n-Butyllithium, an organometallic compound. Four lithium atoms (in purple) form a tetrahedron, with four butyl groups attached to the faces (carbon is black, hydrogen is white).
Organometallic chemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an organic molecule and a metal, including alkali, alkaline earth, and transition metals, and sometimes broadened to include metalloids like boron, silicon, and selenium, as well.[1][2] Aside from bonds to organyl fragments or molecules, bonds to 'inorganic' carbon, like carbon monoxide (metal carbonyls), cyanide, or carbide, are generally considered to be organometallic as well. Some related compounds such as transition metal hydrides and metal phosphine complexes are often included in discussions of organometallic compounds, though strictly speaking, they are not necessarily organometallic. The related but distinct term "metalorganic compound" refers to metal-containing compounds lacking direct metal-carbon bonds but which contain organic ligands. Metal β-diketonates, alkoxides, dialkylamides, and metal phosphine complexes are representative members of this class. The field of organometallic chemistry combines aspects of traditional inorganic and organic chemistry.[3]
Organometallic compounds are widely used both stoichiometrically in research and industrial chemical reactions, as well as in the role of catalysts to increase the rates of such reactions (e.g., as in uses of homogeneous catalysis), where target molecules include polymers, pharmaceuticals, and many other types of practical products.
^Crabtree 2009, p. [page needed].
^IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "organometallic compounds". doi:10.1351/goldbook.O04328
^C. Elschenbroich (2006). Organometallics. VCH. ISBN 978-3-527-29390-2.
and 29 Related for: Organometallic chemistry information
Organometallicchemistry is the study of organometallic compounds, chemical compounds containing at least one chemical bond between a carbon atom of an...
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sparked excitement and led to a rapid growth in the discipline of organometallicchemistry. Geoffrey Wilkinson and Ernst Otto Fischer, both of whom worked...
+ HC ≡ CM {\displaystyle {\ce {HC#CH + RM -> RH + HC#CM}}} Various organometallic and inorganic reagents are effective. Acetylene can be semihydrogenated...
Daviesa, G.A. Solana and A.M. Stuarta "Green OrganometallicChemistry" in Comprehensive OrganometallicChemistry III, 2007, Volume 12, Pages 837-864. doi:10...
is typically classified as an organometallic compound as it satisfies the broad definition that organometallicchemistry covers all compounds that contain...
made between the LUMO level and the conduction band minimum. In organometallicchemistry, the size of the LUMO lobe can help predict where addition to pi...
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