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Trirhenium nonachloride information


Trirhenium nonachloride
Re3Cl12 cluster subunit in ReCl3
Names
IUPAC name
Rhenium(III) chloride
Other names
Rhenium trichloride
Identifiers
CAS Number
  • 13569-63-6 checkY
3D model (JSmol)
  • Interactive image
ECHA InfoCard 100.033.610 Edit this at Wikidata
EC Number
  • 236-987-1
PubChem CID
  • 83581
CompTox Dashboard (EPA)
  • DTXSID8065537 Edit this at Wikidata
InChI
  • InChI=1S/3ClH.Re/h3*1H;/q;;;+3/p-3
SMILES
  • Cl[Re](Cl)Cl
Properties
Chemical formula
ReCl3
Molar mass 292.57 g/mol
Appearance red, crystalline, nonvolatile solid
Density 4800 kg/m3
Melting point N/A
Boiling point 500 °C (932 °F; 773 K) (decomposes)
Solubility in water
hydrolyzes to form Re2O3.xH2O.
Structure
Crystal structure
Rhombohedral, hR72
Space group
R-3m, No. 166
Molecular shape
(trimeric solid and in solution)
(dimeric in acetic acid)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Corrosive (C)
Safety data sheet (SDS) External MSDS
Related compounds
Other anions
Rhenium tribromide
Rhenium triiodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Trirhenium nonachloride is a compound with the formula ReCl3, sometimes also written Re3Cl9. It is a dark red hygroscopic solid that is insoluble in ordinary solvents. The compound is important in the history of inorganic chemistry as an early example of a cluster compound with metal-metal bonds.[1] It is used as a starting material for synthesis of other rhenium complexes.

  1. ^ Cotton, F. A.; Walton, R. A. "Multiple Bonds Between Metal Atoms" Oxford (Oxford): 1993. ISBN 0-19-855649-7.

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Trirhenium nonachloride is a compound with the formula ReCl3, sometimes also written Re3Cl9. It is a dark red hygroscopic solid that is insoluble in ordinary...

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of the early catalysts for olefin metathesis. Reduction gives trirhenium nonachloride. Oxygenation affords the Re(VII) oxychloride: ReCl5 + 3 Cl2O →...

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Rhenium chloride may refer to: Trirhenium nonachloride (rhenium(III) chloride/Rhenium trichloride), Re3Cl9 Rhenium(IV) chloride (rhenium tetrachloride)...

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