The word hydrolysis is applied to chemical reactions in which a substance reacts with water. In organic chemistry, the products of the reaction are usually molecular, being formed by combination with H and OH groups (e.g., hydrolysis of an ester to an alcohol and a carboxylic acid). In inorganic chemistry, the word most often applies to cations forming soluble hydroxide or oxide complexes with, in some cases, the formation of hydroxide and oxide precipitates.
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molecules by hydrolysis (e.g., sucrose being broken down into glucose and fructose), this is recognized as saccharification. Hydrolysis reactions can...
Baes, C. F.; Mesmer, R. E. (1976). "Chapter 18. Survey of Hydrolysis Behaviour". The Hydrolysis of Cations. Wiley. pp. 397–430. Schwarzenbach, G.; Flaschka...
radius, r, increases. Aqua ions are subject to hydrolysis. The logarithm of the first hydrolysisconstant is proportional to z2/r for most aqua ions. The...
phosphate, the hydrolysis of ATP has the effect of lowering the pH of the reaction medium. Under certain conditions, high levels of ATP hydrolysis can contribute...
addition, the metal ion is subject to hydrolysis, that is, it behaves as a weak acid, so the pK values for the hydrolysis reactions must also be known. Assessing...
stability constant explicitly, as illustrated above. The formation of a hydroxo complex is a typical example of a hydrolysis reaction. A hydrolysis reaction...
hypochlorous acid: RR′NCl + H2O ⇌ RR′NH + HOCl The quantitative hydrolysisconstant (K value) is used to express the bactericidal power of chloramines...
extent of hydrolysis can be quantified when the values of the hydrolysisconstants can be determined experimentally. The first hydrolysisconstant refers...
(+0.417) the hydrolysis of substituted benzyl chlorides in acetone-water at 69.8 °C (-1.875). The reaction constant, or sensitivity constant, ρ, describes...
"Nobel lecture" (PDF). Nobel Prize. Baes, C. F.; Mesmer, R. E. (1976). The Hydrolysis of Cations. New York: Wiley. Payghan, Santosh (2008). "Potential Of Solubility...
and 845 nm were observed for the mononuclear and dinuclear hydrolysis species. Hydrolysis of plutonyl is important for an understanding of pollution of...
implications for all protonation equilibria in aqueous solution and for hydrolysisconstants in particular. It is quite usual to omit from the model those species...
bimolecular reaction and a simultaneous hydrolysis (which can be treated as pseudo order one) takes place: the hydrolysis complicates the study of the reaction...
acetate is rarely selected as a reaction solvent because it is prone to hydrolysis, transesterification, and condensations. Ethyl acetate is the most common...
because although the enthalpies of the hydrolysis of esters and lactones are about the same, the entropy of the hydrolysis of lactones is less than the entropy...
numerical value of solubility constant. While the solubility constant is not as simple as solubility, the value of this constant is generally independent of...
second-order rate constant for hydroxide-ion catalyzed hydrolysis of acetonitrile to acetamide is 1.6×10−6 M−1 s−1, which is slower than the hydrolysis of the amide...
Alton; Andrews, Roy C. (1928). "The Relation Between the Hydrolysis Equilibrium Constant of Esters and the Strengths of the Corresponding Acids". Journal...
total amount of ATP + ADP remains fairly constant. The energy used by human cells in an adult requires the hydrolysis of 100 to 150 mol/L of ATP daily, which...
coworkers demonstrated 34 S KIE at natural abundance measurements for the hydrolysis of sulfate monoesters. Their observation of a large KIE suggests S-O bond...
from hydrolysis and oxidation. AlP crystals are dark grey to dark yellow in color and have a zincblende crystal structure with a lattice constant of 5...
of proteins into smaller polypeptides or amino acids. Uncatalysed, the hydrolysis of peptide bonds is extremely slow, taking hundreds of years. Proteolysis...
during hydrolysis and from this a binucleophilic reaction mechanism was proposed. Corriu and coworkers then measured the rates of hydrolysis in the presence...
3, Hydrolases: catalyze the hydrolysis of various bonds EC 4, Lyases: cleave various bonds by means other than hydrolysis and oxidation EC 5, Isomerases:...
3 HCl The second method entails hydrolysis of trichloroethylene: ClHC=CCl2 + 2 H2O → ClH2C−COOH + 2 HCl The hydrolysis is conducted at 130–140 °C in a...
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