Oxidative decarboxylation is a decarboxylation reaction caused by oxidation. Most are accompanied by α- Ketoglutarate α- Decarboxylation caused by dehydrogenation of hydroxyl carboxylic acids such as carbonyl carboxylic acid, malic acid, isocitric acid, etc.[1]
^Dejun, Zhou (2012). Organic reaction mechanism. Chemical Industry Press.
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Oxidativedecarboxylation is a decarboxylation reaction caused by oxidation. Most are accompanied by α- Ketoglutarate α- Decarboxylation caused by dehydrogenation...
uncatalyzed decarboxylation of a picolinic acid gives a stable carbene that attacks a carbonyl electrophile. Oxidativedecarboxylations are generally...
or 2 × 2.5 ATP (malate-aspartate shuttle) 2 NADH+H+ from the oxidativedecarboxylation of pyruvate and 6 from Krebs cycle: 8 × 2.5 ATP 2 FADH2 from the...
Pyruvate decarboxylation or pyruvate oxidation, also known as the link reaction (or oxidativedecarboxylation of pyruvate), is the conversion of pyruvate...
in the pathway. The first is the oxidative phase, in which NADPH is generated, and the second is the non-oxidative synthesis of 5-carbon sugars. For...
acid has never been reported. This reaction is different from oxidativedecarboxylation, which proceeds through a radical mechanism and is characterised...
and carbon dioxide via various means of oxidativedecarboxylation. Henry Drysdale Dakin discovered this oxidation in 1916. From aryl carboxylic acids (Letts...
(750 psi)) yielding ethylene carbonate and its subsequent hydrolysis with decarboxylation: ( CH 2 CH 2 ) O + CO 2 ⟶ ( O − CH 2 CH 2 − O ) C = O ethylene carbonate...
coproporphyrinogen III oxidase is a radical SAM enzyme that catalyzes the oxidativedecarboxylation of coproporphyrinogen III to protoporhyrinogen IX, an important...
bromine in water to form the aldonic acid, which can then undergo oxidativedecarboxylation with hydrogen peroxide and iron (III) acetate to form arabinose...
(EC 1.1.1.42) and (EC 1.1.1.41) is an enzyme that catalyzes the oxidativedecarboxylation of isocitrate, producing alpha-ketoglutarate (α-ketoglutarate)...
results in increased oxidative stress within the cell as it is a required cofactor in the production of GSH, and this oxidative stress can result in DNA...
two carbon acetate units. The glyoxylate cycle bypasses the two oxidativedecarboxylation reactions of the TCA cycle and directly converts isocitrate through...
dehydrogenase, an oxidoreductase (EC 1.2.4.1), that catalyzes the oxidativedecarboxylation of pyruvate to acetyl-CoA. Pyruvate decarboxylase occurs as a...
nitrile synthesis between benzyl chloride and sodium cyanide and by oxidativedecarboxylation of phenylalanine. Benzyl cyanides can also be prepared by arylation...
additional methylene in the aliphatic chain. Many acids undergo oxidativedecarboxylation. Enzymes that catalyze these reactions are known as carboxylases...
gene on chromosome 2. Isocitrate dehydrogenases catalyze the oxidativedecarboxylation of isocitrate to 2-oxoglutarate. These enzymes belong to two distinct...
Benzoic acid is mainly consumed in the production of phenol by oxidativedecarboxylation at 300−400 °C: C 6 H 5 CO 2 H + 1 2 O 2 ⟶ C 6 H 5 OH + CO 2 {\displaystyle...
4-Hydroxy-3-methoxyphenylglyoxylic acid (3) to vanillin (4) by oxidativedecarboxylation. 15% of the world's production of vanillin is produced from lignosulfonates...
diphosphorylated thiamine derivative, TPP, was a cofactor required for the oxidativedecarboxylation of pyruvate. Some contributors to the discovery of thiamine Takaki...
α-ketomethylene-cyclopropylpropionic acid (KMCPP), which then forms MCPA through oxidativedecarboxylation. Hypoglycin A (and hypoglycin B) is found in the ackee fruit,...
tricarboxylic acid cycle. It's a keto acid, formed during the oxidativedecarboxylation of isocitrate to alpha-ketoglutarate, which is catalyzed by the...
alpha-keto acid, which is converted to isobutyryl-CoA through oxidativedecarboxylation by the branched-chain α-ketoacid dehydrogenase complex. This is...