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Sodium formate information


Sodium formate
Structural formula of sodium formate
Ball-and-stick model of the formate anion
Ball-and-stick model of the formate anion
Names
Systematic IUPAC name
Sodium methanoate
Other names
  • formic acid, sodium salt
Identifiers
CAS Number
  • 141-53-7 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:62965
ChEMBL
  • ChEMBL183491 ☒N
ChemSpider
  • 8517 checkY
ECHA InfoCard 100.004.990 Edit this at Wikidata
EC Number
  • 205-488-0
E number E237 (preservatives)
PubChem CID
  • 2723810
UNII
  • 387AD98770 checkY
CompTox Dashboard (EPA)
  • DTXSID2027090 Edit this at Wikidata
InChI
  • InChI=1S/CH2O2.Na/c2-1-3;/h1H,(H,2,3);/q;+1/p-1 checkY
    Key: HLBBKKJFGFRGMU-UHFFFAOYSA-M checkY
  • InChI=1/CH2O2.Na/c2-1-3;/h1H,(H,2,3);/q;+1/p-1
    Key: HLBBKKJFGFRGMU-REWHXWOFAN
SMILES
  • [Na+].[O-]C=O
Properties
Chemical formula
HCOONa
Molar mass 68.007 g/mol
Appearance white granules
deliquescent
Density 1.92 g/cm3 (20 °C)
Melting point 253 °C (487 °F; 526 K)
Boiling point decomposes
Solubility in water
43.82 g/100 mL (0 °C)
97.2 g/100 mL (20 °C)
160 g/100 mL (100 °C)
Solubility insoluble in ether
soluble in glycerol, alcohol, formic acid
Thermochemistry
Heat capacity (C)
82.7 J/mol K
Std molar
entropy (S298)
103.8 J/mol K
Std enthalpy of
formation fH298)
-666.5 kJ/mol
Gibbs free energy fG)
-599.9 kJ/mol
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Sodium formate, HCOONa, is the sodium salt of formic acid, HCOOH. It usually appears as a white deliquescent powder.

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Sodium formate

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Sodium formate, HCOONa, is the sodium salt of formic acid, HCOOH. It usually appears as a white deliquescent powder. For commercial use, sodium formate...

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Formate

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hydrogenation catalysts. ethyl formate, CH3CH2(HCOO) sodium formate, Na(HCOO) potassium formate, K(HCOO) caesium formate, Cs(HCOO); see Caesium: Petroleum...

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Methyl formate

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base, such as sodium methoxide: This process, practiced commercially by BASF among other companies gives 96% selectivity toward methyl formate. The catalyst...

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Sodium salts

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acids with sodium hydroxide. Sodium salts can be categorized into: sodium salts of carboxylic acids (e. g. sodium formate, HCOONa, the sodium salt of formic...

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Sodium oxalate

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produces NaHC2O4, monobasic sodium oxalate or sodium hydrogenoxalate. Alternatively, it can be produced by decomposing sodium formate by heating it at a temperature...

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Sodium acetate

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Sodium acetate, CH3COONa, also abbreviated NaOAc, is the sodium salt of acetic acid. This colorless deliquescent salt has a wide range of uses. Sodium...

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Folinic acid

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suitable concentrations of ascorbic acid. The simultaneous addition of sodium formate to such systems resulted in increased citrovorum factor activity in...

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Ethyl formate

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Ethyl formate is an ester formed when ethanol (an alcohol) reacts with formic acid (a carboxylic acid). Ethyl formate has the characteristic smell of...

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Sodium hydroxide

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Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of...

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Sodium chloride

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Sodium chloride /ˌsoʊdiəm ˈklɔːraɪd/, commonly known as edible salt, is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium...

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Formic acid

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is sodium methoxide. Hydrolysis of the methyl formate produces formic acid: HCO2CH3 + H2O → HCOOH + CH3OH Efficient hydrolysis of methyl formate requires...

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Sodium trifluoroacetate

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Sodium trifluoroacetate is a chemical compound with a formula of CF3CO2Na. It is the sodium salt of trifluoroacetic acid. It is used as a source of...

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Calcium formate

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Calcium formate is the calcium salt of formic acid. It is also known as E238. Under this E number it is used as an animal feed preservative within EU...

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Sodium dithionite

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of H− reduces two equivalents of sulfur dioxide. Formate has also been used as the reductant. Sodium dithionite is stable when dry, but aqueous solutions...

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Formic anhydride

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anhydride can be obtained by reaction of formyl fluoride with excess sodium formate and a catalytic amount of formic acid in ether at −78 °C. It can also...

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Nickel formate

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2 H2O Nickel formate can also be synthesized by the reaction of sodium formate with nickel (II) sulphate. As a dihydrate, nickel formate is a green, odorless...

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Nitric oxide

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research. Nitric oxide can also react directly with sodium methoxide, ultimately forming sodium formate and nitrous oxide by way of an N-methoxydiazeniumdiolate...

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Cannizzaro reaction

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this variation, the reductant is formaldehyde, which is oxidized to sodium formate and the other aldehyde chemical is reduced to the alcohol. Thus, the...

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Acetic formic anhydride

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formylating agent. Acetic formic anhydride can be produced by reacting sodium formate with acetyl chloride in anhydrous diethyl ether between 23–27 °C. It...

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List of food additives

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antioxidant Sodium ethyl para-hydroxybenzoate – preservative Sodium ferrocyanide – anti-caking agent Sodium formate – preservative Sodium fumarate – food...

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Deicing

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3COO) 6) Potassium acetate (CH 3COOK) Potassium formate (CHO 2K) Sodium formate (HCOONa) Calcium formate (Ca(HCOO) 2) Urea (CO(NH 2) 2), a common fertilizer...

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Oxalic acid

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as sulfuric acid. Oxalic acid can also be formed by the heating of sodium formate in the presence of an alkaline catalyst. Although it can be readily...

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International Numbering System for Food Additives

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preservative 236 U formic acid preservative 237 U sodium formate preservative 238 U calcium formate preservative 239 E U hexamethylene tetramine (hexamine)...

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Chloral

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produced from chloral. Treating chloral with sodium hydroxide gives chloroform Cl3CH and sodium formate HCOONa. Cl3CCHO + NaOH → Cl3CH + HCOONa Chloral...

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Woolite

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Tetrasodium glutamate diacetate Sodium chloride Proprietary inert filler Sodium formate Fragrance Butylated hydroxytoluene Benzisothiazolinone Methylisothiazolinone...

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Zeolitic imidazolate framework

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solvents for ZIF formation but require bases such as pyridine, TEA, sodium formate, and NaOH. Polymers such as poly(ethylene oxide)–poly(propylene oxide)–poly(ethylene...

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Emil Erlenmeyer

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glycolic acid from unripe grapes (1864), synthesis of sodium oxalate by heating sodium formate (1868), hydrolysis of ether to alcohol (1858), synthesis...

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Solubility table

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133 172 211 234 Sodium fluoride NaF 3.66 4.06 4.22 4.4 4.68 4.89 5.08 Sodium formate HCOONa 43.9 62.5 81.2 102 108 122 138 147 160 Sodium hydrogen carbonate...

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