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Propyl group information


From left to right: the two isomeric groups propyl and 1-methylethyl (iPr or isopropyl), and the non-isomeric cyclopropyl group.

In organic chemistry, a propyl group is a three-carbon alkyl substituent with chemical formula −CH2CH2CH3 for the linear form. This substituent form is obtained by removing one hydrogen atom attached to the terminal carbon of propane.[1] A propyl substituent is often represented in organic chemistry with the symbol Pr (not to be confused with the element praseodymium).

An isomeric form of propyl is obtained by moving the point of attachment from a terminal carbon atom to the central carbon atom, named isopropyl or 1-methylethyl. To maintain four substituents on each carbon atom, one hydrogen atom has to be moved from the middle carbon atom to the carbon atom which served as attachment point in the n-propyl variant, written as −CH(CH3)2.[2]

Linear propyl is sometimes termed normal and hence written with a prefix n- (i.e., n-propyl), as the absence of the prefix n- does not indicate which attachment point is chosen, i.e. absence of prefix does not automatically exclude the possibility of it being the branched version (i.e. i-propyl[citation needed] or isopropyl).[1][failed verification] In addition, there is a third, cyclic, form called cyclopropyl, or c-propyl[citation needed]. It is not isomeric with the other two forms, having a different chemical formula (−C3H5 vs −C3H7), not just a different connectivity of the atoms.

  1. ^ a b "IUPAC Nomenclature - Acyclic Hydrocarbons Rule A-1". Retrieved 2022-07-31.
  2. ^ "IUPAC Nomenclature - Acyclic Hydrocarbons Rule A-2". Retrieved 2022-07-31.

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Propyl group

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Skeletal formula

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unambiguously indicate an alkyl group) Me for the methyl group Et for the ethyl group Pr, n-Pr, or nPr for the (normal) propyl group (Pr is also the symbol for...

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Alkyl group

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Alkyl groups form homologous series. The simplest series have the general formula −CnH2n+1. Alkyls include methyl, (−CH3), ethyl (−C2H5), propyl (−C3H7)...

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Quaternary ammonium cation

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Propynyl group

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propynyl group is a propyl bearing a triple bond. The 1-propynyl group has the structure CH3-C≡C–R. The 2-propynyl group is also known as a propargyl group, and...

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Isopropyl alcohol

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install an iso-propyl group.  This method would be highly adaptable in this application for diversification and installing other alkyl groups to enable structure-activbity...

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group, or phenyl ring, is a cyclic group of atoms with the formula C6H5, and is often represented by the symbol Ph (archaically φ). The phenyl group is...

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Amine

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cm-1, which are weaker and overlap with C-C and C-H modes. For the case of propyl amine, the H-N-H scissor mode appears near 1600 cm-1, the C-N stretch near...

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