Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Antimony pentachloride is a chemical compound with the formula SbCl5. It is a colourless oil, but typical samples are yellowish due to dissolved chlorine. Owing to its tendency to hydrolyse to hydrochloric acid, SbCl5 is a highly corrosive substance and must be stored in glass or PTFE containers.
^ abc"Antimony pentachloride (UK PID)".
^ abcSigma-Aldrich Co., Antimony(V) chloride. Retrieved on 2014-05-29.
^ abc"Antimony(V) chloride".
^Antimony pentachloride in Linstrom, Peter J.; Mallard, William G. (eds.); NIST Chemistry WebBook, NIST Standard Reference Database Number 69, National Institute of Standards and Technology, Gaithersburg (MD) (retrieved 2014-05-29)
^ abNIOSH Pocket Guide to Chemical Hazards. "#0036". National Institute for Occupational Safety and Health (NIOSH).
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Antimonypentachloride is a chemical compound with the formula SbCl5. It is a colourless oil, but typical samples are yellowish due to dissolved chlorine...
220.7 pm). The pentachlorides of the elements above and below arsenic in group 15, phosphorus pentachloride and antimonypentachloride are much more stable...
react with almost all known compounds. Antimony pentafluoride is prepared by the reaction of antimonypentachloride with anhydrous hydrogen fluoride: SbCl5...
hydrolysis of antimonypentachloride; or by acidification of potassium hexahydroxoantimonate(V). It may also be prepared by oxidation of antimony trioxide...
Antimony chloride may refer to either of the following: Antimony trichloride, SbCl3 Antimonypentachloride, SbCl5 This disambiguation page lists articles...
involved treatment with antimony trifluoride with chlorine or with antimonypentachloride to give the active species antimony trifluorodichloride (SbCl2F3)...
butter of antimony. Antimony trichloride is prepared by reaction of chlorine with antimony, antimony tribromide, antimony trioxide, or antimony trisulfide...
"Synthesis of two crystalline species of the Friedel–Crafts intermediate antimonypentachloride-p-toluoyl chloride. Crystal structures of the donor–acceptor complex...
converted into trifluoromethyl compounds by treatment with antimony trifluoride/antimonypentachloride (the Swarts reaction). Another route to trifluoromethyl...
A crystalline compound composed of cyclooctasulfur monoxide and antimonypentachloride in equimolar quantities can be made (S8O·SbCl5). Ralf Steudel, Michael...
replaced with fluorine, by treatment with antimony trifluoride in the presence of chlorine or of antimonypentachloride. Some metal fluorides are particularly...
typically use a Friedel-Crafts catalyst, such as ferric chloride or antimonypentachloride: n O(C6H5)2 + n SO2Cl2 → {[O(C6H4)2]SO2}n + 2n HCl This route is...
formation between a Lewis base and the standard Lewis acid SbCl5 (antimonypentachloride), in dilute solution in the noncoordinating solvent 1,2-dichloroethane...
"Synthesis of two crystalline species of the Friedel–Crafts intermediate antimonypentachloride-p-toluoyl chloride. Crystal structures of the donor–acceptor complex...
precursor 1 in dichloromethane by reaction with 4 equivalents of antimonypentachloride. Two resonance structures exist for the dication. Structure 2a is...
with hydrogen fluoride in the presence of a catalytic amount of antimonypentachloride: CCl4 + 2HF → CCl2F2 + 2HCl This reaction can also produce trichlorofluoromethane...
Müller synthesised the compound by the reaction of benzene and antimonypentachloride, he then suggested that his compound was the same as Julin's chloride...
oxidant in most of its reactions. With halide acceptors, for example antimonypentachloride, converts to nitrosonium salts: NOCl + SbCl5 → [NO]+[SbCl6]− In...
number is derived from the enthalpy of reaction of the base with antimonypentachloride in 1,2-Dichloroethane as solvent. For acids, an acceptor number...
with hydrogen fluoride in the presence of a catalytic amount of antimonypentachloride: CCl4 + 3HF → CClF3 + 3HCl This reaction can also produce trichlorofluoromethane...
This cation was first prepared by mixing 3-chlorocyclopropene with antimonypentachloride, aluminum trichloride, or silver tetrafluoroborate. Carbon-13 NMR...
3 AgCl Treating thiazyl chloride with sulfur in the presence of antimonypentachloride gives dithionitronium hexachloroantimonate: SNCl + S + SbCl5 → [NS2]SbCl6...
gives the pentachloride SbCl5 and hot concentrated sulfuric acid results in the sulfate Sb2(SO4)3. It is not affected by molten alkali. Antimony is capable...
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