In organometallic chemistry, a transition metal indenyl complex is a coordination compound that contains one or more indenyl ligands. The indenyl ligand is formally the anion derived from deprotonation of indene. The η5-indenyl ligand is related to the η5cyclopentadienyl anion (Cp), thus indenyl analogues of many cyclopentadienyl complexes are known. Indenyl ligands lack the 5-fold symmetry of Cp, so they exhibit more complicated geometries. Furthermore, some indenyl complexes also exist with only η3-bonding mode. The η5- and η3-bonding modes sometimes interconvert.[1]
^O'Connor, Joseph M.; Casey, Charles P. (1987). "Ring-Slippage Chemistry of Transition Metal Cyclopentadienyl and Indenyl Complexes". Chemical Reviews. 87 (2): 307–318. doi:10.1021/cr00078a002.
and 12 Related for: Transition metal indenyl complex information
organometallic chemistry, a transitionmetalindenylcomplex is a coordination compound that contains one or more indenyl ligands. The indenyl ligand is formally...
A metal carbido complex is a coordination complex that contains a carbon atom as a ligand. They are analogous to metal nitrido complexes. Carbido complexes...
A transitionmetal fullerene complex is a coordination complex wherein fullerene serves as a ligand. Fullerenes are typically spheroidal carbon compounds...
compound involves more than one metal sandwiched between two carbocyclic rings. Examples of the double sandwich include V2(indenyl)2, Ni2(COT)2 and Cr2(pentalene)2...
cyclopentadienyl ligand restores the η5-cyclopentadienyl. The so-called indenyl effect also describes changes in hapticity in a substitution reaction....
binding to the metal, each of which involves a different number of electrons "donated." A classic case is the indenyl effect in which an indenyl ligand reversibly...
the world on metalcomplexes of cyclopentadienyl, indenyl, arenes, olefins, and metal carbonyls. In the 1960s his group discovered a metal alkylidene and...
Photolysis of the tetracarbonyl gives Cp2V2(CO)5. Several analogous indenylcomplexes are known. Monocyclopentadienyl vanadium chlorides include CpVCl3...
enantioselective if prochiral alkenes are used. In these reactions, a chiral indenyl zirconium catalyst is used to induce enantioselectivity. In these reactions...
Other alkali metal germyl compounds are known. There are also numerous transitionmetalcomplexes that contain germyl as a ligand. Alkali metal germyl compounds...