Triphenylbismuth, an example of an organometallic bismuth(III) compound
Organobismuth chemistry is the chemistry of organometallic compounds containing a carbon to bismuth chemical bond. Applications are few.[1][2] The main bismuth oxidation states are Bi(III) and Bi(V) as in all higher group 15 elements. The energy of a bond to carbon in this group decreases in the order P > As > Sb > Bi.[3] The first reported use of bismuth in organic chemistry was in oxidation of alcohols by Frederick Challenger in 1934 (using Ph3Bi(OH)2).[4] Knowledge about methylated species of bismuth in environmental and biological media is limited.[5]
^Ollevier, Thierry, ed. (2012). Bismuth-Mediated Organic Reactions. Topics in Current Chemistry. Vol. 311. doi:10.1007/978-3-642-27239-4. ISBN 978-3-642-27239-4. S2CID 92683528.[page needed]
^von Wangelin, Axel Jacobi (2004). "Bismuth Reagents and Catalysts in Organic Synthesis". Transition Metals for Organic Synthesis. pp. 379–394. doi:10.1002/9783527619405.ch2r. ISBN 9783527619405.
^C. Elschenbroich, A. Salzer Organometallics : A Concise Introduction (2nd Ed) (1992) from Wiley-VCH: Weinheim. ISBN 3-527-28165-7.[page needed]
^Challenger, Frederick; Richards, Oswald V. (1934). "94. Organo-derivatives of bismuth and thallium". Journal of the Chemical Society (Resumed): 405. doi:10.1039/JR9340000405.
^Filella, Montserrat (2010). "9. Alkyl Derivatives of Bismuth in Environmental and Biological Media". Organometallics in Environment and Toxicology. Metal Ions in Life Sciences. Vol. 7. pp. 303–318. doi:10.1039/9781849730822-00303. ISBN 978-1-84755-177-1. PMID 20877811.
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Organobismuthchemistry is the chemistry of organometallic compounds containing a carbon to bismuth chemical bond. Applications are few. The main bismuth...
Press: San Diego, 2001. ISBN 0-12-352651-5. Hitomi Suzuki; Yoshihiro Matano (2001). Organobismuthchemistry. Elsevier. pp. 403–404. ISBN 0-444-20528-4....
dimetallic salts and show Lewis acidity at the rhodium center. Organobismuthchemistry Bismuth compounds Braunschweig, Holger; Cogswell, Paul; Schwab...
Vol. 9. Royal Society of Chemistry. p. 93. ISBN 0-85404-690-9. Suzuki, Hitomi; Matano, Yoshihiro (2001). Organobismuthchemistry. Elsevier. p. 8. ISBN 0-444-20528-4...
Bismoles can be used to form ferrocene-like sandwich compounds. Organobismuthchemistry Suzuki, Hitomi; Komatsu, Naoki; Ogawa, Takuji; Murafuji, Toshihiro;...
Matano Y (eds.). OrganobismuthChemistry. Elsevier. ISBN 978-0-444-20528-5. Brauer G (1963). Handbook of Preparative Inorganic Chemistry. Vol. 1 (2 ed.)...
Bismuth subhalides Organobismuthchemistry Bismuth organometallic chemistry Levason, W.; Reid, G. (2003). "Coordination Chemistry of the s, p, and f Metals"...
Phosphine Organophosphorus compound Organoarsenic chemistry Organoantimony chemistryOrganobismuthchemistry Culley, Scott Anthony; Arduengo, Anthony J. (1984-02-01)...
and organobismuth compounds in organic synthesis". In Hartley, Frank Robinson (ed.). The Chemistry of the Metal—Carbon Bond. (Patai's) Chemistry of Functional...
production is often accomplished by the beta decay of 210Bi-containing organobismuth compounds. Some compounds have been claimed but not securely identified...
for enterotoxigenic E. coli a common cause of "traveler's diarrhea." Organobismuth compounds have historically been used in growth media for selective...
thermoelectric properties of β-BiAs and β-BiSb monolayers". Journal of Materials Chemistry C. 8 (2): 581–590. doi:10.1039/C9TC04842A. ISSN 2050-7526. S2CID 213271946...
Bismuthinidenes are a class of organobismuth compounds, analogous to carbenes. These compounds have the general form R-Bi, with two lone pairs of electrons...
properties of bismuth ferrite. Wet chemical synthesis routes based on sol-gel chemistry, modified Pechini routes, hydrothermal synthesis and precipitation have...
Methylbismuth dichloride is the organobismuth compound with the formula CH3BiCl2. It is a pale yellow solid. The compound can be prepared in two steps...
Part-1.35. ISSN 0044-2968. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. p. 572. ISBN 978-0-08-037941-8...
ISBN 978-3-432-02328-1. Haynes, William M. (2012-06-22). CRC Handbook of Chemistry and Physics, 93rd Edition. CRC Press. ISBN 978-1-4398-8049-4. 付大卫, 谢汝义...
90°. The term bismuthine may also refer to a member of the family of organobismuth(III) species having the general formula BiR 3, where R is an organic...
Růžička, Aleš; Dostál, Libor (2010). "Monomeric Organoantimony(I) and Organobismuth(I) Compounds Stabilized by an NCN Chelating Ligand: Syntheses and Structures"...
Bismabenzene (C5H5Bi) is the parent representative of a group of organobismuth compounds that are related to benzene with a carbon atom replaced by a...
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