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Ruthenocene information


Ruthenocene
Names
IUPAC names
Ruthenocene
Bis(η5-cyclopentadienyl)ruthenium
Other names
ruthenium cyclopentadienyl, cp2Ru
Identifiers
CAS Number
  • 1287-13-4 checkY
3D model (JSmol)
  • Interactive image
ChEBI
  • CHEBI:30680
ChemSpider
  • 92229
ECHA InfoCard 100.013.696 Edit this at Wikidata
EC Number
  • 215-065-2
Gmelin Reference
 3469
PubChem CID
  • 11986121
CompTox Dashboard (EPA)
  • DTXSID90903950 Edit this at Wikidata
InChI
  • InChI=1S/2C5H5.Ru/c2*1-2-4-5-3-1;/h2*1-5H;/q-5;-1;
    Key: KRRYFXOQIMANBV-UHFFFAOYSA-N
SMILES
  • [cH-]1cccc1.[cH-]1cccc1.[Ru+2]
Properties
Chemical formula
 C10H10Ru
Molar mass 231.26 g/mol
Appearance pale yellow powder
Density 1.86 g/cm3 (25 °C)
Melting point 195 to 200 °C (383 to 392 °F; 468 to 473 K)
Boiling point 278 °C (532 °F; 551 K)
Solubility in water
 Insoluble in water, soluble in most organic solvents
Hazards
GHS labelling:[1]
Pictograms
 GHS07: Exclamation mark
Signal word
 Warning
Hazard statements
 H315, H319, H335
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Related compounds
Related compounds
 cobaltocene, nickelocene, chromocene, ferrocene, osmocene, bis(benzene)chromium
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Ruthenocene is an organoruthenium compound with the formula (C5H5)2Ru. This pale yellow, volatile solid is classified as a sandwich compound and more specifically, as a metallocene.

  1. ^ "Summary of Classification and Labelling". ECHA. Retrieved 13 December 2021.

and 13 Related for: Ruthenocene information

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Ruthenocene

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Ruthenocene is an organoruthenium compound with the formula (C5H5)2Ru. This pale yellow, volatile solid is classified as a sandwich compound and more...

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Ferrocene

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to Internal Rotation by Means of Electron Diffraction. Ferrocene and Ruthenocene". Acta Chem. Scand. 22: 2653–2670. doi:10.3891/acta.chem.scand.22-2653...

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Metallocene

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could be localized on one ferrocene unit or completely delocalized. Ruthenocene derivatives: in the solid state biruthenocene is disordered and adopts...

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Ruthenium

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carbon–ruthenium bonds. Grubbs' catalyst is used for alkene metathesis. Ruthenocene is analogous to ferrocene structurally, but exhibits distinctive redox...

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Hassium

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ferrocene, ruthenocene, and osmocene, and is expected to have the two cyclopentadienyl rings in an eclipsed conformation like ruthenocene and osmocene...

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Molecular symmetry

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Ruthenocene (stag)...

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Theodore Kuwana

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1960). "Chronopotentiometric Studies on the Oxidation of Ferrocene, Ruthenocene, Osmocene and Some of their Derivatives 1". Journal of the American Chemical...

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Osmocene

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two cyclopentadienyl rings. It is isomorphous to the lighter homologue ruthenocene, both crystallizing in an eclipsed conformation. This is in contrast...

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Organoruthenium chemistry

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the 1st generation catalyst is replaced by an NHC. The parent compound ruthenocene is unreactive because it is coordinatively saturated and contains no...

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IUPAC nomenclature of inorganic chemistry 2005

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[Co(η5-C5H5)2] rhodocene, [Rh(η5-C5H5)2] nickelocene, [Ni(η5-C5H5)2] ruthenocene, [Ru(η5-C5H5)2] osmocene, [Os(η5-C5H5)2] manganocene, [Mn(η5-C5H5)2]...

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Rhodocene

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to that of ferrocene, and in contrast to the eclipsed conformation of ruthenocene). The rhodium–centroid distance is 1.904 Å and the rhodium–carbon bond...

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Ruthenium compounds

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carbon-ruthenium bonds. Grubbs' catalyst is used for alkene metathesis. Ruthenocene is analogous to ferrocene structurally, but exhibits distinctive redox...

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Chemical vapor deposition of ruthenium

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vapor pressure is poor, complicating its practical use in a CVD process. Ruthenocene and bis(ethylcyclopentadienyl)ruthenium(II) and beta-diketonate ruthenium(II)...

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