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Bismuth antimonide information


Bismuth antimonide
Identifiers
CAS Number
  • 12323-19-2
3D model (JSmol)
  • Interactive image
ChemSpider
  • 11201349
ECHA InfoCard 100.204.020 Edit this at Wikidata
PubChem CID
  • 69145232.1.1InChI
InChI
  • InChI=1S/2Bi.2Sb
  • Key: AEMQIQQWIVNHAU-UHFFFAOYSA-N
SMILES
  • [Sb].[Sb].[Bi].[Bi]
Properties
Chemical formula
BiSb
Molar mass 330.74 g/mol
Appearance Faint-grey to dark-grey powder
Density 8.31 g/cm3
Solubility insoluble
Structure
Crystal structure
Hexagonal, A7, SpaceGroup = R-3m, No. 166
Lattice constant
a = 4.546A, c = 11.860A[1]
Hazards
GHS labelling:
Pictograms
GHS07: Exclamation markGHS09: Environmental hazard
Signal word
Warning
Hazard statements
H302, H332, H411
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Safety data sheet (SDS) [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Bismuth antimonides, Bismuth-antimonys, or Bismuth-antimony alloys, (Bi1−xSbx) are binary alloys of bismuth and antimony in various ratios.

Some, in particular Bi0.9Sb0.1, were the first experimentally-observed three-dimensional topological insulators, materials that have conducting surface states but have an insulating interior.[2]

Various BiSb alloys also superconduct at low temperatures,[3] are semiconductors,[1] and are used in thermoelectric devices.[4]

Bismuth antimonide itself (see box to right) is sometimes described as Bi2Sb2.[5]

  1. ^ a b Jain, A. L. (1959). "Temperature Dependence of the Electrical Properties of Bismuth-Antimony Alloys". Physical Review. 114 (6): 1518–1528. Bibcode:1959PhRv..114.1518J. doi:10.1103/physrev.114.1518.
  2. ^ Hsieh, D.; Qian, D.; Wray, L.; Xia, Y.; Hor, Y. S.; Cava, R. J.; Hasan, M. Z. (2008-04-24). "A topological Dirac insulator in a quantum spin Hall phase". Nature. 452 (7190): 970–974. arXiv:0902.1356. Bibcode:2008Natur.452..970H. doi:10.1038/nature06843. ISSN 0028-0836. PMID 18432240. S2CID 4402113.
  3. ^ Zally, G. D.; Mochel, J. M. (1971). "Fluctuation Heat Capacity in Superconducting Thin Films of Amorphous BiSb". Physical Review Letters. 27 (25): 1710–1712. Bibcode:1971PhRvL..27.1710Z. doi:10.1103/physrevlett.27.1710.
  4. ^ Smith, G. E.; Wolfe, R. (1962-03-01). "Thermoelectric Properties of Bismuth-Antimony Alloys". Journal of Applied Physics. 33 (3): 841–846. Bibcode:1962JAP....33..841S. doi:10.1063/1.1777178. ISSN 0021-8979.
  5. ^ PubChem. "Bismuth, compd. with antimony (1:1)". pubchem.ncbi.nlm.nih.gov. Retrieved 2021-06-15.

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