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Ethylaluminium sesquichloride information


Ethylaluminium sesquichloride
Names
IUPAC name
Chloro(diethyl)alumane; dichloro(ethyl)alumane(1)
Other names
Ethylaluminum sesquichloride (EASC)
Identifiers
CAS Number
  • 12075-68-2 checkY
3D model (JSmol)
  • (separate): Interactive image
  • (together): Interactive image
ChemSpider
  • 21171404
ECHA InfoCard 100.031.931 Edit this at Wikidata
EC Number
  • 235-137-7
PubChem CID
  • 25508
UN number 3052
CompTox Dashboard (EPA)
  • DTXSID4027737 Edit this at Wikidata
InChI
  • InChI=1S/3C2H5.2Al.3ClH/c3*1-2;;;;;/h3*1H2,2H3;;;3*1H/q;;;+1;+2;;;/p-3
    Key: LDXMUMPEDOQULK-UHFFFAOYSA-K
SMILES
  • (separate): CC[Al](CC)Cl.CC[Al](Cl)Cl
  • (together): CC[Al-]1(Cl)[Cl+][Al-]([Cl+]1)(CC)CC
Properties
Chemical formula
(C2H5)2AlCl•Cl2AlC2H5
Molar mass 247.51 g/mol
Appearance Clear to yellow liquid
Density 1.092 g/cm3
Melting point −50 °C (−58 °F; 223 K)
Boiling point 204 °C (399 °F; 477 K)
Hazards
GHS labelling:
Pictograms
GHS02: FlammableGHS05: Corrosive
Signal word
Danger
Hazard statements
H225, H250, H260, H314
Precautionary statements
P210, P222, P223, P231+P232, P233, P240, P241, P242, P243, P260, P264, P280, P301+P330+P331, P302+P334, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P335+P334, P363, P370+P378, P402+P404, P403+P235, P405, P422, P501
Flash point −20 °C (−4 °F; 253 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Ethylaluminium sesquichloride, also called EASC, is an industrially important organoaluminium compound used primarily as a precursor to triethylaluminium and as a catalyst component in Ziegler–Natta type systems for olefin and diene polymerizations. Other applications include use in alkylation reactions and as a catalyst component in linear oligomerization and cyclization of unsaturated hydrocarbons. EASC is a colourless liquid, spontaneously combustible in air and reacts violently when in contact with water and many other compounds.[1]

  1. ^ Aluminum alkyls. Albemarle Corporation, 2010

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Ethylaluminium sesquichloride

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Ethylaluminium sesquichloride, also called EASC, is an industrially important organoaluminium compound used primarily as a precursor to triethylaluminium...

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Triethylaluminium

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from ethylaluminium sesquichloride (Al2Cl3Et3), which arises by treating aluminium powder with chloroethane. Reduction of ethylaluminium sesquichloride with...

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Chloroethane

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inexpensive ethylating agent. It reacts with aluminium metal to give ethylaluminium sesquichloride, a precursor to polymers and other useful organoaluminium compounds...

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Diethylaluminium chloride

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octet rule. Diethylaluminium chloride can be produced from ethylaluminium sesquichloride, (C2H5)3Al2Cl3, by reduction with sodium: 2 (C2H5)3Al2Cl3 +...

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List of UN numbers 1901 to 2000

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(UN No. no longer in use) UN 1925 ? (UN No. no longer in use) Ethylaluminium sesquichloride (UN No. no longer in use) UN 1926 ? (UN No. no longer in use)...

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Organoaluminium chemistry

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called ethylaluminium sesquichloride. The term sesquichloride refers to the fact that, on average, the Cl:Al ratio is 1.5. These sesquichlorides can be...

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