Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Dichlorine hexoxide is the chemical compound with the molecular formula Cl 2O 6, which is correct for its gaseous state. However, in liquid or solid form, this chlorine oxide ionizes into the dark red ionic compound chloryl perchlorate [ClO 2]+ [ClO 4]− , which may be thought of as the mixed anhydride of chloric and perchloric acids. This compound is a notable perchlorating agent.[1]
It is produced by reaction between chlorine dioxide and excess ozone:
2 ClO 2 + 2 O 3 → 2 ClO 3 + 2 O 2 → Cl 2O 6 + 2 O 2
Dichlorinehexoxide is the chemical compound with the molecular formula Cl 2O 6, which is correct for its gaseous state. However, in liquid or solid form...
Cl2O4 or ClOClO3, chlorine (I,VII) oxide dichlorine pentoxide, Cl2O5 or ClOOClO3, is hypothetical dichlorinehexoxide or chloryl perchlorate, Cl2O6 or [ClO2]+[ClO4]−...
and decomposes at room temperature to form chlorine, oxygen, and dichlorinehexoxide (Cl2O6). Chlorine perchlorate may also be considered a chlorine derivative...
hypothetical radical akin to chlorine dioxide The empirical formula for dichlorinehexoxide / chloryl perchlorate The perchloryl cation, ClO 3 + {\displaystyle...
to illustrate the separate groupings. For example, the compound dichlorinehexoxide has an empirical formula ClO3, and molecular formula Cl2O6, but in...
room temperature to give O2 (oxygen), Cl2 (chlorine) and Cl2O6 (dichlorinehexoxide): 2ClOClO3 → O2 + Cl2 + Cl2O6 Chlorine perchlorate reacts with metal...
ultraviolet spectrum, and kinetics of the thermolysis of gaseous dichlorinehexoxide". J. Phys. Chem. 94 (9): 3860–3863. doi:10.1021/j100372a094., and...
with perchloric acid enriched in dichlorine heptoxide. Another way uses titanium tetrachloride with dichlorinehexoxide. This forms a complex with Cl2O6...
pentoxide in perchloric acid. The reaction of vanadium pentoxide and dichlorinehexoxide could produce VO(ClO4)3: 2 V2O5 + 12 Cl2O6 → 4 VO(ClO4)3 + 12 ClO2...
adducts rather than true salts. One notable chloryl compound is dichlorinehexoxide, which exists as an ionic compound more accurately described as chloryl...
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