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Rhenium pentachloride information


Rhenium pentachloride
Names
IUPAC name
Rhenium pentachloride
Other names
Rhenium(V) chloride, Rhenium chloride, pentachlororhenium
Identifiers
CAS Number
  • 13596-35-5 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 75428
ECHA InfoCard 100.033.660 Edit this at Wikidata
EC Number
  • 237-042-6
PubChem CID
  • 83602
CompTox Dashboard (EPA)
  • DTXSID1065552 Edit this at Wikidata
InChI
  • InChI=1S/5ClH.Re/h5*1H;/q;;;;;+5/p-5
    Key: XZQYTGKSBZGQMO-UHFFFAOYSA-I
  • InChI=1/5ClH.Re/h5*1H;/q;;;;;+5/p-5/rCl5Re/c1-6(2,3,4)5
    Key: XZQYTGKSBZGQMO-PXGBCINVAP
SMILES
  • Cl[Re](Cl)(Cl)(Cl)Cl
Properties
Chemical formula
ReCl5
Molar mass 363.471 g/mol
Appearance red-brown
Density 4.9 g/cm3, solid
Melting point 220 °C (428 °F; 493 K)
Boiling point N/A
Solubility in water
Will react to decompose and release HCl (g)
Magnetic susceptibility (χ)
+1225.0·10−6 cm3/mol
Structure
Crystal structure
Monoclinic, mP48; a = 0.924 nm, b = 1.154 nm, c = 1.203 nm, α = 90°, β = 109.1°, γ = 90° [1]
Space group
P21/c, No. 14
Molecular shape
Octahedral
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
releases HCl upon hydrolysis
GHS labelling:[2]
Pictograms
GHS07: Exclamation mark
Signal word
Warning
Hazard statements
H315, H319, H335
Precautionary statements
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability (red): no hazard codeInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazard W: Reacts with water in an unusual or dangerous manner. E.g. sodium, sulfuric acid
1
0
W
Safety data sheet (SDS) MSDS
Related compounds
Other anions
Rhenium hexafluoride
Related compounds
Trirhenium nonachloride, rhenium tetrachloride, rhenium hexachloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references

Rhenium pentachloride is an inorganic compound of chlorine and rhenium. The compound has the formula Re2Cl10 but it is usually referred to as rhenium pentachloride. It is a red-brown solid.

  1. ^ Cite error: The named reference s1 was invoked but never defined (see the help page).
  2. ^ GHS: PubChem 83602

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Rhenium pentachloride

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Rhenium pentachloride is an inorganic compound of chlorine and rhenium. The compound has the formula Re2Cl10 but it is usually referred to as rhenium...

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Pentachloride

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Phosphorus pentachloride, PCl5 Protactinium pentachloride, PaCl5 Osmium pentachloride, OsCl5 Rhenium pentachloride, Re2Cl10 Tantalum pentachloride, TaCl5...

Word Count : 95

Trirhenium nonachloride

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nonachloride is efficiently prepared by thermal decomposition of rhenium pentachloride or hexachlororhenic(IV) acid: 3 ReCl5 → Re3Cl9 + 3 Cl2 If the sample...

Word Count : 328

Rhenium chloride

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chloride (rhenium tetrachloride), ReCl4 Rhenium pentachloride (rhenium(V) chloride), ReCl5 Rhenium(VI) chloride (rhenium hexachloride), ReCl6 This set index...

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Group 5 element

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what had formed from the SF activity nearly matched that of niobium pentachloride, rather than hafnium tetrachloride. The team identified a 2.2-second...

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Molybdenum disulfide

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sulfur and can be produced by metathesis reactions from molybdenum pentachloride. All forms of MoS 2 have a layered structure, in which a plane of molybdenum...

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List of inorganic compounds

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– RaF2 Radon difluoride – RnF2 Rhenium(IV) oxide – ReO2 Rhenium(VII) oxide – Re2O7 Rhenium heptafluoride – ReF7 Rhenium hexafluoride – ReF6 Rhodium hexafluoride...

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Edward Divers

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according to which thionyl chloride formed by the action of phosphorus pentachloride on inorganic sulfites was regarded as a direct product of the reaction...

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Niobium

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(NbF5) is a white solid with a melting point of 79.0 °C and niobium pentachloride (NbCl5) is yellow (see image at right) with a melting point of 203.4 °C...

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List of CAS numbers by chemical compound

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ReI4 rhenium(IV) iodide 59301–47–2 ReO2 rhenium(IV) oxide 12036–09–8 ReO3 rhenium(VI) oxide 1314–28–9 ReS2 rhenium(IV) sulfide 12038–63–0 ReTe2 rhenium(IV)...

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Protactinium

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to the nearby chains. These compounds easily hydrolyze in water. The pentachloride melts at 300 °C and sublimates at even lower temperatures. Protactinium(V)...

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Arsenic

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even so, it is a very strong fluorinating and oxidizing agent. (The pentachloride is stable only below −50 °C, at which temperature it decomposes to the...

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Chlorine

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using hydrogen chloride, or with chlorinating agents such as phosphorus pentachloride (PCl5) or thionyl chloride (SOCl2). The last is very convenient in the...

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Glossary of chemical formulae

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bromine chloride 13863-41-7 BrCl3 bromine trichloride BrCl5 bromine pentachloride BrF bromine monofluoride bromine fluoride BrF3 bromine trifluoride 7787-71-5...

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Phosphorus

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is an unstable solid formulated as PBr4+Br−and PI5 is not known. The pentachloride and pentafluoride are Lewis acids. With fluoride, PF5 forms PF6−, an...

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Dubnium

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what had formed from the SF activity nearly matched that of niobium pentachloride, rather than hafnium tetrachloride. The team identified a 2.2-second...

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Transition metal nitrile complexes

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reductant. This method is illustrated by the conversion of molybdenum pentachloride to the molybdenum(IV) complex: 2 MoCl5 + 5 CH3CN → 2 MoCl4(CH3CN)2 +...

Word Count : 1900

Transition metal chloride complex

Last Update:

B. W. Sandor (1991). "Structure of the Second Polymorph of Niobium Pentachloride". Acta Crystallogr. C. 47 (11): 2435–2437. doi:10.1107/S0108270191000239...

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Erbium

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erbium(III) oxide and ammonium chloride to produce the ammonium salt of the pentachloride ([NH4]2ErCl5) then heating it in a vacuum at 350-400 °C. It forms crystals...

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Oxidation state

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doi:10.1016/0925-8388(94)90898-2. Db(V) has been observed in dubnium pentachloride (DbCl5); see H. W. Gäggeler (2007). "Gas Phase Chemistry of Superheavy...

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Actinide

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They are very sensitive to moisture and hydrolyze forming AnO2F2. The pentachloride and black hexachloride of uranium were synthesized, but they are both...

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Seaborgium

Last Update:

hexafluoride (SgF6) as well as a moderately volatile hexachloride (SgCl6), pentachloride (SgCl5), and oxychlorides SgO2Cl2 and SgOCl4. SgO2Cl2 is expected to...

Word Count : 7721

Metalloid

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nitric acid, yielding the hydrated pentoxide Sb2O5. Aqua regia gives the pentachloride SbCl5 and hot concentrated sulfuric acid results in the sulfate Sb2(SO4)3...

Word Count : 28131

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