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In chemistry, NMR line broadening techniques (or NMR line broadening experiments) can be used to determine the rate constant and the Gibbs free energy of exchange reactions of two different chemical compounds. If the two species are in equilibrium and exchange to each other, peaks of both species get broadened in the spectrum. This observation of broadened peaks can be used to obtain kinetic and thermodynamic information of the exchange reaction.
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temperature. If this were the only effect the line shape would be Gaussian. Pressure broadening (Collision broadening). Collisions between atoms or molecules...
materials. NMR is also routinely used in advanced medical imaging techniques, such as in magnetic resonance imaging (MRI). The original application of NMR to...
sample. For example, the broadening of signals is compensated in part by the wide chemical shift range (often 200 ppm in 1H NMR). Since paramagnetism leads...
regime: magnetic-susceptibility-induced linebroadening is attenuated which reduces inhomogeneous broadening of the spectral lines for samples in heterogeneous...
Clearly, processes that induce line-broadening on the IR time-scale must be much more rapid than the cases that exchange on the NMR time scale. The interconversion...
spectroscopy and nuclear magnetic resonance. In nuclear magnetic resonance (NMR), the theory behind it is that frequency is analogous to resonance and its...
observing linebroadening for paramagnetic ion species, and observing intermolecular NOE contacts for organometallic mimics of the metal ions. NMR is also...
solid-state NMR spectroscopy, magic-angle spinning (MAS) is a technique routinely used to produce better resolution NMR spectra. MAS NMR consists in spinning...
radiation. Modern nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) make use of this effect. The NMR signal observed following an initial excitation...
(MRI) techniques, so that signals from similar parts can be separated based on their location in the sample. DNP has triggered enthusiasm in the NMR community...
known as nuclear magnetic resonance (NMR) spectroscopy, is a non-invasive, ionizing-radiation-free analytical technique that has been used to study metabolic...
partial covalent nature. This interpretation remained controversial until NMRtechniques demonstrated information transfer between hydrogen-bonded nuclei, a...
molecular processes to differentiate between inhomogeneous and homogeneous linebroadening as well as identify coupling between the measured spectroscopic transitions...
can be determined by many techniques including calorimetry, fluorescence, spin label electron paramagnetic resonance and NMR by recording measurements...
organometallic compounds can be studied using dynamic NMR spectroscopy. Other notable techniques include X-ray absorption spectroscopy, electron paramagnetic...
Gas electron diffraction can be used for small molecules in the gas phase. NMR and FRET methods can be used to determine complementary information including...
suitability for high-temperature NMR spectroscopic studies. Disadvantages to the use of DMSO-d6 are its high viscosity, which broadens signals, and its hygroscopicity...
analytical techniques for the characterization of metal carbonyls are infrared spectroscopy and 13C NMR spectroscopy. These two techniques provide structural...
measured using sensors like UV-Vis absorption or nuclear magnetic resonance (NMR) frequency changes. A key finding of modern photochemical action plots is...
fertilizer - used the same hardware and techniques as clinical methods, but from the mid-1970s special techniques and modules were developed so that by...
the surface of the crystal. From these spectra, frequency shifts and a broadening of the peaks for the resonant and overtone frequencies of the quartz crystal...
leaf spectral reflectance to chloroplast water content determined using NMR microscopy". Remote Sensing of Environment. 46 (3): 305–310. Bibcode:1993RSEnv...
on-line analytical technique following HPLC. It is limited, however, in that MS, like nuclear magnetic resonance spectroscopy (NMR) or electrospray ionization...