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Antimony information


Antimony, 51Sb
Antimony
Pronunciation
  • UK: /ˈæntɪməni/
    (AN-tə-mə-nee)
  • US: /ˈæntɪmni/
    (AN-tə-moh-nee)
Appearancesilvery lustrous gray
Standard atomic weight Ar°(Sb)
  • 121.760±0.001[1]
  • 121.76±0.01 (abridged)[2]
Antimony in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
As

Sb

Bi
tin ← antimony → tellurium
Atomic number (Z)51
Groupgroup 15 (pnictogens)
Periodperiod 5
Block  p-block
Electron configuration[Kr] 4d10 5s2 5p3
Electrons per shell2, 8, 18, 18, 5
Physical properties
Phase at STPsolid
Melting point903.78 K ​(630.63 °C, ​1167.13 °F)
Boiling point1908 K ​(1635 °C, ​2975 °F)
Density (at 20° C)6.694 g/cm3[3]
when liquid (at m.p.)6.53 g/cm3
Heat of fusion19.79 kJ/mol
Heat of vaporization193.43 kJ/mol
Molar heat capacity25.23 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 807 876 1011 1219 1491 1858
Atomic properties
Oxidation states−3, −2, −1, 0,[4] +1, +2, +3, +4, +5 (an amphoteric oxide)
ElectronegativityPauling scale: 2.05
Ionization energies
  • 1st: 834 kJ/mol
  • 2nd: 1594.9 kJ/mol
  • 3rd: 2440 kJ/mol
  • (more)
Atomic radiusempirical: 140 pm
Covalent radius139±5 pm
Van der Waals radius206 pm
Color lines in a spectral range
Spectral lines of antimony
Other properties
Natural occurrenceprimordial
Crystal structure ​rhombohedral (hR2)
Lattice constants
Rhombohedral crystal structure for antimony
a = 0.45066 nm
α = 57.112°
ah = 0.43084 nm
ch = 1.12736 nm (at 20 °C)[3]
Thermal expansion11.04×10−6/K (at 20 °C)[a]
Thermal conductivity24.4 W/(m⋅K)
Electrical resistivity417 nΩ⋅m (at 20 °C)
Magnetic orderingdiamagnetic[5]
Molar magnetic susceptibility−99.0×10−6 cm3/mol[6]
Young's modulus55 GPa
Shear modulus20 GPa
Bulk modulus42 GPa
Speed of sound thin rod3420 m/s (at 20 °C)
Mohs hardness3.0
Brinell hardness294–384 MPa
CAS Number7440-36-0
History
DiscoveryArabic alchemists (before AD 815)
Symbol"Sb": from Latin stibium 'stibnite'
Isotopes of antimony
Main isotopes[7] Decay
abun­dance half-life (t1/2) mode pro­duct
121Sb 57.2% stable
123Sb 42.8% stable
125Sb synth 2.7576 y β 125Te
Antimony Category: Antimony
| references

Antimony is a chemical element; it has symbol Sb (from Latin stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient times and were powdered for use as medicine and cosmetics, often known by the Arabic name kohl.[8] The earliest known description of the metalloid in the West was written in 1540 by Vannoccio Biringuccio.

China is the largest producer of antimony and its compounds, with most production coming from the Xikuangshan Mine in Hunan. The industrial methods for refining antimony from stibnite are roasting followed by reduction with carbon, or direct reduction of stibnite with iron.

The largest applications for metallic antimony are in alloys with lead and tin, which have improved properties for solders, bullets, and plain bearings. It improves the rigidity of lead-alloy plates in lead–acid batteries. Antimony trioxide is a prominent additive for halogen-containing flame retardants. Antimony is used as a dopant in semiconductor devices.

  1. ^ "Standard Atomic Weights: Antimony". CIAAW. 1993.
  2. ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (4 May 2022). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  3. ^ a b c Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
  4. ^ Anastas Sidiropoulos (2019). "Studies of N-heterocyclic Carbene (NHC) Complexes of the Main Group Elements" (PDF). p. 39. doi:10.4225/03/5B0F4BDF98F60. S2CID 132399530.
  5. ^ Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (PDF) (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
  6. ^ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
  7. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  8. ^ David Kimhi's Commentary on Isaiah 4:30 and I Chronicles 29:2; Hebrew: פוך/כְּחֻל, Aramaic: כּוּחְלִי/צדידא; Arabic: كحل, and which can also refer to antimony trisulfide. See also Z. Dori, Antimony and Henna (Heb. הפוך והכופר), Jerusalem 1983 (Hebrew).


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Antimony

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Antimony is a chemical element; it has symbol Sb (from Latin stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as...

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Antimony trioxide

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Antimony(III) oxide is the inorganic compound with the formula Sb2O3. It is the most important commercial compound of antimony. It is found in nature as...

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Pnictogen

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trihalides. Antimony forms antimony(III) oxide and antimonite but not oxyacids. Its trihalides, antimony trifluoride, antimony trichloride, antimony tribromide...

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Antimony sulfide

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Antimony sulfide may refer to either of two compounds of antimony and sulfur: Antimony trisulfide, Sb2S3 Antimony pentasulfide, Sb2S5, known as antimony...

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Antimony trichloride

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butter of antimony. Antimony trichloride is prepared by reaction of chlorine with antimony, antimony tribromide, antimony trioxide, or antimony trisulfide...

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Antimony oxide

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Antimony oxide may refer to any of the following: Diantimony tetroxide, Sb2O4 Antimony trioxide, Sb2O3 Antimony pentoxide, Sb2O5 Antimony hexitatridecoxide...

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Stibnite

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metalloid antimony. The name is derived from the Greek στίβι stibi through the Latin stibium as the former name for the mineral and the element antimony. Stibnite...

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Isotopes of antimony

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Antimony (51Sb) occurs in two stable isotopes, 121Sb and 123Sb. There are 35 artificial radioactive isotopes, the longest-lived of which are 125Sb, with...

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Antimony trisulfide

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Antimony trisulfide (Sb2S3) is found in nature as the crystalline mineral stibnite and the amorphous red mineral (actually a mineraloid) metastibnite....

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Polyethylene terephthalate

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temperature. Antimony (Sb) is a metalloid element that is used as a catalyst in the form of compounds such as antimony trioxide (Sb2O3) or antimony triacetate...

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Antimony pentoxide

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Antimony pentoxide (molecular formula: Sb2O5) is a chemical compound of antimony and oxygen. It contains antimony in the +5 oxidation state. Antimony...

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Antimony Peak

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Antimony Peak is a steep peak located in southern Kern County, in the San Emigdio Mountains of the Transverse Ranges of California. It is the taller one...

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Antimony tribromide

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Antimony tribromide (SbBr3) is a chemical compound containing antimony in its +3 oxidation state. Antimony tribromide may be made by the reaction of antimony...

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Antimony fluoride

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Antimony fluoride may refer to either of the following: Antimony trifluoride, SbF3 Antimony pentafluoride, SbF5 This set index article lists chemical...

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Antimony nitride

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Antimony nitride, also called antimony mononitride, is an inorganic compound with the chemical formula SbN. Containing only antimony and nitrogen, this...

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Antimony potassium tartrate

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Antimony potassium tartrate, also known as potassium antimonyl tartrate, potassium antimontarterate, or tartar emetic, has the formula K2Sb2(C4H2O6)2....

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Antimony electrode

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The antimony electrode has been investigated for its ability to function as a pH electrode. The electrode is made of elemental antimony. The electrochemical...

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Antimony chloride

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Antimony chloride may refer to either of the following: Antimony trichloride, SbCl3 Antimony pentachloride, SbCl5 This disambiguation page lists articles...

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Antimony oxychloride

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Antimony oxychloride, known since the 15th century, has been known by a plethora of alchemical names. Since the compound functions as both an emetic and...

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Antimony regulus

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Antimony regulus or antimony metal is a partially purified form of the element antimony. In modern commerce, it typically contains 0.4% to 1.0% of impurities...

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Antimony pentafluoride

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Antimony pentafluoride is the inorganic compound with the formula SbF5. This colourless, viscous liquid is a strong Lewis acid and a component of the superacid...

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Antimony pentachloride

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Antimony pentachloride is a chemical compound with the formula SbCl5. It is a colourless oil, but typical samples are yellowish due to dissolved chlorine...

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Bismuth antimonide

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Bismuth antimonides, Bismuth-antimonys, or Bismuth-antimony alloys, (Bi1−xSbx) are binary alloys of bismuth and antimony in various ratios. Some, in particular...

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Pewter

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Pewter (/ˈpjuːtər/) is a malleable metal alloy consisting of tin (85–99%), antimony (approximately 5–10%), copper (2%), bismuth, and sometimes silver. In the...

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Antimony pill

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An antimony pill is a pill made from metallic antimony. It was a popular remedy in the nineteenth century to purge and revitalise the bowels. In use,...

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Naples yellow

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Naples yellow, also called antimony yellow or lead antimonate yellow, is an inorganic pigment that largely replaced lead-tin-yellow and has been used in...

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Type metal

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metal typesetting. Historically, type metal was an alloy of lead, tin and antimony in different proportions depending on the application, be it individual...

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Antimony pentasulfide

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Antimony pentasulfide is an inorganic compound of antimony and sulfur, also known as antimony red. It is a nonstoichiometric compound with a variable...

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