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Sodium oxalate information


Sodium oxalate
Disodium oxalate
Names
Preferred IUPAC name
Disodium oxalate
Other names
Oxalic acid, disodium salt
Sodium ethanedioate
Identifiers
CAS Number
  • 62-76-0 checkY[1]
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:132764 ☒N
ChEMBL
  • ChEMBL182928 ☒N
ChemSpider
  • 5895 ☒N
ECHA InfoCard 100.000.501 Edit this at Wikidata
EC Number
  • 200-550-3
PubChem CID
  • 6125
RTECS number
  • K11750000
UNII
  • 7U0V68LT9X checkY
CompTox Dashboard (EPA)
  • DTXSID1037018 Edit this at Wikidata
InChI
  • InChI=1S/C2H2O4.2Na/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);;/q;2*+1/p-2 ☒N
    Key: ZNCPFRVNHGOPAG-UHFFFAOYSA-L ☒N
SMILES
  • C(=O)(C(=O)[O-])[O-].[Na+].[Na+]
Properties
Chemical formula
Na2C2O4
Molar mass 133.998 g·mol−1
Appearance White crystalline solid
Odor Odorless
Density 2.34 g/cm3
Melting point 260 °C (500 °F; 533 K) decomposes above 290 °C[2]
Solubility in water
  • 2.69 g/(100 mL) (0 °C)
  • 3.7 g/(100 mL) (20 °C)
  • 6.25 g/(100 mL) (100 °C)
Solubility Soluble in formic acid, insoluble in ethanol, diethyl ether
Structure
Crystal structure
monoclinic
Thermochemistry
Std enthalpy of
formation fH298)
−1318 kJ/mol
Hazards
GHS labelling:[3]
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H302, H312
Precautionary statements
P280, P301+P312, P302+P352
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Lethal dose or concentration (LD, LC):
LD50 (median dose)
11160 mg/kg (oral, rat)[1]
Safety data sheet (SDS) Oxford MSDS [unreliable source]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Sodium oxalate, or disodium oxalate, is a chemical compound with the chemical formula Na2C2O4. It is the sodium salt of oxalic acid. It contains sodium cations Na+ and oxalate anions C2O2−4. It is a white, crystalline, odorless solid, that decomposes above 290 °C.[2]

Sodium oxalate can act as a reducing agent, and it may be used as a primary standard for standardizing potassium permanganate (KMnO4) solutions.

The mineral form of sodium oxalate is natroxalate. It is only very rarely found and restricted to extremely sodic conditions of ultra-alkaline pegmatites.[4]

  1. ^ a b "ChemIDplus - 62-76-0 - ZNCPFRVNHGOPAG-UHFFFAOYSA-L - Disodium oxalate - Similar structures search, synonyms, formulas, resource links, and other chemical information". chem.nlm.nih.gov. NIH. Retrieved 7 January 2019.
  2. ^ a b Cite error: The named reference yoshi was invoked but never defined (see the help page).
  3. ^ GHS: GESTIS 570199
  4. ^ "Natroxolate" (PDF). RRUFF. Mineral Data Publishing. Retrieved 7 January 2019.

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Sodium oxalate

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Sodium oxalate, or disodium oxalate, is a chemical compound with the chemical formula Na2C2O4. It is the sodium salt of oxalic acid. It contains sodium...

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Oxalate

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It forms a variety of salts, for example sodium oxalate (Na2C2O4), and several esters such as dimethyl oxalate ((CH3)2C2O4). It is a conjugate base of...

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Calcium oxalate

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the oxalate ion. The basicity of calcium oxalate is weaker than that of sodium oxalate, due to its lower solubility in water. Solid calcium oxalate hydrate...

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Sodium ferrioxalate

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one oxalate to carbon dioxide CO2 and reduction of the iron(III) atom to iron(II). Sodium ferrioxalate can be obtained by mixing solutions of sodium oxalate...

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Sodium hydrogenoxalate

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Sodium hydrogenoxalate or sodium hydrogen oxalate is a chemical compound with the chemical formula NaHC2O4. It is an ionic compound. It is a sodium salt...

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Sodium formate

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heating, sodium formate decomposes to form sodium oxalate and hydrogen. The resulting sodium oxalate can be converted by further heating to sodium carbonate...

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Ferric oxalate

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Ferric oxalate, also known as iron(III) oxalate, refers to inorganic compounds with the formula Fe2(C2O4)3(H2O)x but could also refer to salts of [Fe(C2O4)3]3-...

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Casein

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dispersible in dilute alkalis and in salt solutions such as aqueous sodium oxalate and sodium acetate. The enzyme trypsin can hydrolyze a phosphate-containing...

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Copper oxalate

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produced by precipitation from a mixture of a copper (II) salt and a sodium oxalate solution or by reacting copper sulfate with oxalic acid. C u S O 4 +...

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Hydrogenoxalate

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Ivar (1971). "The crystal structures of normal and deuterated sodium hydrogen oxalate monohydrate NaHC2O4·H2O and NaDC2O4·D2O. Hydrogen bond studies...

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Permanganometry

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the standardization of potassium permanganate solution with standard sodium oxalate solution. The titration involves volumetric manipulations to prepare...

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Diphenyl oxalate

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Diphenyl oxalate (trademark name Cyalume) is a solid whose oxidation products are responsible for the chemiluminescence in a glowstick. This chemical...

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Potassium ferrioxalate

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ferrioxalate is also used. A number of other iron oxalates are known Iron(II) oxalate Iron(III) oxalate Sodium ferrioxalate J. Ladriere (1992): "Mössbauer Study...

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Claytonia perfoliata

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because wild C. perfoliata can sometimes accumulate toxic amounts of sodium oxalate (as can happen in spinach). The plant is known as palsingat or, possibly...

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Pyrotechnic colorant

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increasing it (e.g. nitrates, chlorates) and decreasing it (e.g. carbonates, oxalates), indirectly influencing the flame brightness and brilliancy. For temperature-decreasing...

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Solubility

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large increase in solubility with temperature (ΔH > 0). Some solutes (e.g. sodium chloride in water) exhibit solubility that is fairly independent of temperature...

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Manganese oxalate

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occurs naturally as the mineral Lindbergite. Exchange reaction between sodium oxalate and manganese chloride: M n C l 2 + N a 2 C 2 O 4 + 2 H 2 O   →   M...

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Solubility table

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68.6 71.8 Sodium nitrate NaNO3 73 80.8 87.6 94.9 102 122 148 180 Sodium nitrite NaNO2 71.2 75.1 80.8 87.6 94.9 111 133 160 Sodium oxalate Na2C2O4 2.69...

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Lithium oxalate

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Lithium oxalate is an organic compound with the chemical formula Li2C2O4. It is a salt of lithium metal and oxalic acid. It consists of lithium cations...

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Kidney stone disease

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collection to measure total daily urinary volume, magnesium, sodium, uric acid, calcium, citrate, oxalate, and phosphate; collection of stones (by urinating through...

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Lanthanum oxalate

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Lanthanum oxalate is an inorganic compound, a salt of lanthanum metal and oxalic acid with the chemical formula La 2(C 2O 4) 3. Reaction of soluble lanthanum...

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Borate oxalate

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The borate oxalates are chemical compounds containing borate and oxalate anions. Where the oxalate group is bound to the borate via oxygen, a more condensed...

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TCPO

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TCPO, or bis(2,4,6-trichlorophenyl) oxalate, is a chemical used in some types of glow sticks. When combined with a fluorescent dye like 9...

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Rubidium oxalate

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Rb+ and oxalate anions C2O2−4. Rubidium oxalate forms a monohydrate Rb2C2O4·H2O. Rubidium carbonate and oxalic acid react to form rubidium oxalate: Rb2CO3...

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Oxalic acid

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exclusively by using caustics, such as sodium or potassium hydroxide, on sawdust, followed by acidification of the oxalate by mineral acids, such as sulfuric...

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