Transition metal nitroso complexes information

Transition metal nitroso complexes are coordination complexes containing one or more organonitroso ligands (RNO). Organic nitroso compounds bind to metals...

serve as a ligands giving transition metal nitroso complexes. Many reaction exists which make use of an intermediate nitroso compound, such as the Barton...

Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transition metal. Many kinds of nitrosyl complexes are known, which vary...

temperature, but it will nevertheless react with lithium metal and some transition metal complexes. This is due to its bonding, which is unique among the...

dinitrogen complex to be discovered was [Ru(NH3)5(N2)]2+ (see figure at right), and soon many other such complexes were discovered. These complexes, in which...

terminal vinylidene metal complex chemistry through the dicyanomethylene/oxygen analogy: dicyanovinylidene transition metal complexes". Coordination Chemistry...

dinitrosoalkane cobalt complexes. The dinitrosyl intermediate is known for its alkene binding capability. The resulting dinitrosoalkane cobalt complexes are capable...

equilibrium. In organometallic species, metal complexes with the formulae LnMCRR' are often described as carbene complexes. Such species do not however react...

handle in the absence of stabilization provided by the transition metal. Their metal complexes are deeply colored and water-soluble. They undergo a keto-enol...

to alkynes in carbocyanation: Nitriles are precursors to transition metal nitrile complexes, which are reagents and catalysts. Examples include...

peroxides are prone to spontaneous decomposition or even combustion. Metal complexes are useful catalysts for epoxidations involving hydrogen peroxide and...

S-nitrosothiols, certain organic nitrates, nitrosylated metal complexes, dinitrosyl iron complexes (DNIC), and even nitrite anions (NO2− ) under hypoxic...

{(CH3)2C=}}{\color {red}{\ce {CH2}}}} In transition metal alkene complexes, alkenes serve as ligands for metals. In this case, the π electron density is...

especially DMSO, form coordination complexes with transition metals. Depending on the hard-soft properties of the metal, the sulfoxide binds through either...

important part of cell signalling. Coordination of NO to transition metals to give metal nitrosyl complexes is also referred to as nitrosylation. Nitrosation...

reaction is important in nature. With metal ions, thiolates behave as ligands to form transition metal thiolate complexes. The term mercaptan is derived from...

to give the hydroxyalkyne. Alkynes form complexes with transition metals. Such complexes occur also in metal catalyzed reactions of alkynes such as alkyne...

and "Br+" in organic synthesis. In coordination chemistry transition metal imido complexes feature the NR2- ligand. They are similar to oxo ligands in...

N-methoxydiazeniumdiolate. Nitric oxide reacts with transition metals to give complexes called metal nitrosyls. The most common bonding mode of nitric oxide...

fundamental ligand in transition metal alkene complexes. One of the first organometallic compounds, Zeise's salt is a complex of ethylene. Useful reagents...

principally operates as a Ca2+ binding protein, it also coordinates other metal ions. For example, in the presence of typical intracellular concentrations...

TNT or tetryl. Under certain conditions a deflagration to detonation transition can occur, just like that of ammonium nitrate. It is rarely used alone...

related anhydrides. Xanthates bind to transition metal cations as bidentate ligands. The charge-neutral complexes are soluble in organic solvents. Xanthates...

addition, both NOS1 and NOS2 have been shown to form ferrous-nitrosyl complexes in their heme prosthetic groups that may act partially to self-inactivate...

relevant. Several transition metal complexes of aldehydes and ketones have been characterized crystallographically. Bent geometry: The metal-oxygen-carbon...

Roth (1986). "Comparative Structural Studies of the First Row Early Transition Metal(III) Chloride Tetrahydrofuran Solvates". Inorg. Chim. Acta. 113: 81...

ligands of the general formula NPR3− form transition metal phosphinimide complexeses. Some of these complexes are potential catalysts for the synthesis...

gives isocyanide dichlorides. Isocyanides form coordination complexes with most transition metals. They behave as electron-rich analogues of carbon monoxide...