Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Cobaltocene, known also as bis(cyclopentadienyl)cobalt(II) or even "bis Cp cobalt", is an organocobalt compound with the formula Co(C5H5)2. It is a dark purple solid that sublimes readily slightly above room temperature. Cobaltocene was discovered shortly after ferrocene, the first metallocene. Due to the ease with which it reacts with oxygen, the compound must be handled and stored using air-free techniques.
^ abcd"Bis(cyclopentadienyl)cobalt(II)". American Elements. Retrieved 2018-08-24.
Cobaltocene, known also as bis(cyclopentadienyl)cobalt(II) or even "bis Cp cobalt", is an organocobalt compound with the formula Co(C5H5)2. It is a dark...
which has many analogues for other metals, such as chromocene (CrCp2), cobaltocene (CoCp2), and nickelocene (NiCp2). When the Cp rings are mutually parallel...
are characterised. Cobaltocene, Co(C5H5)2, is a metallocene, the cobalt analogue of ferrocene. It is a dark purple solid. Cobaltocene has 19 valence electrons...
has the highest electron count of the transition metal metallocenes. Cobaltocene, Co(C5H5)2, with only 19 valence electrons is, however, a stronger reducing...
yellow-gold needle-like crystals. Cobaltocene is a structural analog to ferrocene, with cobalt in place of iron. Cobaltocene is much more sensitive to oxidation...
CoCp*2 The permethylated form is more air-sensitive than the parent cobaltocene, owing to the inductive effects of methyl groups. It is a thermally stable...
was diamagnetic and centrosymmetric, also synthesizing nickelocene and cobaltocene and confirming they had the same structure. Fischer described the strcuture...
mentioned above. A QRE with ferrocene or another internal standard, such as cobaltocene or decamethylferrocene, referenced back to ferrocene is ideal for nonaqueous...
archetypal organoiron complex. It is an air-stable, sublimable compound. Cobaltocene is a structural analogue of ferrocene, but is highly reactive toward...
the structural data of ferrocene and the new complexes nickelocene and cobaltocene. Near the same time, he focused also on the then baffling chemistry resulting...
unpaired electron, paramagnetic, substitutionally labile. Examples: cobaltocene. d8 Complexes which are d8 high-spin are usually octahedral (or tetrahedral)...
octaphenylrhodocene has a sandwich structure with a staggered conformation. Unlike cobaltocene, which has become a useful one-electron reducing agent in research, no...
NaCo(CO)4. It is a catalyst in carbonylation and hydrosilylation reactions. Cobaltocene (Co(C5H5)2) is a cyclopentadiene complex of cobalt. It has 19 valence...
Royal Institute of Technology. Her doctorate considered nickelocene, cobaltocene and cyclopentadienyl (tributylphosphine)-copper in organic synthesis...
treating with suitable organic and organometallic reducing agents, such as cobaltocene and tetrakisdimethylaminoethylene. alkali metal fullerides can be subjected...
alkene, allyl, diene, and Cp ligands. A famous sandwich compound is cobaltocene, a rare example of low-spin Co(II) complex. This 19-electron metallocene...
electron transfer: comparisons of self-exchange kinetics for cobaltocenium-cobaltocene and related redox couples with theoretical predictions" (PDF). The Journal...
M(II) monomers. Ferrocene-containing dendrimers and dendrimers with cobaltocene and arylchromiumtricarbonyl units have been reported in end-functional...
generated by the high pressure carbonylation of bis(cyclopentadienyl)cobalt (cobaltocene) at elevated temperature and pressures: Co(C5H5)2 + 2 CO → C5H5Co(CO)2...
consequently lower growth rates. Solid organometallocenes such as ferrocene, cobaltocene, nickelocene are also common catalysts. It is found that the temperature...
Pauson and Wilkinson. The cobalt derivative is a poorer reductant than cobaltocene. The indenyl effect was discovered by Hart-Davis and Mawby in 1969 through...
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