Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Chemical compound
Chloryl fluoride is the chemical compound with the formula ClO2F. It is commonly encountered as side-product in reactions of chlorine fluorides with oxygen sources.[1] It is the acyl fluoride of chloric acid.
^Chrisie, K. O.; Wilson, R. D.; Schack, C. J. "Chloryl fluoride" Inorganic Syntheses, 1986, volume 24, pages 3–5. ISBN 0-471-83441-6
Chlorylfluoride is the chemical compound with the formula ClO2F. It is commonly encountered as side-product in reactions of chlorine fluorides with oxygen...
named as an ionic "chloryl" compound, chlorylfluoride is more a covalent compound than an ionic compound of fluoride and chloryl cation. The second category...
hydrolysis in water occurs very slowly, unlike that of chlorylfluoride. Perchloryl fluoride is produced primarily by the fluorination of perchlorates...
2 H2O + ClF5 ⟶ 4 HF + FClO2 The product, chlorylfluoride, is one of the five known chlorine oxide fluorides. These range from the thermally unstable...
fluorinated by fluorine, bromine trifluoride, sulfur tetrafluoride, or chlorylfluoride, resulting iodine pentafluoride, which also reacts with iodine pentoxide...
between −10 and +10° possibly +12, freezing −60° Difluoroaminosulfinyl fluoride F2NS(O)F is a gas but decomposes over several hours Trifluoromethylsulfinyl...
exothermic reaction, ClF5 reacts with water to produce chlorylfluoride and hydrogen fluoride: ClF 5 + 2 H 2O → ClO 2F + 4 HF It is also a strong fluorinating...
fluorinated by fluorine, bromine trifluoride, sulfur tetrafluoride, or chlorylfluoride, resulting iodine pentafluoride, which also reacts with iodine pentoxide...
solid form, this chlorine oxide ionizes into the dark red ionic compound chloryl perchlorate [ClO 2]+ [ClO 4]− , which may be thought of as the mixed anhydride...
halogens form various oxofluorides with formulae XO2F (chlorylfluoride), XO3F (perchloryl fluoride) and XOF3 with X = Cl, Br and I. IO2F3 and IOF5 are also...
is isoelectronic with chlorylfluoride (ClO2F) and in compounds it resembles chlorate (ClO3−). The heat of formation from fluoride (F−) and sulfur dioxide...
coordination environment of the chlorine atom in ClO+ 2 (the chloryl cation), in crystalline chloryl hexafluoroantimonate, formula [ClO2][SbF6]. The chlorine...
fluoroselenites SeO3F− and the fluorosulfites SO2F−. The sulfate fluorides are distinct, as they contain fluoride ions without a bond to the sulfate groups. One fluorosulfate...