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Formic acid information


Formic acid
Skeletal structure of formic acid
Skeletal structure of formic acid
3D model of formic acid
3D model of formic acid
Names
Preferred IUPAC name
Formic acid[1]
Systematic IUPAC name
Methanoic acid[1]
Other names
  • Isocarbonous acid
  • Carbonous acid
  • Formylic acid
  • Methylic acid
  • Hydrogencarboxylic acid
  • Hydroxy(oxo)methane
  • Metacarbonoic acid
  • Oxocarbinic acid
  • Oxomethanol
  • Hydroxymethylene oxide
Identifiers
CAS Number
  • 64-18-6 checkY
3D model (JSmol)
  • Interactive image
Beilstein Reference
1209246
ChEBI
  • CHEBI:30751 checkY
ChEMBL
  • ChEMBL116736 checkY
ChemSpider
  • 278 checkY
DrugBank
  • DB01942 checkY
ECHA InfoCard 100.000.527 Edit this at Wikidata
EC Number
  • 200-579-1
E number E236 (preservatives)
Gmelin Reference
1008
KEGG
  • C00058 checkY
PubChem CID
  • 284
RTECS number
  • LQ4900000
UNII
  • 0YIW783RG1 checkY
CompTox Dashboard (EPA)
  • DTXSID2024115 Edit this at Wikidata
InChI
  • InChI=1S/HCOOH/c2-1-3/h1H,(H,2,3) ☒N
    Key: BDAGIHXWWSANSR-UHFFFAOYSA-N checkY
  • InChI=1/HCOOH/c2-1-3/h1H,(H,2,3)
    Key: BDAGIHXWWSANSR-UHFFFAOYAT
SMILES
  • O=CO
Properties
Chemical formula
CH2O2
Molar mass 46.025 g·mol−1
Appearance Colorless fuming liquid
Odor Pungent, penetrating
Density 1.220 g/mL
Melting point 8.4 °C (47.1 °F; 281.5 K)
Boiling point 100.8 °C (213.4 °F; 373.9 K)
Solubility in water
Miscible
Solubility Miscible with ether, acetone, ethyl acetate, glycerol, methanol, ethanol
Partially soluble in benzene, toluene, xylenes
log P −0.54
Vapor pressure 35 mmHg (20 °C)[2]
Acidity (pKa) 3.745[3]
Conjugate base Formate
Magnetic susceptibility (χ)
−19.90×10−6 cm3/mol
Refractive index (nD)
1.3714 (20 °C)
Viscosity 1.57 cP at 268 °C
Structure
Molecular shape
Planar
Dipole moment
1.41 D (gas)
Thermochemistry
Std molar
entropy (S298)
131.8 J/mol K
Std enthalpy of
formation fH298)
−425.0 kJ/mol
Std enthalpy of
combustion cH298)
−254.6 kJ/mol
Pharmacology
ATCvet code
QP53AG01 (WHO)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Corrosive; irritant;
sensitizer
GHS labelling:
Pictograms
GHS02: Flammable GHS05: Corrosive
Signal word
Danger
Hazard statements
H314
Precautionary statements
P260, P264, P280, P301+P330+P331, P303+P361+P353, P304+P340, P305+P351+P338, P310, P321, P363, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 2: Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur. Flash point between 38 and 93 °C (100 and 200 °F). E.g. diesel fuelInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
3
2
0
Flash point 69 °C (156 °F; 342 K)
Autoignition
temperature
601 °C (1,114 °F; 874 K)
Explosive limits 14–34%[citation needed]
18–57% (90% solution)[2]
Lethal dose or concentration (LD, LC):
LD50 (median dose)
700 mg/kg (mouse, oral), 1100 mg/kg (rat, oral), 4000 mg/kg (dog, oral)[4]
LC50 (median concentration)
7853 ppm (rat, 15 min)
3246 ppm (mouse, 15 min)[4]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 5 ppm (9 mg/m3)[2]
REL (Recommended)
TWA 5 ppm (9 mg/m3)[2]
IDLH (Immediate danger)
30 ppm[2]
Safety data sheet (SDS) MSDS from JT Baker
Related compounds
Related carboxylic acids
Acetic acid
Propionic acid
Related compounds
Formaldehyde
Methanol
Supplementary data page
Formic acid (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Formic acid (from Latin formica 'ant'), systematically named methanoic acid, is the simplest carboxylic acid, and has the chemical formula HCOOH and structure H−C(=O)−O−H. It is an important intermediate in chemical synthesis and occurs naturally, most notably in some ants. Esters, salts and the anion derived from formic acid are called formates. Industrially, formic acid is produced from methanol.[5]

  1. ^ a b Favre, Henri A.; Powell, Warren H. (2014). Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. p. 745. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.
  2. ^ a b c d e NIOSH Pocket Guide to Chemical Hazards. "#0296". National Institute for Occupational Safety and Health (NIOSH).
  3. ^ Smith, Robert M.; Martell, Arthur E. (1989). Critical Stability Constants Volume 6: Second Supplement. New York: Plenum Press. p. 299. ISBN 0-306-43104-1.
  4. ^ a b "Formic acid". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health. 4 December 2014. Retrieved 26 March 2015.
  5. ^ "Formic acid". American Chemical Society. Retrieved 21 November 2023.

and 27 Related for: Formic acid information

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Formic acid

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Formic acid (from Latin formica 'ant'), systematically named methanoic acid, is the simplest carboxylic acid, and has the chemical formula HCOOH and structure...

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Formate

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methanoate) is the conjugate base of formic acid. Formate is an anion (HCO−2) or its derivatives such as ester of formic acid. The salts and esters are generally...

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Sodium formate

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Sodium formate, HCOONa, is the sodium salt of formic acid, HCOOH. It usually appears as a white deliquescent powder. For commercial use, sodium formate...

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Organic acid

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organic acids. A few common examples include: Lactic acid Acetic acid Formic acid Citric acid Oxalic acid Uric acid Malic acid Tartaric acid Butyric acid Folic...

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Formic acid fuel cell

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Formic acid fuel cells (direct formic acid fuel cells or DFAFCs) are a subcategory of direct liquid-feed fuel cells (DLFCs), in which the liquid fuel is...

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Methyl formate

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Methyl formate, also called methyl methanoate, is the methyl ester of formic acid. The simplest example of a carboxylate ester, it is a colorless liquid...

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Acetic acid

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from at least the third century BC. Acetic acid is the second simplest carboxylic acid (after formic acid). It is an important chemical reagent and industrial...

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Formic

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up formic in Wiktionary, the free dictionary. Formic is an adjective describing ants, from the Latin formica. Formic may also refer to: Formic acid, a...

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Carboxylic acid

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weaker acids (the pKa of formic acid is 3.75 whereas acetic acid, with a methyl substituent, has a pKa of 4.76) Deprotonation of carboxylic acids gives...

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Ethyl formate

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Ethyl formate is an ester formed when ethanol (an alcohol) reacts with formic acid (a carboxylic acid). Ethyl formate has the characteristic smell of...

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Chloroformic acid

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derivative). Chloroformic acid is also structurally related to formic acid, in a way that the non-acidic hydrogen of formic acid is replaced by chlorine...

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Dihydroxymethylidene

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Dihydroxymethylidene or carbonous acid is a chemical compound with formula C(OH)2. It is an unstable tautomer of formic acid. There is no evidence that this...

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Glycolic acid

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cyanohydrin derived from formaldehyde. Some of today's glycolic acids are formic acid-free. Glycolic acid can be isolated from natural sources, such as sugarcane...

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Methanol toxicity

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When methanol is broken down by the body it results in formaldehyde, formic acid, and formate which cause much of the toxicity. The diagnosis may be suspected...

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Formic anhydride

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formic acid (HCOOH). Formic anhydride can be obtained by reaction of formyl fluoride with excess sodium formate and a catalytic amount of formic acid...

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Performic acid

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Performic acid (PFA) is an organic compound with the formula CH2O3. It is an unstable colorless liquid which can be produced by mixing formic acid with hydrogen...

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Ammonium formate

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industry. Formic acid can also be obtained by reacting ammonium formate with a dilute acid, and since ammonium formate is also produced from formic acid, it...

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Acetic formic anhydride

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the reaction of acetic anhydride and formic acid at 0 °C. While more stable than formic anhydride, acetic formic anhydride is thermally unstable and gradually...

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Rasberry crazy ant

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2014, it was discovered that the ant produces and covers itself with formic acid as an antidote to the fire ant's venom. It is the first known example...

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Hydrogen cyanide

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Hydrogen cyanide (also known as prussic acid) is a chemical compound with the formula HCN and structural formula H−C≡N. It is a colorless, extremely poisonous...

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Solvothermal synthesis

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6-diol. Formic acid decomposes at high temperatures to carbon dioxide and hydrogen or carbon monoxide and water. This property allows formic acid to be...

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Calcium formate

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Calcium formate is the calcium salt of formic acid. It is also known as E238. Under this E number it is used as an animal feed preservative within EU...

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Oxalic acid

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formic acid HCOOH. Photolysis with 237–313 nm UV light also produces carbon monoxide CO and water. Evaporation of a solution of urea and oxalic acid in...

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Acid

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O-H. Acetic acid (CH3COOH) Citric acid (C6H8O7) Formic acid (HCOOH) Gluconic acid HOCH2-(CHOH)4-COOH Lactic acid (CH3-CHOH-COOH) Oxalic acid (HOOC-COOH)...

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Propionic acid

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Propionic acid has physical properties intermediate between those of the smaller carboxylic acids, formic and acetic acids, and the larger fatty acids. It is...

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Leuckart reaction

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various ways in which amines can be formed: using either formamide or ammonium formate, or both, or adding formic acid to formamide. However, using just...

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Ester

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esters of formic acid. For example, butyl acetate (systematically butyl ethanoate), derived from butanol and acetic acid (systematically ethanoic acid) would...

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