Chemistry of compounds with a carbon to cobalt bond
Vitamin B12 and related cofactors are organocobalt compounds.
Organocobalt chemistry is the chemistry of organometallic compounds containing a carbon to cobalt chemical bond. Organocobalt compounds are involved in several organic reactions and the important biomolecule vitamin B12 has a cobalt-carbon bond. Many organocobalt compounds exhibit useful catalytic properties, the preeminent example being dicobalt octacarbonyl.[1]
^Omae, Iwao (2007). "Three characteristic reactions of organocobalt compounds in organic synthesis". Applied Organometallic Chemistry. 21 (5): 318–344. doi:10.1002/aoc.1213.
and 25 Related for: Organocobalt chemistry information
Organocobaltchemistry is the chemistry of organometallic compounds containing a carbon to cobalt chemical bond. Organocobalt compounds are involved in...
octacarbonyl is an organocobalt compound with composition Co2(CO)8. This metal carbonyl is used as a reagent and catalyst in organometallic chemistry and organic...
Thus CoCl2(py)4 has proven very useful in organocobaltchemistry and NiCl2(py)4 useful in organonickel chemistry. Shin, Yeung-gyo K.; Szalda, David J.; Brunschwig...
organosilicon, and organomercury chemistry. He also contributed to organocobaltchemistry and organoiron chemistry, e.g. the popularization of Fe2S2(CO)6...
Chuklanova, E. B.; Polynova, T. N.; Porai-Koshits, M. A. (1982). "New Type of Organocobalt Complexes Structure of η2-aminomethylenebis(2,2?-bipyridyl) Cobalt(III)"...
Detrembleur, Christophe (2019). "Organocobalt Complexes as Sources of Carbon-Centered Radicals for Organic and Polymer Chemistries". Chemical Reviews. 119 (12):...
Crystal Structure of Organocobalt(III) Complexes with Secondary Alkyls or Bulky Schiff Base Equatorial Ligands". Inorganic Chemistry. 35 (6): 1502–1508...
Decamethylcobaltocene is an organocobalt compound with the formula Co(C5(CH3)5)2, abbreviated CoCp∗ 2. It is a dark brown solid. This compound is used...
also as bis(cyclopentadienyl)cobalt(II) or even "bis Cp cobalt", is an organocobalt compound with the formula Co(C5H5)2. It is a dark purple solid that sublimes...
In another variation, alkynes and nitriles react in the presence of organocobalt catalysts, a reaction inspired by alkyne trimerization. Chichibabin reaction...
the Loss of Vitamin B(12) in Foods". Journal of Agricultural and Food Chemistry. 46 (1): 206–210. doi:10.1021/jf970670x. PMID 10554220. S2CID 23096987...
obtained as bright red crystals. From the perspective of coordination chemistry, methylcobalamin is notable as a rare example of a compound that contains...
an alkyne trimerisation of tryptamine derivative 1 with acetylene and organocobalt compound CpCo(C2H4)2 (THF, 0 °C) to tricycle 2 after deprotection of...
influential. The cotrimerization of alkynes and nitriles in the presence of organocobalt catalysts has been commercialized for the production of substituted pyridines...
PMID 11740917. Gridnev AA, Ittel SD, Fryd M, Wayland BB (1993). "Formation of organocobalt porphyrin complexes from reactions of cobalt(II) porphyrins and dialkylcyanomethyl...
"Cobalt and Cobalt Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH. doi:10.1002/14356007.a07_281.pub2. ISBN 3527306730. McNeill...
Cyclopentadienylcobalt dicarbonyl is an organocobalt compound with formula (C5H5)Co(CO)2, abbreviated CpCo(CO)2. It is an example of a half-sandwich complex...
complex biomolecule was established, its chemistry remained essentially unknown; exploration of this chemistry became one of the tasks of the vitamin's...
understudied; however, several studies reported various mechanisms involving an organocobalt adduct, a single-electron transfer, and a halogen–cobalt bond. Chloroform...
metal atom migration in the crystalline phase". Journal of Organometallic Chemistry. 573 (1–2): 60–66. doi:10.1016/S0022-328X(98)00879-1. Corradini, P. (1959)...
Global Information