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Fatty acid methyl ester information


Fatty acid methyl esters (FAME) are a type of fatty acid ester that are derived by transesterification of fats with methanol. The molecules in biodiesel are primarily FAME, usually obtained from vegetable oils by transesterification. They are used to produce detergents and biodiesel.[1] FAME are typically produced by an alkali-catalyzed reaction between fats and methanol in the presence of base such as sodium hydroxide, sodium methoxide[2] or potassium hydroxide. One reason for using FAME (fatty acid methyl esters) in biodiesel production, rather than free fatty acids, is to mitigate the potential corrosion they can cause to metals of engines, production facilities, and related infrastructure. While free fatty acids are only mildly acidic, over time they can lead to cumulative corrosion. In contrast, their esters, such as FAME, are less corrosive and therefore preferred for biodiesel production. As an improved quality, FAMEs also usually have about 12-15 units higher cetane number than their unesterified counterparts.[3]

  1. ^ Anneken, David J.; Both, Sabine; Christoph, Ralf; Fieg, Georg; Steinberner, Udo; Westfechtel, Alfred (2006). "Fatty Acids". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a10_245.pub2. ISBN 9783527306732. OCLC 910197915.
  2. ^ Vyas, Amish P.; Verma, Jaswant L.; Subrahmanyam, N. (2010). "A review on FAME production processes". Fuel. 89 (1): 1–9. doi:10.1016/j.fuel.2009.08.014. ISSN 0016-2361.
  3. ^ Schobert, Harold H. (2013). Chemistry of Fossil Fuels and Biofuels. Cambridge, NY: Cambridge University Press. pp. 62–64. doi:10.1017/CBO9780511844188. ISBN 9780511844188. OCLC 823724682.

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Fatty acid methyl ester

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exist as three main classes of esters: triglycerides, phospholipids, and cholesteryl esters. In any of these forms, fatty acids are both important dietary...

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isomer of oleic acid is petroselinic acid. In chemical analysis, fatty acids are separated by gas chromatography of their methyl ester derivatives. Alternatively...

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Ester

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derivatives of acidic hydrogen of other acids are esters as well (e.g. amides), but not according to the IUPAC. Glycerides are fatty acid esters of glycerol;...

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triacylglycerol, TAG, or triacylglyceride) is an ester derived from glycerol and three fatty acids. Triglycerides are the main constituents of body fat...

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The methyl ester of ricinoleic acid, obtained from castor bean oil, is the main commercial precursor to enanthic acid. It is pyrolyzed to the methyl ester...

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combine (by means of ester bonds) to form triglycerides (also known as "triacylglycerols" – to distinguish them from fatty "acids" – or simply as "fat")...

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Biodiesel

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oils, animal fats, or recycled greases, and consisting of long-chain fatty acid esters. It is typically made from fats. The roots of biodiesel as a fuel...

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EN 590

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countries. Based on 98/70/EG it allows the blending of up to 7% fatty acid methyl ester biodiesel with 'conventional' diesel - a 7:93 mix. The EN 590 had...

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biolipid/methanol reaction into fatty-acid methyl esters. Fat interesterification is used in the food industry to rearrange the fatty acids of triglycerides in edible...

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groups, or H in the case of esters of formic acid. Glycerides, which are fatty acid esters of glycerol, are important esters in biology, being one of the...

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18:2 cis-9,12. A linoleate is a salt or ester of this acid. Linoleic acid is a polyunsaturated, omega-6 fatty acid. It is a colorless liquid that is virtually...

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constituent fatty acids, which can be analyzed in various ways. In one approach, fats undergo transesterification to give fatty acid methyl esters (FAMEs)...

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Sucrose esters or sucrose fatty acid esters are a group of non-naturally occurring surfactants chemically synthesized from the esterification of sucrose...

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Toxicodendron succedaneum

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extracted by expression, heat, or the action of solvents. The fatty-acid methyl ester of the kernel oil meets all of the major biodiesel requirements...

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Valeric acid

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the synthesis of its esters. Salts and esters of valeric acid are known as valerates or pentanoates. Volatile esters of valeric acid tend to have pleasant...

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classified as a noxious weed in Australia and New Zealand. The fatty-acid methyl ester of the kernel oil meets all of the major biodiesel requirements...

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The salts and esters of stearic acid are called stearates. As its ester, stearic acid is one of the most common saturated fatty acids found in nature...

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Butyric acid

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isomer. Salts and esters of butyric acid are known as butyrates or butanoates. The acid does not occur widely in nature, but its esters are widespread....

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Propionic acid

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3CH 2CO− 2 as well as the salts and esters of propionic acid are known as propionates or propanoates. Propionic acid was first described in 1844 by Johann...

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Terminalia bellirica

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Terminalia bellirica seeds have an oil content of 40%, whose fatty acid methyl ester meets all of the major biodiesel requirements in the US (ASTM D...

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Palmitic acid

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Palmitic acid (hexadecanoic acid in IUPAC nomenclature) is a fatty acid with a 16-carbon chain. It is the most common saturated fatty acid found in animals...

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