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Organoantimony chemistry information


Organoantimony chemistry is the chemistry of compounds containing a carbon to antimony (Sb) chemical bond. Relevant oxidation states are SbV and SbIII. The toxicity of antimony[1] limits practical application in organic chemistry.[2]

  1. ^ Filella, M. (2010). "Alkyl derivatives of antimony in the environment". Metal Ions in Life Sciences. 7. Cambridge: RSC publishing: 267–301. doi:10.1039/9781849730822-00267. ISBN 978-1-84755-177-1. PMID 20877810.
  2. ^ C. Elschenbroich, A. Salzer Organometallics : A Concise Introduction (2nd Ed) (1992) from Wiley-VCH: Weinheim. ISBN 3-527-28165-7

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Organoantimony chemistry

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Organoantimony chemistry is the chemistry of compounds containing a carbon to antimony (Sb) chemical bond. Relevant oxidation states are SbV and SbIII...

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Organometallic chemistry

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chemistry, organocadmium chemistry, organoindium chemistry, organotin chemistry, organoantimony chemistry, organotellurium chemistry Period 6 elements: organolanthanide...

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Organoarsenic chemistry

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"The direct synthesis of organoarsenic and organoantimony compounds". Journal of Inorganic and Nuclear Chemistry. 16 (3–4): 213–218. doi:10.1016/0022-1902(61)80492-2...

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Metalloid

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glass former. Antimony has an extensive organometallic chemistry (see Organoantimony chemistry). Tellurium is a silvery-white shiny solid. It has a density...

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Organobismuth chemistry

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(1989). "The use of organoantimony and organobismuth compounds in organic synthesis". In Hartley, Frank Robinson (ed.). The Chemistry of the Metal—Carbon...

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Antimony

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thermodynamically unstable and thus antimony does not react with hydrogen directly. Organoantimony compounds are typically prepared by alkylation of antimony halides with...

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Nontrigonal pnictogen compounds

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Phosphine Organophosphorus compound Organoarsenic chemistry Organoantimony chemistry Organobismuth chemistry Culley, Scott Anthony; Arduengo, Anthony J. (1984-02-01)...

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Lewis acidic antimony compounds

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polymerization and hydroamination after being activated by AgNTf2. Antimony Organoantimony chemistry Superacid Caputo, C. B.; Hounjet, L. J.; Dobrovetsky, R.; Stephan...

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Stibole

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Stiboles can be used to form ferrocene-like sandwich compounds. Organoantimony chemistry J.I.G. Cadogan; S.V. Ley; G. Pattenden; R.A. Raphael; C.W. Rees...

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Antimony nitride

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Wiley-VCH Verlag GmbH & Co. KGaA (ed.), Ullmann's Encyclopedia of Industrial Chemistry, Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, doi:10.1002/14356007...

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Triphenylstibine

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is often considered the prototypical organoantimony compound. It is used as a ligand in coordination chemistry and as a reagent in organic synthesis...

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Oxidation state

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organoantimony compounds; for Sb(I), see Šimon, Petr; de Proft, Frank; Jambor, Roman; Růžička, Aleš; Dostál, Libor (2010). "Monomeric Organoantimony(I)...

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Praseodymium antimonide

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(Praseodymium-Antimony)", Ni-Np – Pt-Zr, Landolt-Börnstein - Group IV Physical Chemistry, vol. I, Berlin/Heidelberg: Springer-Verlag, pp. 1–2, doi:10.1007/10542753_2498...

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Antimony trisulfide

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are connected with packing. Haynes, W. M., ed. (2014). CRC Handbook of Chemistry and Physics (95th ed.). Boca Raton, FL: CRC Press. pp. 4–48. ISBN 978-1-4822-0867-2...

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Trimethylstibine

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Trimethylstibine is an organoantimony compound with the formula Sb(CH3)3. It is a colorless pyrophoric and toxic liquid. It is synthesized by treatment...

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Pentaphenylantimony

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Pentaphenylantimony is an organoantimony compound containing five phenyl groups attached to one antimony atom. It has formula Sb(C6H5)5 (or SbPh5). The...

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Fluoroantimonic acid

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Fluorosulfuric acid Hexafluorophosphoric acid Olah, G. A. (2001). A Life of Magic Chemistry: Autobiographical Reflections of a Nobel Prize Winner. John Wiley and...

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Bismuthinidene

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Jambor, Roman; Růžička, Aleš; Dostál, Libor (2 July 2010). "Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand:...

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Holmium diantimonide

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1969). "High-pressure synthesis of rare earth diantimonides". Inorganic Chemistry. 8 (7): 1439–1445. doi:10.1021/ic50077a014. ISSN 0020-1669. Archived from...

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Antimony pentachloride

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pentachloride in Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute...

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Antimony tetroxide

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Valero, C. Ruiz (1988). "Diantimony Tetraoxides Revisited". Inorganic Chemistry. 27 (8): 1367–1370. doi:10.1021/ic00281a011. NIOSH Pocket Guide to Chemical...

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Antimony trichloride

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1101–1109. Abstract (PDF) "Antimony: Inorganic Chemistry" R. Bruce King Encyclopedia of Inorganic Chemistry Editor R Bruce King (1994) John Wiley and Sons...

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Antimony pentasulfide

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"The oxidation number of antimony in antimony pentasulfide". Inorganic and Nuclear Chemistry Letters. 5 (1): 21–25. doi:10.1016/0020-1650(69)80231-X....

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Antimony pentafluoride

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Encyclopedia of Industrial Chemistry 2006, Wiley-VCH, Weinheim doi:10.1002/14356007.a03_055.pub2 Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by...

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Stibinin

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antimony (Sb) atom. Stibinin is a molecule that is considered to be an organoantimony compound due to it containing carbon, hydrogen, and antimony atoms....

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Indium antimonide

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Retrieved 2020-01-11. Haynes, William M., ed. (2016). CRC Handbook of Chemistry and Physics (97th ed.). CRC Press. ISBN 9781498754293. National Compound...

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Antimony telluride

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of Chemistry and Physics (92nd ed.). Boca Raton, FL: CRC Press. p. 4.48. ISBN 1-4398-5511-0. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of...

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Antimony trifluoride

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applications, it is used as a reagent in inorganic and organofluorine chemistry. In solid SbF3, the Sb centres have octahedral molecular geometry and...

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