Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Chemical compound
In chemistry, chloryl refers to a triatomic cation with chemical formula ClO+ 2. This species has the same general structure as chlorite (ClO− 2) but it is electronically different, with chlorine having a +5 oxidation state (rather than the +3 of chlorite). This makes it a rare example of a positively charged oxychloride. Chloryl compounds, such as FClO 2 and [ClO2][RuF6], are all highly reactive and react violently with water and most organic compounds.[1][2]
^Christe, K. O.; Schack, C. J.; Pilipovich, D.; Sawodny, W. (1969). "Chloryl cation, ClO+ 2". Inorganic Chemistry. 8 (11): 2489–2494. doi:10.1021/ic50081a050.
^Bougon, R.; Cicha, W. V.; Lance, M.; Meublat, L.; Nierlich, M.; Vigner, J. (1991). "Preparation characterization and crystal structure of chloryl hexafluororuthenate(1-). Crystal structure of [ClF 2]+ [RuF 6]− ". Inorganic Chemistry. 30 (1): 102–109. doi:10.1021/ic00001a019.
In chemistry, chloryl refers to a triatomic cation with chemical formula ClO+ 2. This species has the same general structure as chlorite (ClO− 2) but...
Chloryl fluoride is the chemical compound with the formula ClO2F. It is commonly encountered as side-product in reactions of chlorine fluorides with oxygen...
solid form, this chlorine oxide ionizes into the dark red ionic compound chloryl perchlorate [ClO 2]+ [ClO 4]− , which may be thought of as the mixed anhydride...
Chloral hydrate is a geminal diol with the formula Cl3C−CH(OH)2. It was first used as a sedative and hypnotic in Germany in the 1870s. Over time it was...
reacts vigorously as follows: 2 H2O + ClF5 ⟶ 4 HF + FClO2 The product, chloryl fluoride, is one of the five known chlorine oxide fluorides. These range...
akin to chlorine dioxide The empirical formula for dichlorine hexoxide / chloryl perchlorate The perchloryl cation, ClO 3 + {\displaystyle {\ce {ClO3+}}}...
of other chlorine oxides. Tetrachlorodecaoxide, a chlorite-based drug Chloryl, ClO+ 2 Greenwood, N.N.; Earnshaw, A. (2006). Chemistry of the elements...
coordination environment of the chlorine atom in ClO+ 2 (the chloryl cation), in crystalline chloryl hexafluoroantimonate, formula [ClO2][SbF6]. The chlorine...
fluoride. In a highly exothermic reaction, ClF5 reacts with water to produce chloryl fluoride and hydrogen fluoride: ClF 5 + 2 H 2O → ClO 2F + 4 HF It is also...
dioxide (ClO 2), an explosive gas Chlorite (ClO− 2), a chlorine oxyanion Chloryl (ClO+ 2), a rare example of an oxycation This disambiguation page lists...
chloromethylation via an intermediate (hydroxymethyl)arene (benzyl alcohol), chloryl cation (ClO3+) for electrophilic perchlorylation. In the multistep Lehmstedt–Tanasescu...
fluorinated by fluorine, bromine trifluoride, sulfur tetrafluoride, or chloryl fluoride, resulting iodine pentafluoride, which also reacts with iodine...
hydrides, etc. Its hydrolysis in water occurs very slowly, unlike that of chloryl fluoride. Perchloryl fluoride is produced primarily by the fluorination...
large cations. The halogens form various oxofluorides with formulae XO2F (chloryl fluoride), XO3F (perchloryl fluoride) and XOF3 with X = Cl, Br and I. IO2F3...
place, resulting in static disorder. Fluorosulfite is isoelectronic with chloryl fluoride (ClO2F) and in compounds it resembles chlorate (ClO3−). The heat...
fluorinated by fluorine, bromine trifluoride, sulfur tetrafluoride, or chloryl fluoride, resulting iodine pentafluoride, which also reacts with iodine...
trifluorosulfonate S2O5F2 PO(SO3F) ClSO3F chlorosulfuryl fluoride ClO2SO3F chloryl fluorosulfate red or pale yellow low melting point KSO3F potassium fluorosulfate...
Global Information
