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Niobium information


Niobium, 41Nb
A lump of gray shining crystals with hexagonal facetting
Niobium
Pronunciation/nˈbiəm/ (ny-OH-bee-əm)
AppearanceGray metallic, bluish when oxidized
Standard atomic weight Ar°(Nb)
  • 92.90637±0.00001[1]
  • 92.906±0.001 (abridged)[2]
Niobium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
V

Nb

Ta
zirconium ← niobium → molybdenum
Atomic number (Z)41
Groupgroup 5
Periodperiod 5
Block  d-block
Electron configuration[Kr] 4d4 5s1
Electrons per shell2, 8, 18, 12, 1
Physical properties
Phase at STPsolid
Melting point2750 K ​(2477 °C, ​4491 °F)
Boiling point5017 K ​(4744 °C, ​8571 °F)
Density (at 20° C)8.582 g/cm3[3]
Heat of fusion30 kJ/mol
Heat of vaporization689.9 kJ/mol
Molar heat capacity24.60 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 2942 3207 3524 3910 4393 5013
Atomic properties
Oxidation states−3, −1, 0, +1, +2, +3, +4, +5 (a mildly acidic oxide)
ElectronegativityPauling scale: 1.6
Ionization energies
  • 1st: 652.1 kJ/mol
  • 2nd: 1380 kJ/mol
  • 3rd: 2416 kJ/mol
Atomic radiusempirical: 146 pm
Covalent radius164±6 pm
Color lines in a spectral range
Spectral lines of niobium
Other properties
Natural occurrenceprimordial
Crystal structure ​body-centered cubic (bcc) (cI2)
Lattice constant
Cubic body-centered crystal structure for niobium
a = 330.05 pm (at 20 °C)[3]
Thermal expansion7.07×10−6/K (at 20 °C)[3]
Thermal conductivity53.7 W/(m⋅K)
Electrical resistivity152 nΩ⋅m (at 0 °C)
Magnetic orderingparamagnetic
Young's modulus105 GPa
Shear modulus38 GPa
Bulk modulus170 GPa
Speed of sound thin rod3480 m/s (at 20 °C)
Poisson ratio0.40
Mohs hardness6.0
Vickers hardness870–1320 MPa
Brinell hardness735–2450 MPa
CAS Number7440-03-1
History
Namingafter Niobe in Greek mythology, daughter of Tantalus (tantalum)
DiscoveryCharles Hatchett (1801)
First isolationChristian Wilhelm Blomstrand (1864)
Recognized as a distinct element byHeinrich Rose (1844)
Isotopes of niobium
Main isotopes[4] Decay
abun­dance half-life (t1/2) mode pro­duct
91Nb synth 680 y ε 91Zr
92Nb trace 3.47×107 y β+ 92Zr
93Nb 100% stable
93mNb synth 16.12 y IT 93Nb
94Nb trace 2.04×104 y β 94Mo
95Nb synth 34.991 d β 95Mo
Niobium Category: Niobium
| references

Niobium is a chemical element; it has symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and ductile transition metal. Pure niobium has a Mohs hardness rating similar to pure titanium,[5] and it has similar ductility to iron. Niobium oxidizes in Earth's atmosphere very slowly, hence its application in jewelry as a hypoallergenic alternative to nickel. Niobium is often found in the minerals pyrochlore and columbite, hence the former name "columbium". Its name comes from Greek mythology: Niobe, daughter of Tantalus, the namesake of tantalum. The name reflects the great similarity between the two elements in their physical and chemical properties, which makes them difficult to distinguish.[6]

English chemist Charles Hatchett reported a new element similar to tantalum in 1801 and named it columbium. In 1809, English chemist William Hyde Wollaston wrongly concluded that tantalum and columbium were identical. German chemist Heinrich Rose determined in 1846 that tantalum ores contain a second element, which he named niobium. In 1864 and 1865, a series of scientific findings clarified that niobium and columbium were the same element (as distinguished from tantalum), and for a century both names were used interchangeably. Niobium was officially adopted as the name of the element in 1949, but the name columbium remains in current use in metallurgy in the United States.

It was not until the early 20th century that niobium was first used commercially. Niobium is an important addition to high-strength low-alloy steels. Brazil is the leading producer of niobium and ferroniobium, an alloy of 60–70% niobium with iron. Niobium is used mostly in alloys, the largest part in special steel such as that used in gas pipelines. Although these alloys contain a maximum of 0.1%, the small percentage of niobium enhances the strength of the steel by scavenging carbide and nitride. The temperature stability of niobium-containing superalloys is important for its use in jet and rocket engines.

Niobium is used in various superconducting materials. These alloys, also containing titanium and tin, are widely used in the superconducting magnets of MRI scanners. Other applications of niobium include welding, nuclear industries, electronics, optics, numismatics, and jewelry. In the last two applications, the low toxicity and iridescence produced by anodization are highly desired properties. Niobium is considered a technology-critical element.

  1. ^ "Standard Atomic Weights: Niobium". CIAAW. 2017.
  2. ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (4 May 2022). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  3. ^ a b c Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
  4. ^ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  5. ^ Samsonov, G. V. (1968). "Mechanical Properties of the Elements". In G.V. Samsonov (ed.). Handbook of the Physicochemical Properties of the Elements. New York, US: IFI-Plenum. pp. 387–446. doi:10.1007/978-1-4684-6066-7_7. ISBN 978-1-4684-6066-7. Archived from the original on 2 April 2015.
  6. ^ Knapp, Brian (2002). Francium to Polonium. Atlantic Europe Publishing Company, p. 40. ISBN 0717256774.

and 24 Related for: Niobium information

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Niobium

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Niobium is a chemical element; it has symbol Nb (formerly columbium, Cb) and atomic number 41. It is a light grey, crystalline, and ductile transition...

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Isotopes of niobium

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Naturally occurring niobium (41Nb) is composed of one stable isotope (93Nb). The most stable radioisotope is 92Nb with a half-life of 34.7 million years...

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Niobium oxide

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Niobium oxide, archaically called columbium oxide, may refer to: Niobium monoxide (niobium(II) oxide), NbO Niobium dioxide (niobium(IV) oxide), NbO2 Niobium...

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Niobium carbide

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Niobium carbide (NbC and Nb2C) is an extremely hard refractory ceramic material, commercially used in tool bits for cutting tools. It is usually processed...

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Tantalum

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element, along with vanadium and niobium, and it always occurs in geologic sources together with the chemically similar niobium, mainly in the mineral groups...

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Group 5 element

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group of elements in the periodic table. Group 5 contains vanadium (V), niobium (Nb), tantalum (Ta) and dubnium (Db). This group lies in the d-block of...

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Niobium pentoxide

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Niobium pentoxide is the inorganic compound with the formula Nb2O5. A colorless, insoluble, and fairly unreactive solid, it is the most widespread precursor...

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Niobium capacitor

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A niobium electrolytic capacitor (historically also Columbium capacitor) is an electrolytic capacitor whose anode (+) is made of passivated niobium metal...

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Niobium monoxide

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Niobium monoxide is the inorganic compound with the formula NbO. It is a grey solid with metallic conductivity. NbO adopts an unusual cubic structure...

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Niobium chloride

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Niobium chloride may refer to: Niobium(IV) chloride (niobium tetrachloride), NbCl4 Niobium(V) chloride (niobium pentachloride), NbCl5 This set index article...

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Niobium dioxide

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Niobium dioxide, is the chemical compound with the formula NbO2. It is a bluish-black non-stoichiometric solid with a composition range of NbO1.94-NbO2...

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Niobium alloy

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A niobium alloy is one in which the most common element is niobium. The most common commercial niobium alloys are ferroniobium and nickel-niobium, produced...

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Niobium disulfide

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Niobium disulfide is the chemical compound with the formula NbS2. It is a black layered solid that can be exfoliated into ultrathin grayish sheets similar...

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Niobium perchlorate

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with moist air or water to produce niobium(V) oxide. Niobium perchlorate is produced from the reaction of niobium pentachloride and anhydrous perchloric...

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Niobium fluoride

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Two fluorides of niobium are well characterized: Niobium(IV) fluoride Niobium(V) fluoride This set index article lists chemical compounds articles associated...

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Coltan

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from which the elements niobium and tantalum are extracted. The niobium-dominant mineral in coltan is columbite (after niobium's original American name...

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Niobium bromide

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Niobium bromide may refer to Niobium(III) bromide. NbBr3 Niobium(IV) bromide, NbBr4 Niobium(V) bromide, NbBr5 Greenwood, Norman N.; Earnshaw, Alan (1997)...

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Ferroniobium

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Ferroniobium is an important iron-niobium alloy, with a niobium content of 60-70%. It is the main source for niobium alloying of HSLA steel and covers...

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Niobium oxychloride

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impurity in samples of niobium pentachloride, a common reagent in niobium chemistry. In the solid state the coordination sphere for niobium is a distorted octahedron...

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Superconductivity

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chemical elements (e.g. mercury or lead), alloys (such as niobium–titanium, germanium–niobium, and niobium nitride), ceramics (YBCO and magnesium diboride), superconducting...

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Niobium nanowire

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Niobium nanowires are nanowires made of the element niobium, which is a transition metal. Niobium nanowires in form oxide or nitride are used to detect...

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Niobium diselenide

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Niobium diselenide or niobium(IV) selenide is a layered transition metal dichalcogenide with formula NbSe2. Niobium diselenide is a lubricant, and a superconductor...

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Lithium niobate

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Lithium niobate (LiNbO3) is a synthetic salt consisting of niobium, lithium, and oxygen. Its single crystals are an important material for optical waveguides...

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Niobium nitride

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Niobium nitride is a compound of niobium and nitrogen (nitride) with the chemical formula NbN. At low temperatures (about 16 K) NbN becomes a superconductor...

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