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Acetic formic anhydride information


Acetic formic anhydride
Skeletal formula of acetic formic anhydride
Ball-and-stick model of the acetic formic anhydride molecule
Names
Preferred IUPAC name
Acetic formic anhydride
Other names
  • Acetyloxymethanone
  • Formyl acetate
  • Formic acetic anhydride
  • ethanoic methanoic anhydride
Identifiers
CAS Number
  • 2258-42-6 ☒N
3D model (JSmol)
  • Interactive image
ChemSpider
  • 67812 checkY
PubChem CID
  • 75269
CompTox Dashboard (EPA)
  • DTXSID80177103 Edit this at Wikidata
InChI
  • InChI=1S/C3H4O3/c1-3(5)6-2-4/h2H,1H3 checkY
    Key: ORWKVZNEPHTCQE-UHFFFAOYSA-N checkY
SMILES
  • CC(=O)OC=O
Properties
Chemical formula
C3H4O3
Molar mass 88.062 g·mol−1
Appearance colourless liquid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Acetic formic anhydride is an organic compound with the chemical formula C
3
H
4
O
3
, which can be viewed as the mixed anhydride of acetic acid and formic acid. It is used on a laboratory-scale as a formylating agent.[1]

  1. ^ Strazzolini, Paolo; Giumanini, Angelo G.; Cauci, Sabina (1990). "Acetic formic anhydride a review". Tetrahedron. 46 (4): 1081–1118. doi:10.1016/S0040-4020(01)86676-X.

and 27 Related for: Acetic formic anhydride information

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Acetic formic anhydride

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Formic anhydride Acetic anhydride Acetic oxalic anhydride Strazzolini, Paolo; Giumanini, Angelo G.; Cauci, Sabina (1990). "Acetic formic anhydride a...

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Acetic anhydride

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Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH3CO)2O. Commonly abbreviated Ac2O, it is the simplest isolable anhydride...

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Organic acid anhydride

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anhydride. Thus, (CH3CO)2O is called acetic anhydride. Mixed (or unsymmetrical) acid anhydrides, such as acetic formic anhydride (see below), are known, whereby...

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Formic anhydride

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structural formula of (H(C=O)−)2O. It can be viewed as the anhydride of formic acid (HCOOH). Formic anhydride can be obtained by reaction of formyl fluoride with...

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Acetic acid

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history from at least the third century BC. Acetic acid is the second simplest carboxylic acid (after formic acid). It is an important chemical reagent...

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Formic acid

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reaction occurs instead, and formic acid adds to the alkene to produce a larger carboxylic acid. An unstable formic anhydride, H(C=O)−O−(C=O)H, can be obtained...

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Monsanto process

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acetate salts or acetic acid to give the anhydride. Rhodium iodides and lithium salts are employed as catalysts. Because acetic anhydride hydrolyzes, the...

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C3H4O3

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molecular formula C3H4O3 (molar mass: 88.06 g/mol) may refer to: Acetic formic anhydride Ethylene carbonate Glucic acid Glycidic acid Pyruvic acid This...

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Methyl acetate

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polish removers. Acetic anhydride is produced by carbonylation of methyl acetate in a process that was inspired by the Monsanto acetic acid synthesis....

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Acetaldehyde

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crotonaldehyde. Urea and acetaldehyde combine to give a useful resin. Acetic anhydride reacts with acetaldehyde to give ethylidene diacetate, a precursor...

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Peracetic acid

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without a strong acid catalyst will not form peracetic acid. As an alternative, acetyl chloride and acetic anhydride can be used to generate a solution of...

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Pummerer rearrangement

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acetic anhydride. The stoichiometry of the reaction is: RS(O)CHR'2 + Ac2O → RSC(OAc)R'2 + AcOH Aside from acetic anhydride, trifluoroacetic anhydride...

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Propionic acid

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acids, formic and acetic acids, and the larger fatty acids. It is miscible with water, but can be removed from water by adding salt. As with acetic and formic...

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Acetylated wood

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produced from a special chemical treatment (acetylation) involving acetic anhydride and a chemical modification process to make wood highly resistant to...

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Acetyl chloride

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industrial scale, the reaction of acetic anhydride with hydrogen chloride produces a mixture of acetyl chloride and acetic acid: ( CH 3 CO ) 2 O + HCl ⟶ CH...

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Cellulose acetate

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reacts with acetic anhydride to form cellulose acetate. The German chemists Arthur Eichengrün and Theodore Becker invented the first soluble forms of cellulose...

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Zinc acetate

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are prepared by the action of acetic acid on zinc carbonate or zinc metal. Treatment of zinc nitrate with acetic anhydride is an alternative route. In anhydrous...

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Methanol

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acetic acid and acetic anhydride. These processes include the Monsanto acetic acid synthesis, Cativa process, and Tennessee Eastman acetic anhydride process...

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Butyric anhydride

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Butyric anhydride or butanoic anhydride is the chemical compound with the formula (CH3CH2CH2CO)2O. The molecule can be described as a condensation of...

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Acetylation

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achieved using these three reagents: Acetic anhydride. This reagent is common in the laboratory; its use cogenerates acetic acid. Acetyl chloride. This reagent...

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Ester

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the case of esters of formic acid. For example, butyl acetate (systematically butyl ethanoate), derived from butanol and acetic acid (systematically ethanoic...

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Avantor

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opioid epidemic. According to Bloomberg, one of their compounds "acetic anhydride", was used illicitly by drug traffickers to convert crude opium into...

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Black tar heroin

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acetylating agent, acetic anhydride. The acetic anhydride reacts with the moisture to produce the milder acetylating agent glacial acetic acid which is unable...

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Clandestine chemistry

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by acid-base extraction and turned into heroin by reacting it with acetic anhydride. Other drugs (such as methamphetamine and MDMA) are normally made from...

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Aluminium acetate

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aluminium chloride (AlCl3) or Al powder with a mixture of acetic acid (CH3COOH) and acetic anhydride (C4H6O3). It is referred as the normal salt and is only...

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Carbonylation

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Monsanto acetic acid process and Cativa process, which convert methanol to acetic acid. In another major industrial process, acetic anhydride is prepared...

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Cellobiose

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Crohn's disease and malabsorption syndrome. Treatment of cellulose with acetic anhydride and sulfuric acid gives cellobiose acetoacetate, of which there is...

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