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Fulleride information


Cs3C60 crystal structure

Fullerides are chemical compounds containing fullerene anions. Common fullerides are derivatives of the most common fullerenes, i.e. C60 and C70. The scope of the area is large because multiple charges are possible, i.e., [C60]n (n = 1, 2...6), and all fullerenes can be converted to fullerides. The suffix "-ide" implies their negatively charged nature.

Fullerides can be isolated as derivatives with a wide range of cations. Most heavily studied derivatives are those with alkali metals, but fullerides have been prepared with organic cations. Fullerides are typically dark colored solids that generally dissolve in polar organic solvents.

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Fulleride

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Fullerides are chemical compounds containing fullerene anions. Common fullerides are derivatives of the most common fullerenes, i.e. C60 and C70. The scope...

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Buckminsterfullerene

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suggests that reduction of C60 should occur at mild potentials leading to fulleride anions, [C60]n− (n = 1–6). The midpoint potentials of 1-electron reduction...

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Isotopes of lithium

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nuclei and lies within +10 (for LiNH2 in liquid NH3) and −12 (for Li+ in fulleride). mLi – Excited nuclear isomer. ( ) – Uncertainty (1σ) is given in concise...

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Alkali metal

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buckminsterfullerene to produce solid fullerides MnC60; sodium, potassium, rubidium, and caesium can form fullerides where n = 2, 3, 4, or 6, and rubidium...

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Molecular symmetry

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fulleride ion...

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Carbide

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carbon compounds exist: graphite intercalation compounds alkali metal fullerides endohedral fullerenes, where the metal atom is encapsulated within a fullerene...

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Molecular solid

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ISBN 978-81-88597-83-3.[permanent dead link] O. Gunnarsson (1997). "Superconductivity in Fullerides". Reviews of Modern Physics. 69 (2): 575. arXiv:cond-mat/9611150. Bibcode:1997RvMP...

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Carbon peapod

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potential as semiconductors is still ongoing. Although both the doped fullerides and ropes of SWNTs are superconductors, unfortunately, the critical temperatures...

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David Manolopoulos

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E. (1992-01-30). "Magic numbers and stable structures for fullerenes, fullerides and fullerenium ions". Nature. 355 (6359): 428–430. Bibcode:1992Natur...

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Beate Paulus

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graduated with a thesis under J. Keller entitled "Electrical conductivity in fullerides" From 1993 to 1995 she was a doctoral student at the Max Planck Institute...

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