The ball-and-stick model of diisobutylaluminium hydride, showing aluminium as pink, carbon as black, and hydrogen as white.
Organoaluminium chemistry is the study of compounds containing bonds between carbon and aluminium. It is one of the major themes within organometallic chemistry.[1][2] Illustrative organoaluminium compounds are the dimer trimethylaluminium, the monomer triisobutylaluminium, and the titanium-aluminium compound called Tebbe's reagent. The behavior of organoaluminium compounds can be understood in terms of the polarity of the C−Al bond and the high Lewis acidity of the three-coordinated species. Industrially, these compounds are mainly used for the production of polyolefins.
^D. F. Shriver; P. W. Atkins (2006). Inorganic Chemistry. Oxford University Press. ISBN 978-0199264636.
^M. Witt; H. W. Roesky (2000). "Organoaluminum chemistry at the forefront of research and development" (PDF). Curr. Sci. 78 (4): 410. Archived from the original (PDF) on 2014-10-06.
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Organoaluminiumchemistry is the study of compounds containing bonds between carbon and aluminium. It is one of the major themes within organometallic...
1898 – 12 August 1973) was a German chemist who won the Nobel Prize in Chemistry in 1963, with Giulio Natta, for work on polymers. The Nobel Committee...
not form bridged dimers as organoaluminium compounds do. Organogallium compounds are also less reactive than organoaluminium compounds. They do form stable...
aluminium hydride is a powerful reducing agent used in organic chemistry. Organoaluminiums are used as Lewis acids and co-catalysts. Methylaluminoxane is...
these catalysts are prepared by treating titanium chlorides with organoaluminium compounds, such as triethylaluminium. In some cases, the catalyst is...
Triethylaluminium is one of the simplest examples of an organoaluminium compound. Despite its name the compound has the formula Al2(C2H5)6 (abbreviated...
RSnCl3 A related method involves redistribution of tin halides with organoaluminium compounds. The mixed organo-halo tin compounds can be converted to...
Trimethylaluminium is one of the simplest examples of an organoaluminium compound. Despite its name it has the formula Al2(CH3)6 (abbreviated as Al2Me6...
tributyltin azide has been replaced by the less toxic trioctyltin azide and organoaluminium azides. Tributyl tin compounds are highly toxic and have penetrating...
Emeléus HJ, Nyholm R (1973). The Chemistry of Aluminium, Gallium, Indium and Thallium : Comprehensive Inorganic Chemistry. Saint Louis: Elsevier Science...
demonstrated that the N-aluminylene could act as an important precursor to organoaluminium compounds. In these reactions, the aluminylene performs cycloaddition...
Triisobutylaluminium (TiBA) is an organoaluminium compound with the formula Al(CH2CH(CH3)2)3. This colorless pyrophoric liquid is mainly used to make...
often prepared by in-situ activation of a metal halide (MClx) using organoaluminium or organotin compounds, e.g. combining MClx–EtAlCl2. A typical catalyst...
acetylacetonate with organoaluminium activators. Titanium compounds Chromium compounds Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements...
C14H10E2. Electrophiles include ketones, CO2, organotin chlorides, and organoaluminium chlorides. Ethylene inserts into one Mg-C bond. Hydrogen induces release...
formula (i-Bu2AlH)2, where i-Bu represents isobutyl (-CH2CH(CH3)2). This organoaluminium compound is a reagent in organic synthesis. Like most organoaluminum...
respectively. Lithium aluminium hydride (LAH) is widely used in organic chemistry as a reducing agent. It is more powerful than the related reagent sodium...
Diethylaluminium chloride, abbreviated DEAC, is an organoaluminium compound. Although often given the chemical formula (C2H5)2AlCl, it exists as a dimer...
ethylaluminium sesquichloride, a precursor to polymers and other useful organoaluminium compounds. Chloroethane is used to convert cellulose to ethylcellulose...
of ethene and propene. There are also some heterocyclic and cluster organoaluminium compounds involving Al–N bonds. The industrially most important aluminium...
catalysis. The precatalysts, e.g. titanium trichloride, are activated by organoaluminium compounds, which function as catalyst activators. Metal oxides are...
Ethylaluminium sesquichloride, also called EASC, is an industrially important organoaluminium compound used primarily as a precursor to triethylaluminium and as...
not form bridged dimers as organoaluminium compounds do. Organogallium compounds are also less reactive than organoaluminium compounds. They do form stable...
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