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Sodium hydroxide information


Sodium hydroxide
Unit cell, spacefill model of sodium hydroxide
  Sodium, Na
  Oxygen, O
  Hydrogen, H
Sample of sodium hydroxide as pellets in a watchglass
Names
IUPAC name
Sodium hydroxide[3]
Other names
  • Ascarite
  • Caustic soda
  • Lye[1][2]
  • Soda lye
  • Sodium hydrate
  • White caustic[3]
Identifiers
CAS Number
  • 1310-73-2 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:32145 checkY
ChemSpider
  • 14114 checkY
ECHA InfoCard 100.013.805 Edit this at Wikidata
EC Number
  • 215-185-5
E number E524 (acidity regulators, ...)
Gmelin Reference
68430
KEGG
  • D01169 checkY
MeSH Sodium+Hydroxide
PubChem CID
  • 14798
RTECS number
  • WB4900000
UNII
  • 55X04QC32I checkY
UN number 1823 (solid)
1824 (solution)
CompTox Dashboard (EPA)
  • DTXSID0029634 Edit this at Wikidata
InChI
  • InChI=1S/Na.H2O/h;1H2/q+1;/p-1 checkY
    Key: HEMHJVSKTPXQMS-UHFFFAOYSA-M checkY
  • InChI=1/Na.H2O/h;1H2/q+1;/p-1
    Key: HEMHJVSKTPXQMS-REWHXWOFAM
SMILES
  • [OH-].[Na+]
Properties
Chemical formula
NaOH
Molar mass 39.9971 g/mol
Appearance White, opaque crystals
Odor odorless
Density 2.13 g/cm3[4]
Melting point 323 °C (613 °F; 596 K)[4]
Boiling point 1,388 °C (2,530 °F; 1,661 K)[4]
Solubility in water
418 g/L (0 °C)
1000 g/L (25 °C)[4]
3370 g/L (100 °C)
Solubility soluble in glycerol, negligible in ammonia, insoluble in ether, slowly soluble in propylene glycol
Solubility in methanol 238 g/L
Solubility in ethanol <<139 g/L
Vapor pressure <2.4 kPa (20 °C)
0.1 kPa (700 °C)
Acidity (pKa) 15.7
Magnetic susceptibility (χ)
−15.8·10−6 cm3/mol (aq.)[5]
Refractive index (nD)
1.3576
Structure[6]
Crystal structure
Orthorhombic, oS8
Space group
Cmcm, No. 63
Lattice constant
a = 0.34013 nm, b = 1.1378 nm, c = 0.33984 nm
Formula units (Z)
4
Thermochemistry[7]
Heat capacity (C)
59.5 J/(mol·K)
Std molar
entropy (S298)
64.4 J/(mol·K)
Std enthalpy of
formation fH298)
−425.8 kJ/mol
Gibbs free energy fG)
-379.7 kJ/mol
Hazards
GHS labelling:
Pictograms
GHS05: Corrosive GHS07: Exclamation mark
Signal word
Danger
Hazard statements
H290, H302, H314
Precautionary statements
P280, P305+P351+P338, P310
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazard ALK: Alkaline
3
0
1
ALK
Lethal dose or concentration (LD, LC):
LD50 (median dose)
40 mg/kg (mouse, intraperitoneal)[9]
140 - 340 mg/kg (rat, oral)
1350 mg/kg (rabbit, dermal)
LDLo (lowest published)
500 mg/kg (rabbit, oral)[10]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 2 mg/m3[8]
REL (Recommended)
C 2 mg/m3[8]
IDLH (Immediate danger)
10 mg/m3[8]
Safety data sheet (SDS) External SDS
Related compounds
Other anions
  • Sodium hydrosulfide
  • Sodium hydride
  • Sodium oxide
Other cations
  • Lithium hydroxide
  • Potassium hydroxide
  • Rubidium hydroxide
  • Caesium hydroxide
  • Francium hydroxide
Related compounds
  • Sodium deuteroxide
  • Sodium chloroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Sodium hydroxide, also known as lye and caustic soda,[1][2] is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+ and hydroxide anions OH.

Sodium hydroxide is a highly corrosive base and alkali that decomposes lipids and proteins at ambient temperatures and may cause severe chemical burns. It is highly soluble in water, and readily absorbs moisture and carbon dioxide from the air. It forms a series of hydrates NaOH·nH2O.[11] The monohydrate NaOH·H2O crystallizes from water solutions between 12.3 and 61.8 °C. The commercially available "sodium hydroxide" is often this monohydrate, and published data may refer to it instead of the anhydrous compound.

As one of the simplest hydroxides, sodium hydroxide is frequently used alongside neutral water and acidic hydrochloric acid to demonstrate the pH scale to chemistry students.[12]

Sodium hydroxide is used in many industries: in the making of wood pulp and paper, textiles, drinking water, soaps and detergents, and as a drain cleaner. Worldwide production in 2004 was approximately 60 million tons, while demand was 51 million tons.[13]

  1. ^ a b "Material Safety Datasheet" (PDF). certified-lye.com. Archived from the original (PDF) on 2008-02-28. Retrieved 2010-02-24.
  2. ^ a b "Material Safety Datasheet 2" (PDF). hillbrothers.com. Archived from the original (PDF) on 2012-08-03. Retrieved 2012-05-20.
  3. ^ a b "Sodium Hydroxide – Compound Summary". Retrieved June 12, 2012.
  4. ^ a b c d Haynes, p. 4.90
  5. ^ Haynes, p. 4.135
  6. ^ Jacobs, H.; Kockelkorn, J. and Tacke, Th. (1985). "Hydroxide des Natriums, Kaliums und Rubidiums: Einkristallzüchtung und röntgenographische Strukturbestimmung an der bei Raumtemperatur stabilen Modifikation". Z. Anorg. Allg. Chem. 531 (12): 119–124. doi:10.1002/zaac.19855311217.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  7. ^ Haynes, p. 5.13
  8. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0565". National Institute for Occupational Safety and Health (NIOSH).
  9. ^ Michael Chambers. "ChemIDplus – 1310-73-2 – HEMHJVSKTPXQMS-UHFFFAOYSA-M – Sodium hydroxide [NF] – Similar structures search, synonyms, formulas, resource links, and other chemical information.". nih.gov.
  10. ^ "Sodium hydroxide". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  11. ^ Cite error: The named reference siem was invoked but never defined (see the help page).
  12. ^ "Examples of Common Laboratory Chemicals and their Hazard Class". Archived from the original on 2018-01-10. Retrieved 2018-01-09.
  13. ^ Cite error: The named reference Ullmann was invoked but never defined (see the help page).

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Sodium hydroxide

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Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of...

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Hydroxide

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catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton...

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Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a...

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Sodium

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Sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide. Among many other useful sodium compounds, sodium hydroxide...

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Sodium hypochlorite

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nitrogen trichloride. With excess ammonia and sodium hydroxide, hydrazine may be generated. Anhydrous sodium hypochlorite can be prepared but, like many...

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Sodium bicarbonate

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ion: HCO− 3 + H2O → H 2CO 3 + OH− Sodium bicarbonate can often be used as a safer alternative to sodium hydroxide, and as such can be used as a wash...

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Lye

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refers to sodium hydroxide (NaOH), but historically has been conflated to include other alkali materials, most notably potassium hydroxide. Today, lye...

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Calcium hydroxide

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can be prepared by mixing aqueous solutions of calcium chloride and sodium hydroxide. The mineral form, portlandite, is relatively rare but can be found...

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Sodium carbonate

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carbonating sodium hydroxide which is made using the Chlor-alkali process. Sodium carbonate is obtained as three hydrates and as the anhydrous salt: sodium carbonate...

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Chloralkali process

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for the electrolysis of sodium chloride (NaCl) solutions. It is the technology used to produce chlorine and sodium hydroxide (caustic soda), which are...

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Aluminium hydroxide

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bauxite in sodium hydroxide at temperatures up to 270 °C (518 °F). The waste solid, bauxite tailings, is removed and aluminium hydroxide is precipitated...

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Sodium oxide

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ions. Sodium oxide is produced by the reaction of sodium with sodium hydroxide, sodium peroxide, or sodium nitrite: 2 NaOH + 2 Na → 2 Na2O + H2 To the extent...

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Zinc hydroxide

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and also in a solution of an alkali such as sodium hydroxide. It can be prepared by adding sodium hydroxide solution, but not in excess, to a solution...

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Sodium chloride

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chloralkali process, the industrial process to produce chlorine and sodium hydroxide, according to the chemical equation 2 NaCl + 2 H 2 O → e l e c t r...

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Alkali hydroxide

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Lithium hydroxide (LiOH) Sodium hydroxide (NaOH) Potassium hydroxide (KOH) Rubidium hydroxide (RbOH) Caesium hydroxide (CsOH) Francium hydroxide (FrOH)...

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Sodium aluminate

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Sodium aluminate is an inorganic chemical that is used as an effective source of aluminium hydroxide for many industrial and technical applications. Pure...

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Saponification

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salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide solutions are used. It is an important type of alkaline hydrolysis...

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Flavonoid

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compound is dissolved in water, warmed, and filtered. 10% aqueous sodium hydroxide is added to 2 ml of this solution. This produces a yellow coloration...

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Sodium acetate

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solution known as vinegar, with sodium carbonate ("washing soda"), sodium bicarbonate ("baking soda"), or sodium hydroxide ("lye", or "caustic soda"). Any...

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Carbon dioxide scrubber

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kJ/mol Other strong bases such as soda lime, sodium hydroxide, potassium hydroxide, and lithium hydroxide are able to remove carbon dioxide by chemically...

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Sodium salts

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acids with sodium hydroxide. Sodium salts can be categorized into: sodium salts of carboxylic acids (e. g. sodium formate, HCOONa, the sodium salt of formic...

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Sodium methoxide

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water to give methanol and sodium hydroxide. Indeed, samples of sodium methoxide are often contaminated with sodium hydroxide, which is difficult to detect...

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Soda lime

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Soda lime, a mixture of sodium hydroxide (NaOH) and calcium oxide (CaO), is used in granular form within recirculating breathing environments like general...

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Sodium bisulfate

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of sulfuric acid by an equivalent of sodium base, typically in the form of either sodium hydroxide (lye) or sodium chloride (table salt). It is a dry granular...

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Chlorine production

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The production of chlorine results in the co-products caustic soda (sodium hydroxide, NaOH) and hydrogen gas (H2). These two products, as well as chlorine...

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Sodium cocoate

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is produced by hydrolysis of the ester linkages in coconut oil with sodium hydroxide, a strong base. R. Marc Dahlgren; et al. "Effects of Bar Soap Constituents...

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Sodium bisulfite

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bleaching industry. Sodium bisulfite solutions can be prepared by treating a solution of suitable base, such as sodium hydroxide or sodium bicarbonate with...

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Sodium iodide

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as the salt formed when acidic iodides react with sodium hydroxide. It is a chaotropic salt. Sodium iodide, as well as potassium iodide, is commonly used...

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