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Chloryl fluoride information


Chloryl fluoride
Chloryl fluoride
Names
Other names
chlorine dioxide fluoride
Identifiers
CAS Number
  • 13637-83-7 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 123044 ☒N
PubChem CID
  • 139523
CompTox Dashboard (EPA)
  • DTXSID00159769 Edit this at Wikidata
InChI
  • InChI=1S/ClFO2/c2-1(3)4 ☒N
    Key: YVRLYFHVJLYEHM-UHFFFAOYSA-N ☒N
  • InChI=1/ClFO2/c2-1(3)4
    Key: YVRLYFHVJLYEHM-UHFFFAOYAO
SMILES
  • FCl(=O)=O
Properties
Chemical formula
ClFO2
Molar mass 86.45 g·mol−1
Density 3.534 g/L
Melting point −115 °C
Boiling point −6 °C
Related compounds
Related compounds
Perchloryl fluoride
Chloryl trifluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Chloryl fluoride is the chemical compound with the formula ClO2F. It is commonly encountered as side-product in reactions of chlorine fluorides with oxygen sources.[1] It is the acyl fluoride of chloric acid.

  1. ^ Chrisie, K. O.; Wilson, R. D.; Schack, C. J. "Chloryl fluoride" Inorganic Syntheses, 1986, volume 24, pages 3–5. ISBN 0-471-83441-6

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Chloryl fluoride

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Chloryl fluoride is the chemical compound with the formula ClO2F. It is commonly encountered as side-product in reactions of chlorine fluorides with oxygen...

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Chloryl

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named as an ionic "chloryl" compound, chloryl fluoride is more a covalent compound than an ionic compound of fluoride and chloryl cation. The second category...

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Perchloryl fluoride

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hydrolysis in water occurs very slowly, unlike that of chloryl fluoride. Perchloryl fluoride is produced primarily by the fluorination of perchlorates...

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Chlorine

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2 H2O + ClF5 ⟶ 4 HF + FClO2 The product, chloryl fluoride, is one of the five known chlorine oxide fluorides. These range from the thermally unstable...

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Iodine

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fluorinated by fluorine, bromine trifluoride, sulfur tetrafluoride, or chloryl fluoride, resulting iodine pentafluoride, which also reacts with iodine pentoxide...

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List of gases

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between −10 and +10° possibly +12, freezing −60° Difluoroaminosulfinyl fluoride F2NS(O)F is a gas but decomposes over several hours Trifluoromethylsulfinyl...

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Chlorine oxide

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chlorine oxides: chloryl, ClO+2 perchloryl, ClO+3 hypochlorite, ClO− chlorite, ClO−2 chlorate, ClO−3 perchlorate, ClO−4 Oxygen fluoride(s), bromine oxide(s)...

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Chlorine pentafluoride

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exothermic reaction, ClF5 reacts with water to produce chloryl fluoride and hydrogen fluoride: ClF 5 + 2 H 2O → ClO 2F + 4 HF It is also a strong fluorinating...

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Iodine compounds

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fluorinated by fluorine, bromine trifluoride, sulfur tetrafluoride, or chloryl fluoride, resulting iodine pentafluoride, which also reacts with iodine pentoxide...

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List of inorganic compounds

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Chlorosulfonic acid – ClSO3H Chlorosulfonyl isocyanate – ClSO2NCO Chloryl fluoride – ClO2F Chromium(II) chloride – CrCl2 Chromium(III) chloride – CrCl3...

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Dichlorine hexoxide

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solid form, this chlorine oxide ionizes into the dark red ionic compound chloryl perchlorate [ClO 2]+ [ClO 4]− , which may be thought of as the mixed anhydride...

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Oxohalide

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halogens form various oxofluorides with formulae XO2F (chloryl fluoride), XO3F (perchloryl fluoride) and XOF3 with X = Cl, Br and I. IO2F3 and IOF5 are also...

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Fluorosulfite

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is isoelectronic with chloryl fluoride (ClO2F) and in compounds it resembles chlorate (ClO3−). The heat of formation from fluoride (F−) and sulfur dioxide...

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Chlorine trifluoride dioxide

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Chlorine trifluoride dioxide Names Other names Chloryl trifluoride, chlorine dioxytrifluoride, trifluorodioxychlorine Identifiers CAS Number 38680-84-1 Y...

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Dichlorine pentoxide

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image PubChem CID 153991604 (perchloryl chloride peroxide) 154081050 (chloryl chlorate) SMILES ClOOCl(=O)(=O)=O Properties Chemical formula Cl2O5 Molar...

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Thermal ellipsoid

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coordination environment of the chlorine atom in ClO+ 2 (the chloryl cation), in crystalline chloryl hexafluoroantimonate, formula [ClO2][SbF6]. The chlorine...

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Fluorosulfates

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fluoroselenites SeO3F− and the fluorosulfites SO2F−. The sulfate fluorides are distinct, as they contain fluoride ions without a bond to the sulfate groups. One fluorosulfate...

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