P261, P264, P270, P271, P273, P301+P312, P304+P312, P304+P340, P312, P330, P391, P501
Lethal dose or concentration (LD, LC):
LD50 (median dose)
7000 mg/kg
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 0.5 mg/m3 (as Sb)[1]
REL (Recommended)
TWA 0.5 mg/m3 (as Sb)[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Antimony tribromide (SbBr3) is a chemical compound containing antimony in its +3 oxidation state.

  1. ^ a b NIOSH Pocket Guide to Chemical Hazards. "#0036". National Institute for Occupational Safety and Health (NIOSH).

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Antimony tribromide

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Antimony tribromide (SbBr3) is a chemical compound containing antimony in its +3 oxidation state. Antimony tribromide may be made by the reaction of antimony...

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Tribromide

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Americium tribromide, AmBr3 Antimony tribromide, SbBr3 Arsenic tribromide, AsBr3 Berkelium tribromide, BkBr3 Bismuth tribromide, BiBr3 Boron tribromide, BBr3...

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Antimony trichloride

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butter of antimony. Antimony trichloride is prepared by reaction of chlorine with antimony, antimony tribromide, antimony trioxide, or antimony trisulfide...

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Phosphorus tribromide

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Phosphorus tribromide is a colourless liquid with the formula PBr3. The liquid fumes in moist air due to hydrolysis and has a penetrating odour. It is...

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Bismuth tribromide

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Bismuth tribromide is an inorganic compound of bismuth and bromine with the chemical formula BiBr3. It may be formed by the reaction of bismuth oxide and...

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Pnictogen

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Antimony forms antimony(III) oxide and antimonite but not oxyacids. Its trihalides, antimony trifluoride, antimony trichloride, antimony tribromide,...

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Tungsten hexabromide

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by the metathesis reaction of boron tribromide and tungsten hexachloride. WBr6 is reduced with elemental antimony at elevated temperatrues, consecutively...

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List of CAS numbers by chemical compound

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28950–34–7 SbBr3 antimony tribromide 7789–61–9 SbCl2F3 antimony dichlorotrifluoride 7791–16–4 SbCl3 antimony trichloride 10025–91–9 SbCl5 antimony pentachloride...

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Antimony oxychloride

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(1981). "Physiochemical analysis of antimony trioxide–antimony trichloride, antimony trioxide–antimony tribromide systems". Zhurnal Neorganicheskoi Khimii...

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Bromoantimonates

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can be made using a water solution of antimony tribromide, hydrobromic acid, and an amine. Alternately antimony trioxide can be used. Variants can be...

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Metalloid

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commonly recognised metalloids are boron, silicon, germanium, arsenic, antimony and tellurium. Five elements are less frequently so classified: carbon...

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Neptunium tetrabromide

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under strong heating to form neptunium tribromide: 2NpBr4 → 2NpBr3 + Br2 With careful oxidation with antimony(III) oxide, the compound forms neptunium...

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List of inorganic compounds

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Antimony hydride (stybine) – SbH3 Antimony pentachloride – SbCl5 Antimony pentafluoride – SbF5 Antimony potassium tartrate – K2Sb2(C4H2O6)2 Antimony sulfate...

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Berkelium

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californium-249 ingrowth into crystalline berkelium-249 tribromide: a new crystalline phase of californium tribromide". Inorganic Chemistry. 19 (8): 2209. doi:10...

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Stibinin

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an antimony (Sb) atom. Stibinin is a molecule that is considered to be an organoantimony compound due to it containing carbon, hydrogen, and antimony atoms...

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Bromine

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nitrides, fluorides, or chlorides of bromine. (Nonetheless, nitrogen tribromide is named as a bromide as it is analogous to the other nitrogen trihalides...

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Explosive

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hydrazine perchlorate Nitrogen trihalides: Nitrogen trichloride Nitrogen tribromide Nitrogen triiodide Nitroglycerin Nitronium perchlorate Nitrosyl perchlorate...

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Aluminium

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trigonal planar AlCl3 monomers similar to the structure of BCl3. Aluminium tribromide and aluminium triiodide form Al2X6 dimers in all three phases and hence...

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Nitrogen compounds

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and is thus used industrially to bleach and sterilise flour. Nitrogen tribromide (NBr3), first prepared in 1975, is a deep red, temperature-sensitive,...

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Actinium

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ammonia. Reaction of aluminium bromide and actinium oxide yields actinium tribromide: Ac2O3 + 2 AlBr3 → 2 AcBr3 + Al2O3 and treating it with ammonium hydroxide...

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Ethanol

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specialized halogenating agents, such as thionyl chloride or phosphorus tribromide. CH3CH2OH + SOCl2 → CH3CH2Cl + SO2 + HCl Upon treatment with halogens...

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Nitrogen

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and is thus used industrially to bleach and sterilise flour. Nitrogen tribromide (NBr3), first prepared in 1975, is a deep red, temperature-sensitive,...

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Technetium

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either trichloride phase. Instead it has the structure of molybdenum tribromide, consisting of chains of confacial octahedra with alternating short and...

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Nitrogen trifluoride

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reactive than the other nitrogen trihalides nitrogen trichloride, nitrogen tribromide and nitrogen triiodide, all of which are explosive. Alone among the nitrogen...

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Phosphorus trichloride

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examination of the basic nature of the trihalides of phosphorus, arsenic and antimony". Journal of Inorganic and Nuclear Chemistry. 12 (3–4): 266–275. doi:10...

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Osmium

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states are stabilized by the larger halogens, so that the trichloride, tribromide, triiodide, and even diiodide are known. The oxidation state +1 is known...

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Glossary of chemical formulae

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telluride 12002-99-2 Ag3Br2 silver dibromide 11078-32-3 Ag3Br3 silver tribromide 11078-33-4 Ag3Cl3 silver(III) trichloride 12444-96-1 Ag3I3 silver(III)...

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Lanthanide

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hydrolyse producing ammonia. The other pnictides phosphorus, arsenic, antimony and bismuth also react with the lanthanide metals to form monopnictides...

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