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Nontrigonal pnictogen compounds information


Nontrigonal pnictogen compounds
General structure of nontrigonal pnictogen compounds

Nontrigonal pnictogen compounds refer to tricoordinate trivalent pnictogen (phosphorus, arsenic, antimony and bismuth: P, As, Sb and Bi) compounds that are not of typical trigonal pyramidal molecular geometry. By virtue of their geometric constraint, these compounds exhibit distinct electronic structures and reactivities, which bestow on them potential to provide unique nonmetal platforms for bond cleavage reactions.

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Nontrigonal pnictogen compounds

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Nontrigonal pnictogen compounds refer to tricoordinate trivalent pnictogen (phosphorus, arsenic, antimony and bismuth: P, As, Sb and Bi) compounds that...

Word Count : 1861

Bismuthinidene

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tert-butyl imino version of this compound at the M06/cc-pVTZ level of theory reveals that, as in other nontrigonal pnictogen compounds, the central bismuth atom...

Word Count : 4397

Phosphetane

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T. (2019-05-20). "Validating the Biphilic Hypothesis of Nontrigonal Phosphorus(III) Compounds". Angewandte Chemie International Edition. 58 (21): 6993–6998...

Word Count : 5154

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