Chaconine information

Chaconine
	; 3D model of chaconine using MolView
Names
	IUPAC name Solanid-5-en-3β-yl α-L-rhamnopyranosyl-(1→2)-[α-L-rhamnopyranosyl-(1→4)]-β-D-glucopyranoside
	Systematic IUPAC name (2S,2′S,3R,3′R,4R,4′R,5R,5′R,6S,6′S)-2,2′-{[(2R,3S,4S,5R,6R)-4-Hydroxy-2-(hydroxymethyl)-6-{[(2S,4aR,4bS,6aS,6bR,7S,7aR,10S,12aS,13aS,13bS)-4a,6a,7,10-tetramethyl-1,3,4,4a,4b,5,6,6a,6b,7,7a,8,9,10,11,12a,13,13a,13b,14-icosahydro-2H-naphtho[2′,1′:4,5]indeno[1,2-b]indolizin-2-yl]oxy}oxane-3,5-diyl]bis(oxy)}bis(6-methyloxane-3,4,5-triol)
	Other names α-Chaconine, Chaconine
Identifiers
CAS Number	20562-03-2 ;
3D model (JSmol)	Interactive image;
Beilstein Reference	77396
ChEBI	CHEBI:CHEBI:10219;
ChEMBL	ChEMBL2288884;
ChemSpider	391274 ;
ECHA InfoCard	100.161.828
PubChem CID	442971;
UNII	5QOL0LIM81 ;
	InChI InChI=1S/C45H73NO14/c1-19-7-10-28-20(2)31-29(46(28)17-19)16-27-25-9-8-23-15-24(11-13-44(23,5)26(25)12-14-45(27,31)6)57-43-40(60-42-37(53)35(51)33(49)22(4)56-42)38(54)39(30(18-47)58-43)59-41-36(52)34(50)32(48)21(3)55-41/h8,19-22,24-43,47-54H,7,9-18H2,1-6H3/t19-,20+,21-,22-,24-,25+,26-,27-,28+,29-,30+,31-,32-,33-,34+,35+,36+,37+,38-,39+,40+,41-,42-,43+,44-,45-/m0/s1 Key: TYNQWWGVEGFKRU-AJDPQWBVSA-N ; InChI=1/C45H73NO14/c1-19-7-10-28-20(2)31-29(46(28)17-19)16-27-25-9-8-23-15-24(11-13-44(23,5)26(25)12-14-45(27,31)6)57-43-40(60-42-37(53)35(51)33(49)22(4)56-42)38(54)39(30(18-47)58-43)59-41-36(52)34(50)32(48)21(3)55-41/h8,19-22,24-43,47-54H,7,9-18H2,1-6H3/t19-,20+,21-,22-,24-,25+,26-,27-,28+,29-,30+,31-,32-,33-,34+,35+,36+,37+,38-,39+,40+,41-,42-,43+,44-,45-/m0/s1 Key: TYNQWWGVEGFKRU-AJDPQWBVBS;
	SMILES O([C@H]8[C@H](O[C@@H]4C/C3=C/C[C@H]2[C@@H]5C[C@@H]1N6[C@@H]([C@@H](C)[C@@H]1[C@@]5(C)CC[C@@H]2[C@@]3(C)CC4)CC[C@H](C)C6)O[C@H](CO)[C@@H](O[C@@H]7O[C@@H](C)[C@H](O)[C@@H](O)[C@H]7O)[C@@H]8O)[C@@H]9O[C@H]([C@H](O)[C@@H](O)[C@H]9O)C;
Properties
Chemical formula	C45H73NO14
Molar mass	852.072 g·mol−1
Melting point	243 °C (469 °F; 516 K)
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

α-Chaconine is a steroidal glycoalkaloid that occurs in plants of the family Solanaceae. It is a natural toxicant produced in green potatoes and gives the potato a bitter taste.^[1] Tubers produce this glycoalkaloid in response to stress, providing the plant with insecticidal and fungicidal properties.^[1] It belongs to the chemical family of saponins. Since it causes physiological effects on individual organism, chaconine is considered to be defensive allelochemical.^[2] Solanine is a related substance that has similar properties.

^ ^a ^b Kuiper-Goodman, T.; Nawrot, P.S. "Toxin profile: Solanine and Chaconine IPCS, INCHEM". Archived from the original on 2001-02-25. Retrieved 2021-03-15.
^ Saponins used in traditional and modern medicine. Boston, MA: Springer. 1996. pp. 277–295. ISBN 978-1-4899-1369-2.

[toxin-1] Kuiper-Goodman, T.; Nawrot, P.S. "Toxin profile: Solanine and Chaconine IPCS, INCHEM". Archived from the original on 2001-02-25. Retrieved 2021-03-15.

[2] Saponins used in traditional and modern medicine. Boston, MA: Springer. 1996. pp. 277–295. ISBN 978-1-4899-1369-2.

Chaconine information

and 29 Related for: Chaconine information

Chaconine

Solanine

Fish

Solanum jamesii

Solanum americanum

Vegetable

Tomato

Potato

Solanaceae

Clostridium botulinum

Ricin

Botulinum toxin

Tetrodotoxin

Exotoxin

Poison dart frog

Shiga toxin

Ciguatera fish poisoning

Lipopolysaccharide

Neurotoxin

Cardiotoxicity

Muscimol

Solanidine

Snake venom

Clostridium perfringens

Aflatoxin B1

Tetanus toxin

Virulence factor

Amatoxin

Toxin

Names

3D model of chaconine using MolView
IUPAC name Solanid-5-en-3β-yl α-L-rhamnopyranosyl-(1→2)-[α-L-rhamnopyranosyl-(1→4)]-β-D-glucopyranoside
Systematic IUPAC name (2S,2′S,3R,3′R,4R,4′R,5R,5′R,6S,6′S)-2,2′-{[(2R,3S,4S,5R,6R)-4-Hydroxy-2-(hydroxymethyl)-6-{[(2S,4aR,4bS,6aS,6bR,7S,7aR,10S,12aS,13aS,13bS)-4a,6a,7,10-tetramethyl-1,3,4,4a,4b,5,6,6a,6b,7,7a,8,9,10,11,12a,13,13a,13b,14-icosahydro-2H-naphtho[2′,1′:4,5]indeno[1,2-b]indolizin-2-yl]oxy}oxane-3,5-diyl]bis(oxy)}bis(6-methyloxane-3,4,5-triol)
Other names α-Chaconine, Chaconine
Identifiers
CAS Number	20562-03-2^Y
3D model (JSmol)	Interactive image
Beilstein Reference	77396
ChEBI	CHEBI:CHEBI:10219
ChEMBL	ChEMBL2288884
ChemSpider	391274^N
ECHA InfoCard	100.161.828
PubChem CID	442971
UNII	5QOL0LIM81^Y
InChI InChI=1S/C45H73NO14/c1-19-7-10-28-20(2)31-29(46(28)17-19)16-27-25-9-8-23-15-24(11-13-44(23,5)26(25)12-14-45(27,31)6)57-43-40(60-42-37(53)35(51)33(49)22(4)56-42)38(54)39(30(18-47)58-43)59-41-36(52)34(50)32(48)21(3)55-41/h8,19-22,24-43,47-54H,7,9-18H2,1-6H3/t19-,20+,21-,22-,24-,25+,26-,27-,28+,29-,30+,31-,32-,33-,34+,35+,36+,37+,38-,39+,40+,41-,42-,43+,44-,45-/m0/s1^N Key: TYNQWWGVEGFKRU-AJDPQWBVSA-N^N InChI=1/C45H73NO14/c1-19-7-10-28-20(2)31-29(46(28)17-19)16-27-25-9-8-23-15-24(11-13-44(23,5)26(25)12-14-45(27,31)6)57-43-40(60-42-37(53)35(51)33(49)22(4)56-42)38(54)39(30(18-47)58-43)59-41-36(52)34(50)32(48)21(3)55-41/h8,19-22,24-43,47-54H,7,9-18H2,1-6H3/t19-,20+,21-,22-,24-,25+,26-,27-,28+,29-,30+,31-,32-,33-,34+,35+,36+,37+,38-,39+,40+,41-,42-,43+,44-,45-/m0/s1 Key: TYNQWWGVEGFKRU-AJDPQWBVBS
SMILES O([C@H]8[C@H](O[C@@H]4C/C3=C/C[C@H]2[C@@H]5C[C@@H]1N6[C@@H]([C@@H](C)[C@@H]1[C@@]5(C)CC[C@@H]2[C@@]3(C)CC4)CC[C@H](C)C6)O[C@H](CO)[C@@H](O[C@@H]7O[C@@H](C)[C@H](O)[C@@H](O)[C@H]7O)[C@@H]8O)[C@@H]9O[C@H]([C@H](O)[C@@H](O)[C@H]9O)C
Properties
Chemical formula	C₄₅H₇₃NO₁₄
Molar mass	852.072 g·mol⁻¹
Melting point	243 °C (469 °F; 516 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references